메뉴 건너뛰기




Volumn 27, Issue 5-6, 2009, Pages 638-662

Extraction of Neptunium (IV) ions into 30% tri-butyl phosphate from nitric acid

Author keywords

Distribution ratio; Hydrolysis; Neptunium(IV); Nitrate complexation; Oxidation; Purex

Indexed keywords

AQUEOUS PHASE; DISTRIBUTION RATIO; NITRATE COMPLEXES; SOLVENT PHASE; SPECTROSCOPIC EVIDENCE; THERMODYNAMIC DATA; TRI-BUTYL PHOSPHATE;

EID: 70749155277     PISSN: 07366299     EISSN: 15322262     Source Type: Journal    
DOI: 10.1080/07366290903114031     Document Type: Article
Times cited : (20)

References (52)
  • 1
    • 0011288923 scopus 로고    scopus 로고
    • Reprocessing irradiated fuel
    • Wilson, P. D. Ed.; Oxford Science Publications, Oxford
    • Denniss, I. S., Jeapes, A. P. Reprocessing irradiated fuel. In The Nuclear Fuel Cycle, Wilson, P. D. Ed.; Oxford Science Publications, Oxford, 1996; 116-137.
    • (1996) In The Nuclear Fuel Cycle , pp. 116-137
    • Denniss, I.S.1    Jeapes, A.P.2
  • 2
    • 1842729883 scopus 로고
    • On the mechanism of the extraction of uranyl nitrate by TBP (partition study)
    • Naito, K. On the mechanism of the extraction of uranyl nitrate by TBP (partition study). Bull. Chem. Soc. Jpn. 1960, 33, 363-371.
    • (1960) Bull. Chem. Soc. Jpn. , vol.33 , pp. 363-371
    • Naito, K.1
  • 3
    • 0342870408 scopus 로고
    • Tri-n-butyl phosphate as an extracting solvent for inorganic nitrates - III The plutonium nitrates
    • Best, G. F.; McKay, H. A. C.; Woodgate, P. R. Tri-n-butyl phosphate as an extracting solvent for inorganic nitrates - III The plutonium nitrates. J. Inorg. Nuc. Chem. 1957, 4, 315-320.
    • (1957) J. Inorg. Nuc. Chem. , vol.4 , pp. 315-320
    • Best, G.F.1    McKay, H.A.C.2    Woodgate, P.R.3
  • 4
    • 0005698479 scopus 로고
    • Tri-n-butyl phosphate as an extracting solvent for inorganic nitrates - V Further results for the tetraand hexavalent actinide nitrates
    • Alcock, K.; Best, G. F.; Hesford, E.; McKay, H. A. C. Tri-n-butyl phosphate as an extracting solvent for inorganic nitrates - V Further results for the tetraand hexavalent actinide nitrates. J. Inorg. Nuc. Chem. 1958, 6, 328-333.
    • (1958) J. Inorg. Nuc. Chem. , vol.6 , pp. 328-333
    • Alcock, K.1    Best, G.F.2    Hesford, E.3    McKay, H.A.C.4
  • 5
    • 0042346116 scopus 로고
    • Tri-n-butyl phosphate as an extracting solvent for inorganic nitrates - VII, the trivalent actinide nitrates
    • Best, G. F.; Hesford, E.; McKay, H. A. C. Tri-n-butyl phosphate as an extracting solvent for inorganic nitrates - VII, the trivalent actinide nitrates. J. Inorg. Nuc. Chem. 1959, 12, 136-140.
    • (1959) J. Inorg. Nuc. Chem. , vol.12 , pp. 136-140
    • Best, G.F.1    Hesford, E.2    McKay, H.A.C.3
  • 6
    • 0642368907 scopus 로고
    • The extraction of nitrates by tri-n-butyl phosphate (TBP) Part 3. - Extraction at trace concentrations. Trans
    • Hesford, E.; McKay, H. A. C. The extraction of nitrates by tri-n-butyl phosphate (TBP) Part 3. - Extraction at trace concentrations. Trans. Faraday Soc. 1958, 54, 573-586.
    • (1958) Faraday Soc. , vol.54 , pp. 573-586
