Iodine speciation in rain, snow and aerosols

Atmospheric Chemistry and Physics

Volumn 8, Issue 20, 2008, Pages 6069-6084

  Gilfedder, B S ^a,d   Lai, S C ^b   Petri, M ^c   Biester, H ^a,d   Hoffmann, T ^b  

^a Institut für Umwelt Geochemie   (Germany)

^b JOHANNES GUTENBERG UNIVERSITY   (Germany)

^c Sipplingen Laboratory   (Germany)

^d TECHNICAL UNIVERSITY OF BRAUNSCHWEIG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 72449198735     PISSN: 16807316     EISSN: 16807324     Source Type: Journal    
DOI: 10.5194/acp-8-6069-2008     Document Type: Article

References (50)

1. Andersson, M., De Benoist, B., Darnton-Hill, I., and Delange, F.: Iodine deficiency in Europe: a continuing public health problem, World Health Organization, Geneva, 1-86, 2007.
2. Baker, A. R., Thompson, D., Campos, A. M., Parry, S. J., and Jickells, T. D.: Iodine concentrations and availability in atmospheric aerosol, Atmos. Environ., 34, 4331-4336, 2000. (Pubitemid 30628399)
3. Baker, A. R., Tunnicliffe, C., and Jickells, T. D.: Iodine speciation and deposition fluxes from the marine atmosphere, J. Geophys. Res., 106, 28 743-28 749, 2001.
4. Baker, A. R.: Inorganic iodine speciation in tropical Atlantic aerosol, Geophys. Res. Lett., 31, L23S02, doi:10.1029/2004GL020144, 2004. (Pubitemid 40482471)
5. Baker, A. R.: Marine aerosol iodine chemistry: the importance of soluble organic iodine, Environ. Chem., 2, 295-298, 2005. (Pubitemid 41801209)
6. Biester, H., Keppler, F., Putschew, A., Martinez-Cortizas, A., and Petri, M.: Halogen Retention, Organohalogens and the Role of Organic Matter Decomposition on Halogen Enrichment in Two Chilean Peat bogs, Environ. Sci. Technol., 38, 1984-1991, 2004. (Pubitemid 38468796)
7. Bigg, E. K.: Source, nature and influence on climate of marine airborne particles, Environ. Chem., 4, 155-161, 2007. (Pubitemid 46985269)
8. Cainey, J. M.: Understanding the origin of clouds, Environ. Chem., 4, 141-142, 2007. (Pubitemid 46985266)
9. Cainey, J. M., Keywood, M., Bigg, E. K., Grose, M. R., Gillett, R. W., and Meyer, M.: Flux chamber study of particle formation from Durvillaea potatorum, Environ. Chem., 4, 151-154, 2007. (Pubitemid 46985268)
10. Campos, M. L. A. M., Nightingale, P. D., and Jickells, T. D.: A comparison of methyl iodide emissions from seawater and wet depositional fluxes of iodine over the southern North Sea, Tellus, 48 B, 106-114, 1996.
11. Chin, W.-C., Orellana, M. V., and Verdugo, P.: Spontaneous assembly of marine dissolved organic matter into polymer gels, Nature, 391, 568-572, 1998. (Pubitemid 28157594)
12. De Benoist, B., Andersson, A., Egli, I., Takkouche, B., and Allen, H.: Iodine status worldwide, World Health Organization, Geneva, 1-46, 2004.
13. Duce, R. A., Winchester, J. W., and Van Nahl, T. W.: Iodine, bromine, and chlorine in the Hawaiian marine atmosphere, J. Geophys. Res., 70, 1775-1799, 1965.
14. Enami, S., Vecitis, C. D., Cheng, J., Hoffmann, M. R., and Colussi, A. J.: Global inorganic source of atmospheric bromine, J. Phys. Chem. A, Letters, 111, 8749-8752, doi:10.1021/jp074903r, 2007. (Pubitemid 47497588)
15. Fuge, R., and Johnson, C. C.: The geochemistry of iodine - a review, Environ. Geochem. Health, 8, 31-54, 1986.
16. Gilfedder, B. S., Petri, M., and Biester, H.: Iodine speciation in rain and snow: Implications for the atmospheric iodine sink, J. Geophys. Res., 112, DO7301, doi:10.1029/2006JD007356, 2007a. (Pubitemid 46916221)
