Design formulae for reactive barrier membranes

Chemical Engineering Science

Volumn 65, Issue 3, 2010, Pages 1151-1158

  Carranza, S ^a   Paul, D R ^a   Bonnecaze, R T ^a  

^a The University of Texas at Austin   (United States)

Author keywords

Barrier and packaging materials; Diffusion; Mathematical modeling; Oxygen scavenging; Reactive membranes

Indexed keywords

ANALYTIC DESIGN; BARRIER AND PACKAGING MATERIALS; BARRIER PROPERTIES; DESIGN FORMULAE; FULL NUMERICAL SOLUTION; MATCHED ASYMPTOTIC EXPANSION; MATHEMATICAL MODELING; MOBILE SPECIES; MOVING REACTION FRONTS; NONLINEAR PARTIAL DIFFERENTIAL EQUATIONS; NUMERICAL SOLUTION; OXYGEN SCAVENGING; PERTURBATION THEORY; REACTION FRONT; REACTIVE BARRIERS; REACTIVE MEMBRANES; REACTIVE SITE; REACTIVE TERMS; TIME LAG; TIME VARYING; TRANSIENT FLUXES; TRANSPORT EQUATION;

ASYMPTOTIC ANALYSIS; DIFFERENTIAL EQUATIONS; FILMS; MATERIALS PROPERTIES; MEMBRANES; OXYGEN; PERTURBATION TECHNIQUES; PLASTIC COATINGS; SCAVENGING;

PACKAGING MATERIALS;

EID: 71549123756     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ces.2009.09.070     Document Type: Article

References (21)

1. Adam C., Lacoste J., and Lemaire J. Photo-oxidation of elastomeric materials. Part 1-Photo-oxidation of polybutadienes. Polymer Degradation and Stability 24 (1989) 185-200
2. Bauman R.G., and Maron S.H. Oxidation of polybutadiene. I. Rate of oxidation. Journal of Polymer Science 22 (1956) 1-12
3. Beavan S.W., and Phillips D. Mechanistic studies on the photo-oxidation of commercial poly(butadiene). European Polymer Journal 10 (1974) 593-603
4. Carranza, S., Paul, D.R., Bonnecaze, R.T. Analytic formulae for the design of reactive polymer blend barrier materials, submitted for publication.
5. Ferrari M.C., Carranza S., Bonnecaze R.T., Tung K.K., Freeman B.D., and Paul D.R. Modeling of oxygen scavenging for improved barrier behavior: blend films. Journal of Membrane Science 329 (2009) 183-192
6. Frisch H.L. The time lag in diffusion. The Journal of Physical Chemistry 61 (1957) 93-95
7. Ivanov V.B., Burkova S.G., Morozov Y.L., and Shlyapintokh V.Y. Kinetics of the chain-propagation and chain-termination reactions in the oxidation of polybutadiene and copolymers of butadiene with styrene. Kinetika i Kataliz 20 5 (1979) 1330-1333
8. Lehto V.P., and Lankinen T. Moisture transfer into medicament chambers equipped with a double-barrier-desiccant system. International Journal of Pharmaceutics 275 (2004) 155-164
9. Paul D.R. The effect of immobilizing adsorption on the diffusion time lag. Journal of Polymer Science 7A-2 (1969) 1811-1818
10. Paul D.R., and Kemp D.R. The diffusion time lag in polymer membranes containing adsorptive fillers. Journal of Polymer Science 41C (1973) 79-93
11. Paul D.R., and Koros W.J. Effect of partially immobilizing sorption on permeability and the diffusion time lag. Journal of Polymer Science: Polymer Physics Edition 14 (1976) 675-685
12. Ng E.P., and Mintova S. Review: nanoporous materials with enhanced hydrophilicity and high water sorption capacity. Microporous and Mesoporous Materials 114 (2008) 1-26
13. Piton M., and Rivaton A. Photooxidation of polybutadiene at long wavelengths (λ>300 nm). Polymer Degradation and Stability 53 (1996) 343-359
14. Nuxoll E.E., and Cussler E.L. The third parameter in reactive barrier films. AIChE Journal 51 2 (2005) 456-463
15. Siegel R.A. Algebraic, differential, and integral relations for membranes in series and other multilaminar media: permeabilities, solute consumption, lag times, and mean first passage times. The Journal of Physical Chemistry 95 6 (1991) 2556-2565
16. Siegel R.A., and Cussler E.L. Reactive barrier membranes: some theoretical observations regarding the time lag and breakthrough curves. Journal of Membrane Science 229 (2004) 33-41
17. Solovyov S.E., and Goldman A.Y. Theory of transient permeation through reactive barrier films. I. Steady state theory for homogeneous passive and reactive media. International Journal of Polymeric Materials 54 (2005) 71-91
18. Solovyov S.E., and Goldman A.Y. Theory of transient permeation through reactive barrier films. II. Two layer reactive-passive structures with dynamic interface. International Journal of Polymeric Materials 54 (2005) 93-115
19. Solovyov S.E., and Goldman A.Y. Theory of transient permeation through reactive barrier films. III. Solute ingress dynamics and model lag times. International Journal of Polymeric Materials 54 (2005) 117-139
20. Yang C., Nuxoll E.E., and Cussler E.L. Reactive barrier films. AIChE Journal 47 2 (2001) 295-302
21. Yang C., and Cussler E.L. Oxygen barriers that use free radical chemistry. AIChE Journal 47 12 (2001) 2725-2732