Detection of iodine monoxide radicals in the marine boundary layer using laser induced fluorescence spectroscopy

Journal of Atmospheric Chemistry

Volumn 58, Issue 1, 2007, Pages 19-39

  Whalley, Lisa K ^a   Furneaux, Kate L ^a   Gravestock, Tom ^a   Atkinson, Helen M ^a   Bale, Catherine S E ^a   Ingham, Trevor ^a   Bloss, William J ^b   Heard, Dwayne E ^a  

^a UNIVERSITY OF LEEDS   (United Kingdom)

^b UNIVERSITY OF BIRMINGHAM   (United Kingdom)

Author keywords

Free radicals; Iodine monoxide; Laser induced fluorescence; Marine boundary layer; RHaMBLe

Indexed keywords

ATMOSPHERIC CHEMISTRY; BOUNDARY LAYER; CALIBRATION; FLUORESCENCE; FREE RADICAL; IODINE; MARINE ENVIRONMENT;

ACCURACY; ARTICLE; ATMOSPHERE; CALIBRATION; CHEMICAL ANALYSIS; FLUORESCENCE SPECTROSCOPY; FRANCE; INSTRUMENT; MARINE ENVIRONMENT; MEASUREMENT; NEODYMIUM LASER; SENSITIVITY ANALYSIS; STATISTICAL SIGNIFICANCE;

BRETAGNE; EURASIA; EUROPE; FINISTERE; FRANCE; ROSCOFF; WESTERN EUROPE;

EID: 34548098054     PISSN: 01677764     EISSN: None     Source Type: Journal    
DOI: 10.1007/s10874-007-9075-9     Document Type: Article

References (55)