17. Gilfedder, B. S., Petri, M., and Biester, H.: Iodine and bromine speciation in snow and the effect of orographically induced precipitation, Atmos. Chem. Phys., 7, 2661-2669, 2007b, http://www.atmos-chem-phys.net/7/2661/ 2007/. (Pubitemid 46791232)
18. Jenk, T., Gäggeler, H. W., Schwerzman, A. A., and Schwikowski, M.: Recovery of a 150m ice core down to bedrock from the Fiescherhorn Glacier, PSI - annual report, Bern, http://lch.web.psi. ch/pdf/anrep02/023-analytics.pdf, last access: September 2008, 2002.
19. Keppler, F., Eiden, R., Niedan, V., Pracht, J., and Schöler, H. F.: Halocarbons produced by natural oxidation processes during degradation of organic matter, Nature, 403, 298-301, doi:10.1038/35002055, 2000. (Pubitemid 30062383)
20. Krupp, G. and Aumann, D. C.: The origin of iodine in soil: I. Iodine in rainfall over Germany, Chem. Erde., 59, 57-67, 1999. (Pubitemid 29176302)
21. Leck, C., and Bigg, E. K.: Source and evolution of marine aerosol - A new perspective, Geophys. Res. Lett., 32, L19803, doi:10.1029/12005GL023651, 2005.
22. Leck, C. and Bigg, E. K.: Comparison of sources and nature of the tropical aerosol with the summer high Arctic aerosol, Tellus, 118-126, doi: 10.1111/j.1600-0889.2007.00315.x, 2007.
23. Manley, S. L., Wang, N.-Y., Walser, M. L., and Cicerone, R. J.: Methyl halide emissions from greenhousegrown mangroves, Geophys. Res. Lett., 34, L01806, doi:01810.01029/02006GL027777, 2007.
24. McFiggans, G., Plane, J. M. C., Allan, B. J., and Carpenter, L. J.: A modeling study of iodine chemistry in the marine boundary layer, J. Geophys. Res., 105, 14 371-14 385, 2000.
25. McFiggans, G., Coe, H., Burgess, R., Allan, J., Cubison, M., Alfarra, M. R., Saunders, R., Saiz-Lopez, A., Plane, J. M. C., Wevill, D. J., Carpenter, L. J., Rickard, A. R., and Monks, P. S.: Direct evidence for coastal iodine particles from Laminaria macroalgae - Linkage to emissions of molecular iodine, Atmos. Chem. Phys., 4, 701-713, 2004, http://www.atmos-chem-phys.net/4/701/2004/ . (Pubitemid 39000909)
26. McFiggans, G.: Marine aerosols and iodine emissions, Nature, 433, E13-E14, doi:10.1038/nature03373, 2005.
27. Moyers, J. L. and Duce, R. A.: Gaseous and particulate iodine in the marine atmosphere, J. Geophys. Res., 77, 5229-5238, 1972.
28. Murphy, D. M., Cziczo, D. J., Hudson, P. K., and Thompson, D. S.: Carbonaceous material in aerosol particles in the lower stratosphere and tropopause region, J. Geophys. Res., 112, DO4203, doi:4210.1029/2006JD007297, 2007. (Pubitemid 47489835)
29. O'Dowd, C. D., Jimenez, J. L., Bahreini, R., Flagan, R. C., Seinfeld, J. H., Hameri, K., Pirjola, L., Kulmala, M., Jennings, S. G., and Hoffmann, T.: Marine aerosol formation from biogenic iodine emissions, Nature, 417, 632-636, 2002. (Pubitemid 34614818)
30. O'Dowd, C. D., Facchini, M. C., Cavalli, F., Ceburnis, D., Mircea, M., Decesari, S., Fuzzi, S., Yoon, Y. J., and Putaud, J. P.: Biogenically driven organic contribution to marine aerosol, Nature, 431, 676, 2004.
31. O'Dowd, C. D. and Hoffmann, T.: Coastal new particle formation: a review of the current state-of-the-art, Environ. Chem., 2, 245-255, 2005. (Pubitemid 41801203)
32. Orellana, M. V. and Verdugo, P.: Ultraviolet radiation blocks the organic carbon exchange between the dissolved phase and the gel phase in the ocean, Limnol. Oceanogr., 48, 1618-1623, 2003. (Pubitemid 36964781)
33. Pechtl, S., Lovejoy, E. R., Burkholder, J. B., and von Glasow, R.: Modeling the possible role of iodine oxides in atmospheric new particle formation, Atmos. Chem. Phys., 6, 505-523, 2006, http://www.atmos-chem-phys.net/ 6/505/2006/.
