Kinetic studies on the oxidation of aryl methyl sulfides and sulfoxides by dimethyldioxirane; Absolute rate constants and activation parameters for 4-nitrophenyl methyl sulfide and sulfoxide

Organic and Biomolecular Chemistry

Volumn 6, Issue 4, 2008, Pages 762-771

  Hanson, Peter ^a   Hendrickx, Ramon A A J ^a,b   Lindsay Smith, John R ^a  

^a UNIVERSITY OF YORK   (United Kingdom)

^b ASTRAZENECA R AND D   (Sweden)

Author keywords

[No Author keywords available]

Indexed keywords

ACETONE; ACETONITRILE; CHEMICAL OXYGEN DEMAND; HEXANE; HYDROGEN; HYDROGEN BONDS; HYDROGEN SULFIDE; MECHANISMS; METHANOL; NONMETALS; OXIDATION; OXYGEN; PARAMETER ESTIMATION; SOLUTIONS; SOLVENTS; SULFUR; ULTRAVIOLET SPECTROSCOPY; ZINC SULFIDE;

ACTIVATION PARAMETERS; AQUEOUS ACETONE; CONCERTED MECHANISM; DIMETHYLDIOXIRANE (DMDO); DONICITY; ELECTRON PAIRS; HYDROGEN-BOND DONORS; KINETIC STUDIES; MECHANISTIC INFORMATION; MONITOR (CO); NUCLEOPHILIC DISPLACEMENT; POLAR SOLVENTS; ROYAL SOCIETY OF CHEMISTRY (RSC); SECOND ORDER KINETICS; SECOND ORDER RATE CONSTANTS; SULFIDE OXIDATION; TEMPERATURE RANGES; TWO STEP REACTIONS; UV VIS SPECTROSCOPY;

RATE CONSTANTS;

4 NITROPHENYL METHYL SULFIDE; 4 NITROPHENYL METHYL SULFOXIDE; 4-NITROPHENYL METHYL SULFIDE; 4-NITROPHENYL METHYL SULFOXIDE; DIMETHYLDIOXIRANE; EPOXIDE; ORGANIC COMPOUND; SOLVENT; SULFIDE; SULFOXIDE; WATER;

ARTICLE; CHEMISTRY; KINETICS; OXIDATION REDUCTION REACTION; TEMPERATURE;

EPOXY COMPOUNDS; KINETICS; ORGANIC CHEMICALS; OXIDATION-REDUCTION; SOLVENTS; SULFIDES; SULFOXIDES; TEMPERATURE; WATER;

EID: 38949089657     PISSN: 14770520     EISSN: None     Source Type: Journal    
DOI: 10.1039/b714713a     Document Type: Article

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