    • Hesford, E.1    McKay, H.A.C.2
  • 7
    • 0004966105 scopus 로고
    • The 1981 purex distribution data index
    • Unpublished report, Kernforschungszentrum Karlsruhe, KfK
    • Petrich, G.; Kolarik, Z. The 1981 Purex Distribution Data Index. Unpublished report, Kernforschungszentrum Karlsruhe, KfK 3081, 1981.
    • (1981) , pp. 3081
    • Petrich, G.1    Kolarik, Z.2
  • 8
    • 0347991563 scopus 로고
    • Purex process related distribution data on neptunium (IV,VI)
    • Unpublished report, Kernforschungszentrum Karlsruhe, KfK
    • Kolarik, Z.; Dressler, P. Purex process related distribution data on neptunium (IV,VI). Unpublished report, Kernforschungszentrum Karlsruhe, KfK 4667, 1990.
    • (1990) , pp. 4667
    • Kolarik, Z.1    Dressler, P.2
  • 9
    • 0011365501 scopus 로고
    • Separation of plutonium and uranium
    • W. W. Schulz, L. L. Burger, J. D. Navratil, Eds., CRC Press: Boca Raton
    • Miles, J. H. Separation of plutonium and uranium. In Science and Technology of Tributyl Phosphate Vol. III, W. W. Schulz, L. L. Burger, J. D. Navratil, Eds., CRC Press: Boca Raton, 1990; 11-54.
    • (1990) Science and Technology of Tributyl Phosphate , vol.III , pp. 11-54
    • Miles, J.H.1
  • 11
    • 0000710651 scopus 로고    scopus 로고
    • Np(IV) distribution between 30% tributyl phosphate in odorless kerosene and nitric acid
    • May, I.; Taylor, R.J.; Brown, G.; Hill, N.J. Np(IV) distribution between 30% tributyl phosphate in odorless kerosene and nitric acid. Radiochim. Acta 1998, 83, 135-138.
    • (1998) Radiochim Acta , vol.83 , pp. 135-138
    • May, I.1    Taylor, R.J.2    Brown, G.3    Hill, N.J.4
  • 12
    • 30444448725 scopus 로고    scopus 로고
    • Recent developments in the purex process for nuclear fuel reprocessing: Complexant based stripping for uranium - plutonium separation
    • Birkett, J.E.; Carrott, M.J.; Fox, O.D.; Jones, C.J.; Maher, C.J.; Roube, C.V.; Taylor, R.J.; Woodhead, D.A. Recent developments in the purex process for nuclear fuel reprocessing: complexant based stripping for uranium - plutonium separation. Chimia 2005, 59, 898-904.
    • (2005) Chimia , vol.59 , pp. 898-904
    • Birkett, J.E.1    Carrott, M.J.2    Fox, O.D.3    Jones, C.J.4    Maher, C.J.5    Roube, C.V.6    Taylor, R.J.7    Woodhead, D.A.8
  • 13
    • 34249710112 scopus 로고    scopus 로고
    • Advanced separation technologies for processing spent nuclear fuel and the potential benefits to a geologic repository
    • Lumetta, G.J, Nash, K.L., Clark, S.B., Friese, J.I., Eds.; ACS Symposium Series 933, American Chemical Society, Washington DC
    • st Century; Lumetta, G.J, Nash, K.L., Clark, S.B., Friese, J.I., Eds.; ACS Symposium Series 933, American Chemical Society, Washington DC., 2006; 41-56.
    • (2006) st Century , pp. 41-56
    • Todd, T.A.1    Wigelund, R.A.2
  • 14
    • 36949031075 scopus 로고    scopus 로고
    • Advanced PUREX flowsheets for future Np and Pu fuel cycle demands
    • Lumetta, G.J, Nash, K.L., Clark, S.B., Friese, J.I., Eds.; ACS Symposium Series 933, American Chemical Society, Washington DC
