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Volumn 13, Issue 1, 2010, Pages 191-194

A red luminescent organic-inorganic hybrid network with double-stranded zigzag [Cu4I4]n chains

Author keywords

Cu(I) coordination polymer; Heterocyclic thione ligand; Luminescence; Organic inorganic hybrid

Indexed keywords


EID: 72249120808     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2009.11.013     Document Type: Article
Times cited : (6)

References (35)
  • 27
    • 72249119325 scopus 로고    scopus 로고
    • To the stirring colorless solution of bmt (0.15 g, 1 mmol) in MeOH (15 mL, CuI (0.38 g, 2 mmol) in MeCN (15 mL) was added. The reaction mixture turned to white suspension, and the mixture was kept stirring for 6 h and filtered. After filtration, the filter residue was resolved in DMF. The filtrate was allowed to stand at ambient temperatures for several days. Then colorless prism crystals of complex 1 suitable for single crystal X-ray analysis were obtained. Yield: 55, 0.067 g) based on Cu. Anal. Calc. for C20H26Cu4I4N6O2S2: C, 19.88; H, 2.17; N, 6.95; Found: C, 19.84; H, 2.20; N, 6.97, IR KBr pellet, 4000-400 cm-1, 3450m, 3276vs, 3050m, 2805w, 1645vs, 1618m, 1530w, 1497m, 1454m, 1361m, 1182m, 1003w, 960w, 738s
    • -1): 3450m, 3276vs, 3050m, 2805w, 1645vs, 1618m, 1530w, 1497m, 1454m, 1361m, 1182m, 1003w, 960w, 738s.
  • 28
    • 72249091581 scopus 로고    scopus 로고
    • Crystal data for 1: C20H26Cu4I4N6O2S2, M, 1208.35, colorless prism crystal (0.20 × 0.15 × 0.10 mm, monoclinic, space group C2/m, a, 22.342(10, b, 6.479(3, c, 11.277(5) Å, β, 106.363(7)°, V, 1566.1(12) Å3, Z, 4, Dc, 2.562 g/cm3, F(0 0 0, 1128, μ, 6.785 mm-1, T, 293(2) K. 6021 reflections collected, 1920 unique (Rint, 0.0244, R1, 0.0293, wR2, 0.0801 and S, 1.044, based on 1660 reflections with I > 2σ(I, refinement on F2, Intensity data were collected on a Rigaku mercury CCD diffractometer with graphite-monochromated Mo Ka (λ, 0.71073 Å) radiation by using ω-2θ scan method at room temperature. The structure was solved by direct methods and refined by shelxtl-97 program. All non-hydrogen atoms were refined anisotropically. Positions of
    • 2). Intensity data were collected on a Rigaku mercury CCD diffractometer with graphite-monochromated Mo Ka (λ = 0.71073 Å) radiation by using ω-2θ scan method at room temperature. The structure was solved by direct methods and refined by shelxtl-97 program. All non-hydrogen atoms were refined anisotropically. Positions of the hydrogen atoms attached to carbon atoms were fixed at their ideal positions.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.