1. Alicke, B., Hebestreit, K., Stutz, J., Platt, U.: Iodine oxide in the marine boundary layer. Nature 397, 572-573 (1999)
2. Allan, B.J., McFiggans, G., Plane, J.M.C., Coe, H.: Observations of iodine monoxide in the remote marine boundary layer. J. Geophys. Res. 105, 14363-14369 (2000)
3. Atkinson, R., Wayne, R. P.: Summary of evaluated kinetic and photochemical data for atmospheric chemistry (2000)
4. Bauer, D., Ingham, T., Carl, S.A., Moortgat, G.K., Crowley, J.N.: Ultraviolet-visible absorption cross sections of gaseous HOI and its photolysis at 355 nm. J. Phys. Chem. A 102, 2857-2864 (1998)
5. 3/2 system of iodine oxide (IO). J. Mol. Spectrosc. 102, 320-343 (1983)
6. Bloss, W.J., Rowley, D.M., Cox, R.A., Jones, R.L.: Kinetics and products of the IO self-reaction. J. Phys. Chem. A 105, 7840-7854 (2001)
7. 2, NO and IO by laser-induced fluorescence. J. Environ. Monit. 5, 21-28 (2003)
8. 2 concentrations at a coastal site. Geophys. Res. Lett. 32, L06814 (2005) doi: 10.1029/2004GL022084
9. 3P). J. Atmos. Chem. 34, 153-162 (1999)
10. Carpenter, L.J., Sturges, W.T., Penkett, S.A., Liss, P.S., Alicke, B., Hebestreit, K., Platt, U.: Short-lived alkyl iodides and bromides at Mace Head, Ireland: links to biogenic sources and halogen oxide production. J. Geophys. Res. 104, 1679-1689 (1999)
11. Carpenter, L.J., Hebestreit, K., Platt, U., Liss, P.S.: Coastal zone production of IO precursors: a 2-dimensional study. Atmos. Chem. Phys. 1, 9-18 (2001)
12. 3. J. Phys. Chem. 96, 3321-3331 (1992)
13. Chameides, W.L., Davis, D.D.: Iodine - its possible role in tropospheric photochemistry. J. Geophys. Res. 85, 7383-7398 (1980)
14. Cox, R.A., Bloss, W.J., Jones, R.L., Rowley, D.M.: OIO and the atmospheric cycle of iodine. Geophys. Res. Lett. 26, 1857-1860 (1999)
15. Creasey, D.J., Heard, D.E., Pilling, M.J., Whitaker, B.J., Berzins, M., Fairlie, R.: Visualisation of a supersonic free-jet expansion using laser-induced fluorescence spectroscopy: application to the measurement of rate constants at ultralow temperatures. Appl. Phys. B 65, 375-391 (1997)
16. 2 radicals. Geophys. Res. Lett. 27, 1651-1654 (2000)
17. Curtis, A.R., Sweetenham, W.P.: H. M. Stationary Office (1987)
18. Durie, R.A., Ramsay, D.A.: Absorption spectra of the halogen monoxides. Can. J. Phys. 36, 35 (1958)
19. 2. Anal. Chem. 75, 5317-5327 (2003)
20. 2: characteristics and calibration. J. Atmos. Chem. 47, 139-167 (2004)
21. 2. Rev. Sci. Instrum. 68, 4253-4262 (1997)
22. 2. J. Atmos. Chem. 12, 195-209 (1991)
23. 3P) with alkyl iodides: rate coefficients and reaction products. J. Phys. Chem. 100, 14005-14015 (1996)
24. Gravestock, T.: A kinetic and spectroscopic study of chemistry relating to the atmospheric role of iodine species. PhD Thesis University of Leeds (2006)
25. Gravestock, T., Blitz, M.A., Heard, D.E.: Kinetics study of the reaction of iodine monoxide radicals with dimethyl sulfide. Phys. Chem. Chem. Phys. 7, 2173-2181 (2005)
26. 2 in the troposphere. Chem. Rev. 103, 5163-5198 (2003)
27. 2 radical concentrations and photolysis frequencies during BERLIOZ. J. Geophys. Res. 108, 8246-8267 (2003)
28. JPL. Chemical kinetics and photochemical data for use in atmospheric studies evaluation, number 15, 42 (2006)
29. 2 using light emitting diodes. Analyst 131, 916-922 (2006)
30. Lanzendorf, E.J., Hanisco, T.F., Donahue, N.M., Wennberg, P.O.: The measurement of tropospheric OH radicals by laser-induced fluorescence spectroscopy during the POPCORN field campaign and intercomparison of tropospheric OH radical measurements by multiple folded long-path laser absorption and laser induced fluorescence - comment. Geophys. Res. Lett. 24, 3037-3038 (1997)
31. 2 mixtures. J. Phys. Chem. 99, 11701-11707 (1995)
32. Lide, D.R. (ed.): CRC Handbook of Chemistry and Physics, Internet Version 2007, 87th edn. Taylor and Francis, Boca Raton, FL (2007) http://www. hbcpnetbase.com
33. 2. Anal. Chem. 73, 5485-5493 (2001)
34. 2 in the marine atmosphere by laser-induced fluorescence technique. Atmos. Environ. 35, 2803-2814 (2001)
35. McFiggans, G., The RHaMBLe Coastal Team: Iodine-mediated ultrafine particle formation in the RHaMBLe Roscoff 2007 coastal experiment. Geophys. Res. Abstr. 9, 10701 (2007)
36. McFiggans, G., Plane, J.M.C., Allan, B.J., Carpenter, L.J., Coe, H., O'Dowd, C.: A modeling study of iodine chemistry in the marine boundary layer. J. Geophys. Res. 105, 14371-14385 (2000)
37. McFiggans, G., Coe, H., Burgess, R., Allan, J., Cubison, M., Alfarra, M.R., Saunders, R., Saiz-Lopez, A., Plane, J.M.C., Wevill, D.J., Carpenter, L.J., Rickard, A.R., Monks, P.S.: Direct evidence for coastal iodine particles from Laminaria macroalgae - linkage to emissions of molecular iodine. Atmos. Chem. Phys. 4, 701-713 (2004)
38. Nakano, Y., Enami, S., Nakamichi, S., Aloisio, S., Hashimoto, S., Kawasaki, M.: Temperature and pressure dependence study of the reaction of IO radicals with dimethyl sulfide by cavity ring-down laser spectroscopy. J. Phys. Chem. A 107, 6381-6387 (2003)
39. 3/2 state of IO studied by cavity ring-down spectroscopy. J. Chem. Soc. Faraday Trans. 94, 2681-2688 (1998)
40. 2 (415-525 nm). J. Phys. Chem. A 108, 4864-4872 (2004)
41. O'Dowd, C.D., Hoffmann, T.: Coastal new particle formation: a review of the current state-of-the-art. Environ. Chem. 2, 245-255 (2005)
42. O'Dowd, C.D., Jimenez, J.L., Bahreini, R., Flagan, R.C., Seinfeld, J.H., Hameri, K., Pirjola, L., Kulmala, M., Jennings, S.G., Hoffmann, T.: Marine aerosol formation from biogenic iodine emissions. Nature 417, 632-636 (2002)
43. Peters, C., Pechtl, S., Stutz, J., Hebestreit, K., Honninger, G., Heumann, K.G., Schwarz, A., Winterlik, J., Platt, U.: Reactive and organic halogen species in three different European coastal environments. Atmos. Chem. Phys. 5, 3357-3375 (2005)
44. Plane, J.M.C., Joseph, D.M., Allan, B.J., Ashworth, S.H., Francisco, J.S.: An experimental and theoretical study of the reactions OIO plus NO and OH plus OH. J. Phys. Chem. A 110, 93-100 (2006)
45. Platt, U., Honninger, G.: The role of halogen species in the troposphere. Chemosphere 52, 325-338 (2003)
46. 2ICl. J. Chem. Soc. Faraday Trans. 93, 2839-2846 (1997)
47. Saiz-Lopez, A., Plane, J.M.C.: Novel iodine chemistry in the marine boundary layer. Geophys. Res. Lett. 31, L04112 (2004) doi: 10.1029/2003GL019215
48. 3 in the mid-latitude marine boundary layer. Atmos. Chem. Phys. 6, 1513-1528 (2006a)
49. Saiz-Lopez, A., Plane, J.M.C., McFiggans, G., Williams, P.I., Ball, S.M., Bitter, M., Jones, R.L., Hongwei, C., Hoffmann, T.: Modelling molecular iodine emissions in a coastal marine environment: the link to new particle formation. Atmos. Chem. Phys. 6, 883-895 (2006b)
50. 3 radicals. Chem. Phys. Lett. 124, 68-72 (1986)
51. 2 radicals during NAMBLEX: measurements and steady state analysis. Atmos. Chem. Phys. 6, 1435-1453 (2006)
52. 2: in situ laser-induced fluorescence detection at parts per trillion mixing ratios. Anal. Chem. 72, 528-539 (2000)
53. Vipond, A., Canosa-Mas, C.E., Flugge, M.L., Gray, D.J., Shallcross, D.E., Shah, D., Wayne, R.P.: A discharge-flow study of the self-reaction of IO. Phys. Chem. Chem. Phys. 4, 3648-3658 (2002)
54. Vogt, R., Sander, R., Von Glasow, R., Crutzen, P.J.: Iodine chemistry and its role in halogen activation and ozone loss in the marine boundary layer: a model study. J. Atmos. Chem. 32, 375-395 (1999)
55. Wada, R., Beames, J.M., Orr-Ewing, A.J.: Measurement of IO radical concentrations in the marine boundary layer using a cavity ring-down spectrometer. J. Atmos. Chem. (in press)