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84906364767
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Since we could not quantify the absolute molar fraction of N-H groups participating in hydrogen bonding in the samples, the concept of hydrogen bonding index is used herein in a qualitative fashion to describe differences in hydrogen bonding as a function of temperature
-
Since we could not quantify the absolute molar fraction of N-H groups participating in hydrogen bonding in the samples, the concept of hydrogen bonding index is used herein in a qualitative fashion to describe differences in hydrogen bonding as a function of temperature.
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-
-
-
30
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84906379119
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-
This temperature was chosen because viscosity is low enough that the apparatus does not reach shear stress limit at high shear rate
-
This temperature was chosen because viscosity is low enough that the apparatus does not reach shear stress limit at high shear rate.
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-
-
-
33
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84906393003
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The high resistance of compound 9a to crystallization under thermal conditions was already reported. See ref 11
-
The high resistance of compound 9a to crystallization under thermal conditions was already reported. See ref 11.
-
-
-
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34
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84906364768
-
-
Frequency scans were performed at various amplitudes, but the results did not vary significantly
-
Frequency scans were performed at various amplitudes, but the results did not vary significantly.
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-
-
-
35
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84906406854
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No degradation was observed in the same temperature range by DSC, possibly because the DSC measurement was taken under nitrogen atmosphere. Chlorinated polymers such as PVC are known to degrade upon heating: Fuchsman, C. H. SPE J. 1959, 15, 787-790.
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84906379116
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For ease of comparison, bonded N-H vs free N-H ratios (which were calculated by comparing the heights of the respective bands) were normalized to a value of 1 for the measure taken at the lowest temperature for each data set. Thus, for every sample, the bonded N-H vs free N-H ratio for every temperature was divided by the ratio taken at the lowest temperature
-
For ease of comparison, bonded N-H vs free N-H ratios (which were calculated by comparing the heights of the respective bands) were normalized to a value of 1 for the measure taken at the lowest temperature for each data set. Thus, for every sample, the bonded N-H vs free N-H ratio for every temperature was divided by the ratio taken at the lowest temperature.
-
-
-
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38
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0000002354
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27744564366
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While the CH2 group of compound 1 rotates freely, triazine amines (such as the headgroups of compounds 6 and 9) are known to be hybridized sp2 (see refs 10 and 11) and display rotational barriers on the order of 18 kcal/mol: Hyengoyan, A. P.; Mamyan, S. S.; Gomktsyan, T. A.; Hambardzumyan, E. N.; Vorskanyan, A. S.; Eliazyan, K. A.; Pivazyan, V. A.; Dovlatyan, V. V. Chem. Heterocycl. Compd. 2005, 41, 1059-1061.
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