    • st Century; Lumetta, G.J, Nash, K.L., Clark, S.B., Friese, J.I., Eds.; ACS Symposium Series 933, American Chemical Society, Washington DC., 2006; 89-102.
    • (2006) st Century , pp. 89-102
    • Fox, O.D.1    Jones, C.J.2    Birkett, J.E.3    Carrott, M.J.4    Maher, C.J.5    Roube, C.V.6    Taylor, R.J.7
  • 15
    • 0034747558 scopus 로고    scopus 로고
    • Modelling of Np(VI) and Np(IV) distribution coefficients in 30% TBP/ n-dodecane/ nitric acid/ water biphasic Purex system
    • Kumar, S.; Koganti, S.B. Modelling of Np(VI) and Np(IV) distribution coefficients in 30% TBP/ n-dodecane/ nitric acid/ water biphasic Purex system. Ind. J. Chem. Tech. 2001, 8, 41-43.
    • (2001) Ind. J. Chem. Tech. , vol.8 , pp. 41-43
    • Kumar, S.1    Koganti, S.B.2
  • 16
    • 0038608958 scopus 로고    scopus 로고
    • An empirical correlation for Pu(III) distribution coefficients in 30% TBP/ n-dodecane PUREX system in the presence of U(VI), U(IV), Pu(IV), Pu(III) and hydrazine nitrate
    • Kumar, S.; Koganti, S.B. An empirical correlation for Pu(III) distribution coefficients in 30% TBP/ n-dodecane PUREX system in the presence of U(VI), U(IV), Pu(IV), Pu(III) and hydrazine nitrate. Solv. Extr. Ion Exch. 2003, 21, 369-380.
    • (2003) Solv. Extr. Ion Exch. , vol.21 , pp. 369-380
    • Kumar, S.1    Koganti, S.B.2
  • 17
    • 0018545603 scopus 로고
    • Mathematical model of distribution equilibria in the extraction of U(VI), U(IV), Pu(IV), Np(VI), Np(IV), and nitric acid by 30% tributyl phosphate (TBP) in aliphatic diluents
    • Kolarik, Z.; Petrich, G. A mathematical model of distribution equilibria in the extraction of U(VI), U(IV), Pu(IV), Np(VI), Np(IV), and nitric acid by 30% tributyl phosphate (TBP) in aliphatic diluents. Ber. Bunsenges. Phys. Chem. 1979, 83, 1110-1113.
    • (1979) Ber. Bunsenges. Phys. Chem. , vol.83 , pp. 1110-1113
    • Kolarik, Z.1    Petrich, G.A.2
  • 18
    • 37848998799 scopus 로고    scopus 로고
    • Solvent extraction behaviour of neptunium (IV) ions between nitric acid and diluted 30% tributyl phosphate in the presence of simple hydroxamic acids
    • Taylor, R. J.; Sinkov, S. I.; Choppin, G. R.; May, I. Solvent extraction behaviour of neptunium (IV) ions between nitric acid and diluted 30% tributyl phosphate in the presence of simple hydroxamic acids. Solv. Extr. Ion Exch. 2008, 26, 41-61.
    • (2008) Solv. Extr. Ion Exch. , vol.26 , pp. 41-61
    • Taylor, R.J.1    Sinkov, S.I.2    Choppin, G.R.3    May, I.4
  • 20
    • 37549044641 scopus 로고    scopus 로고
    • The hydrolysis of hydroxamic acid complexants in the presence of non-oxidizing metal ions 2: Neptunium (IV) ions
    • Andrieux, F. P. L.; Boxall, C.; May, I.; Taylor, R. J. The hydrolysis of hydroxamic acid complexants in the presence of non-oxidizing metal ions 2: Neptunium (IV) ions. J. Solution. Chem. 2008, 37, 215-232.
    • (2008) J. Solution. Chem. , vol.37 , pp. 215-232
    • Andrieux, F.P.L.1    Boxall, C.2    May, I.3    Taylor, R.J.4
  • 21
    • 37249041663 scopus 로고    scopus 로고
    • Neptunium (V) disproportionation and cation cation interactions in TBP/kerosene solvent
