On the noninnocent nature of 1,3-dialkylimidazolium ionic liquids

Angewandte Chemie - International Edition

Volumn 43, Issue 40, 2004, Pages 5296-5297

  Dupont, Jairton ^a   Spencer, John ^b  

^a FEDERAL UNIVERSITY OF RIO GRANDE DO SUL   (Brazil)

^b James Black Foundation   (United Kingdom)

Author keywords

Carbenes; Homogeneous catalysis; Ionic liquids; Solvent effects; Synthetic methods

Indexed keywords

CATALYSIS; CHEMICAL BONDS; DECOMPOSITION; SOLVENTS;

INERT SOLVENTS; IONIC LIQUIDS;

ORGANIC COMPOUNDS;

1 N BUTYL 3 METHYLIMIDAZOLIUM HEXAFLUOROPHOSPHATE; 1,3 DIIMIDAZOLIUM DERIVATIVE; IMIDAZOLE DERIVATIVE; SOLVENT; UNCLASSIFIED DRUG;

ANALYSIS; CATALYSIS; CHEMICAL BOND; DECOMPOSITION; HECK REACTION; HILL REACTION; IONIC STRENGTH; LIQUID CULTURE; PHOSPHORUS NUCLEAR MAGNETIC RESONANCE; PHYSICAL CHEMISTRY; RING CLOSING METATHESIS; SHORT SURVEY; SYNTHESIS;

EID: 7244250129     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200460431     Document Type: Short Survey

References (23)

1. Y. Chauvin, L. Mussmann, H. Olivier, Angew. Chem. 1995, 107, 2941-2943; Angew. Chem. Int. Ed. Engl. 1995, 34, 2698-2700.
2. Y. Chauvin, L. Mussmann, H. Olivier, Angew. Chem. 1995, 107, 2941-2943; Angew. Chem. Int. Ed. Engl. 1995, 34, 2698-2700.
3. Recent review: J. Dupont, R. F. de Souza, P. A. Z. Suarez, Chem. Rev. 2002, 102, 3667-3691.
4. a) R. P. Swatloski, J. D. Holbrey, R. D. Rogers, Green Chem. 2003, 5, 361-363.
5. b) G. S. Fonseca, A. P. Umpierre, P. F. P. Fichtner, S. R. Teixeira, J. Dupont, Chem. Eur. J. 2003, 9, 3263-3269.
6. a) A. E. Bradley, J. E. Hatter, M. Nieuwenhuyzen, W. R. Pitner, K. R. Seddon, R. C. Thied, Inorg. Chem. 2002, 41, 1692-1694;
7. b) P. A. Z. Suarez, J. E. L. Dullius, S. Einloft, R. F. de Souza, J. Dupont, Inorg. Chim. Acta 1997, 255, 207-209.
8. T. L. Aymes, S. T. Diver, J. P. Richard, F. M. Rivas, K. Toth, J. Am. Chem. Soc. 2004, 126, 4366-4374.
9. Reviews: a) A. J. Arduengo III, Acc. Chem. Res. 1999, 32, 913-921;
10. b) P. Formentin, H. Garcia, A. Leyva, J. Mol. Catal. A 2004, 214, 137-142.
11. a) L. J. Xu, W. P. Chen, J. L. Xiao, Organometallics 2000, 19, 1123-1127;
12. C. J. Mathews, P. J. Smith, T. Welton, A. J. P. White, D. J. Williams, Organometallics 2001, 20, 3848-3850;
13. M. Hasan, I. V. Kozhevnikov, M. Rafiq H. Siddiqui, C. Femoni, A. Steiner, N. Winterton, Inorg. Chem. 2001, 40, 795-800.
14. a) V. K. Aggarwal, I. Emme, A. Mereu, Chem. Commun. 2002, 1612-1613;
15. b) ILs can be used under basic conditions, for example, for N-indole and O-naphthol deprotonation/alkylations: M. J. Earle, P. B. McCormac, K. R. Seddon, Chem. Commun. 1998, 2245-2246.
16. N. D. Clement, K. J. Cavell, C. Jones, C. J. Elsevier, Angew. Chem. 2004, 116, 1297-1299; Angew. Chem. Int. Ed. 2004, 43, 1277-1279.
17. N. D. Clement, K. J. Cavell, C. Jones, C. J. Elsevier, Angew. Chem. 2004, 116, 1297-1299; Angew. Chem. Int. Ed. 2004, 43, 1277-1279.
18. D. S. McGuinness, K. J. Cavell, B. F. Yates, Chem. Commun., 2001, 355-356.
19. a) M. Amirnasr, M. K. Nazeeruddin, M. Grätzel, Thermochim. Acta 2000, 31, 105-114;
20. b) M. R. R. Prasad, V. N. Krishnamurthy, Thermochim. Acta 1991, 22, 1-10.
21. J. E. L. Dullius, P. A. Z. Suarez, S. Einloft, R. F. de Souza, J. Dupont, J. Fischer, A. De Cian, Organometallics 1998, 17, 815-819.
22. J. D. Oxley, T. Prozorov, K. S. Suslick, J. Am. Chem. Soc. 2003, 125, 11138-11139.
23. H. Lebel, M. K. Janes, A. B. Charette, S. P. Nolan, J. Am. Chem. Soc. 2004, 126, 5046-5047.