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71049116306
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note
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Of course, evaluation of the intrinsic contribution due to chemical modification relies on the assumption that, at least to a first approximation, effects on optical activities are nearly additive. To the best of our knowledge, no data are available in order to get similar estimations for unprotonated AmβCD at pH 11.0. Nevertheless, it seems reasonable to admit that a different protonation state for the amino group should imply different effects on the overall conformational behaviour of the host. Further investigations on the point are needed.
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note
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At the moment, we do not have a satisfactory rationale for the peculiar behaviour of 3. Nevertheless, we might tentatively suggest that factors related to molecular symmetry could be involved.
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71049155274
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note
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