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31144471837
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note
-
Though the crystal structures of 1-I and 3-Br have been reported, we confirmed the structures of our samples by X-ray analysis. They showed results identical to those previously reported.
-
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62
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0037322474
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65
-
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31144464201
-
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note
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Using preliminary measurements with an integrating sphere at room temperature, we determined the quantum yields of 1-Br and 1-I to be 0.18 and 0.23, respectively.
-
-
-
-
66
-
-
31144454390
-
-
note
-
1-I did not show the bathochromic shift, but showed the slightly structured spectrum at 80 K. The single-exponential decay of 1-I at 80 K ruled out the appearance of a new excited state.
-
-
-
-
67
-
-
31144434104
-
-
note
-
3 and N-heteroaromatic ligands, which also indicate the weak binding and fluctuation of the ligands in solution.
-
-
-
-
68
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31144461063
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note
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From this point of view, the structure can be described as the linear chain composed of {Cu(I)-L-Cu(I)} and bridging halide ligands.
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69
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31144441146
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note
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The powder X-ray diffraction pattern of the 2-Br samples showed the broad signals slightly deviated from those expected for the structures determined by the single-crystal structure analysis.
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70
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0039721999
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(a) Juris, A.; Balzani, V.; Barigelletti, F.; Campagna, S.; Belser, P.; Von Zelewsky, A. Coord. Chem. Rev. 1988, 84, 85-277.
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(1988)
Coord. Chem. Rev.
, vol.84
, pp. 85-277
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Juris, A.1
Balzani, V.2
Barigelletti, F.3
Campagna, S.4
Belser, P.5
Von Zelewsky, A.6
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71
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0000536207
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(b) Juris, A.; Campagna, S.; Balzani, V.; Gremaud, G. Inorg. Chem. 1988, 27, 3652-3655.
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(1988)
Inorg. Chem.
, vol.27
, pp. 3652-3655
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Juris, A.1
Campagna, S.2
Balzani, V.3
Gremaud, G.4
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73
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31144469929
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note
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10 spherical ion, we assumed that the effects of coordination to Cu(I) should be estimated by the protonated compounds at the first approximation.
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74
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31144455419
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note
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+ is no longer symmetrical.
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-
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75
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0037121912
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Aslanidis, P.; Cox, P. J.; Divanidis, S.; Tsipis, A. C. Inorg. Chem. 2002, 41, 6875-6896.
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(2002)
Inorg. Chem.
, vol.41
, pp. 6875-6896
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Aslanidis, P.1
Cox, P.J.2
Divanidis, S.3
Tsipis, A.C.4
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76
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31144434619
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note
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We carried out the MO calculation for the corresponding iodide complex that shows results similar to those for the bromide complex. The mixing of iodine and copper AOs around the HOMO was greater than that found in bromide complexes.
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