34. Pechtl, S., Schmitz, G., and von Glasow, R.: Modelling iodide - iodate speciation in atmospheric aerosol: Contributions of inorganic and organic iodine chemistry, Atmos. Chem. Phys., 7, 1381-1393, 2007, http://www.atmos-chem-phys. net/7/1381/2007/. (Pubitemid 46353428)
35. Rancher, J. and Kritz, M. A.: Diurnal fluctuations of Br and I in the tropical marine atmosphere, J. Geophys. Res., 85, 5581-5587, 1980.
36. Rosinski, J. and Parungo, F.: Terpene-Iodine compounds as ice nuclei, J. Appl. Meteorol., 5, 119-123, 1966.
37. Saiz-Lopez, A. and Plane, J. M. C.: Novel iodine chemistry in the marine boundry layer, Geophys. Res. Lett., 31, L04112, doi:1029/2003GL019215, 2004.
38. Saiz-Lopez, A., Plane, J. M. C., McFiggans, G., Williams, P. I., Ball, S. M., Bitter, M., Jones, R. L., Hongwei, C., and Hoffmann, T.: Modelling molecular iodine emissions in a costal marine environment: the link to new particle formation, Atmos. Chem. Phys., 6, 883-895, 2006, http://www.atmos-chem- phys.net/6/883/2006/.
39. Saunders, R. W. and Plane, J. M. C.: Formation pathways and composition of iodine oxide ultra-fine particles, Environ. Chem., 2, 299-303, 2005. (Pubitemid 41801210)
40. Schnell, D. and Aumann, D. C.: The origin of iodine in soil: Iodine in soils of Germany, Chem. Erde., 59, 69-76, 1999. (Pubitemid 29176303)
41. Sellegri, K., Yoon, Y. J., Jennings, S. G., O'Dowd, C. D., Pirjola, L., Cautenet, S., Chen, H., and Hoffmann, T.: Quantification of coastal new ultra-fine particles formation from in situ and chamber measurements during the BIOFLUX campaign, Environ. Chem., 2, 260-270, 2005. (Pubitemid 41801205)
42. Seto, F. Y. B. and Duce, R. A.: A laboratory study of iodine enrichment on atmospheric sea-salt particles produced by bubbles, Geophys. Res., 77, 5339-5349, 1972.
43. Sive, B. C., Varner, R. K., Mao, H., Blake, D. R., Wingenter, O. W., and Talbot, R.: A large terrestrial source of methyl iodide, Geophys. Res. Lett., 34, L17808, doi:17810.11029/12007GL030528, 2007.
44. Sturges, W. T. and Barrie, L. A.: Chlorine, bromine and iodine in arctic aerosols, Atmos. Environ., 22, 1179-1194, 1988. (Pubitemid 19298722)
45. Toyota, K., Kanaya, Y., Takahashi, M., and Akimoto, H.: A box model study on photochemical interactions between VOCs and reactive halogen species in the marine boundary layer, Atmos. Chem. Phys., 4, 1961-1987, 2004, http://www.atmos-chem-phys.net/4/1961/2004/.
46. Truesdale, V. W. and Jones, S. D.: The variation of iodate and total iodine in some UK rainwater samples during 1980-1981, J. Hydrol., 179, 67-86, 1996.
47. Väkevä, M., Hämeri, K., and Aalto, P. P.: Hygroscopic properties of nucleation mode and Aitken mode particles during nucleation bursts and in background air on the west coast of Ireland, J. Geophys. Res., 107, 8104, 2002.
48. Vogt, R., Sander, R., von Glasow, R., and Crutzen, P. J.: Iodine chemistry and its role in halogen activation and ozone loss in the marine boundary layer: A model study, J. Atmos. Chem., 32, 375-395, 1999. (Pubitemid 29134790)
49. Whalley, L. K., Furneaux, K. L., Gravestock, T., Atkinson, H. M., Bale, C. S. E., Ingham, T., Bloss, W. J., and Heard, D. E.: Detection of iodine monoxide radicals in the marine boundary layer using laser induced fluorescence spectroscopy, J. Atmos. Chem., 58, 19-39, 2007. (Pubitemid 47292868)
50. Wong, G. T. F. and Cheng, X. H.: The formation of iodide in inshore waters from the photochemical decomposition of dissolved organic iodine, Mar. Chem., 74, 53-64, 2001. (Pubitemid 32176632)