Kinetics and mechanism of oxidation of aryl methyl sulfoxides with (salen)MnIII/H2O2 catalytic system

Journal of Molecular Catalysis A: Chemical

Volumn 317, Issue 1-2, 2010, Pages 104-110

  Chellamani, Arunachalam ^a   Sengu, Paramasivan ^a   Alhaji, Naina Mohamed Ismail ^a  

^a MANONMANIAM SUNDARANAR UNIVERSITY   (India)

Author keywords

(Salen)MnIII complexes; Hydrogen peroxide; Mechanism; Organic sulfoxides

Indexed keywords

(SALEN)MNIII COMPLEXES; CATALYSED OXIDATION; CATALYTIC SYSTEM; DECOMPOSITION RATE CONSTANTS; FIRST-ORDER; HYDROPEROXIDES; KINETICS AND MECHANISM; MICHAELIS-MENTEN; PRODUCT ANALYSIS; RADICAL INHIBITOR; RATE LAWS; RATE OF REACTION; REACTIVE SPECIES; SOLVENT MIXTURES; SUBSTRATE COMPLEXES; SUBSTRATE EFFECTS; WATER SOLVENT MIXTURES;

ACETONITRILE; DIMETHYL SULFOXIDE; HYDROGEN; HYDROGEN PEROXIDE; MANGANESE COMPOUNDS; ORGANIC SOLVENTS; OXIDANTS; OXIDATION; RATE CONSTANTS; REACTION KINETICS; STOICHIOMETRY; SUBSTRATES; WATER CONTENT;

MANGANESE;

EID: 72049100686     PISSN: 13811169     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.molcata.2009.11.002     Document Type: Article

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