    • Sarsfield, M. J.; Taylor, R. J.; Maher, C. J. Neptunium (V) disproportionation and cation cation interactions in TBP/kerosene solvent. Radiochimica Acta 2007, 95, 677-682.
    • (2007) Radiochimica Acta , vol.95 , pp. 677-682
    • Sarsfield, M.J.1    Taylor, R.J.2    Maher, C.J.3
  • 23
    • 67849099285 scopus 로고    scopus 로고
    • Modelling of PuIV) extraction from acidic nitrate media by tri-n-butyl phosphate
    • Tkac, P.; Paulenova, A.; Vandegrift, G. F.; Krebs, J. F. Modelling of PuIV) extraction from acidic nitrate media by tri-n-butyl phosphate. J. Chem. Eng. Data 2009, 54, 1976-1974.
    • (2009) J. Chem. Eng. Data , vol.54 , pp. 1976-1974
    • Tkac, P.1    Paulenova, A.2    Vandegrift, G.F.3    Krebs, J.F.4
  • 24
    • 24244458899 scopus 로고
    • Solution chemistry of plutonium
    • Wick, O. J., Ed.; American Nuclear Society, LaGrange Park
    • Cleveland, J. M.: Solution chemistry of plutonium. In Plutonium handbook: A Guide to the Technology, Vol. I & II; Wick, O. J., Ed.; American Nuclear Society, LaGrange Park, 1980; 403-520.
    • (1980) Plutonium Handbook: A Guide to the Technology , vol.I and II , pp. 403-520
    • Cleveland, J.M.1
  • 25
    • 0032455614 scopus 로고    scopus 로고
    • Plutonium (IV) mononitrate and dinitrate complex formation in acid solutions as a function of ionic strength
    • Berg, J. M.; Veirs, D. K.; Vaughn, R. B.; Cisneros, M. A.; Smith, C. A. Plutonium (IV) mononitrate and dinitrate complex formation in acid solutions as a function of ionic strength. J. Radioanal. Nucl. Chem. 1998, 235, 25-29.
    • (1998) J. Radioanal. Nucl. Chem. , vol.235 , pp. 25-29
    • Berg, J.M.1    Veirs, D.K.2    Vaughn, R.B.3    Cisneros, M.A.4    Smith, C.A.5
  • 26
    • 0001709863 scopus 로고    scopus 로고
    • Characterization of aqueous plutonium (IV) nitrate complexes by extended X-ray absorption fine structure spectroscopy
    • Allen, P. G.; Veirs, D. K.; Conradson, S. D.; Smith, C. A.; Marsh, S. F. Characterization of aqueous plutonium (IV) nitrate complexes by extended X-ray absorption fine structure spectroscopy. Inorg. Chem. 1996, 35, 2841-2845.
    • (1996) Inorg. Chem. , vol.35 , pp. 2841-2845
    • Allen, P.G.1    Veirs, D.K.2    Conradson, S.D.3    Smith, C.A.4    Marsh, S.F.5
  • 27
    • 0001346977 scopus 로고    scopus 로고
    • On weak complex formation: Re-interpretation of literature data on the Np and Pu nitrate complexation
    • Spahiu, K.; Puigdomenech, I. On weak complex formation: re-interpretation of literature data on the Np and Pu nitrate complexation. Radiochim. Acta 1998, 82, 413-419.
    • (1998) Radiochim. Acta , vol.82 , pp. 413-419
    • Spahiu, K.1    Puigdomenech, I.2
  • 28
    • 37549056043 scopus 로고
    • Stability constants of nitrate and chloride complexes of Np(IV), Np(V) and Np(VI) ions
    • Danesi, P. R.; Chiarizia, R.; Scibona, G.; D'Alessandro, G. D. Stability constants of nitrate and chloride complexes of Np(IV), Np(V) and Np(VI) ions. J. Inorg. Nuc. Chem. 1971, 33, 3503-3510.
    • (1971) J. Inorg. Nuc. Chem. , vol.33 , pp. 3503-3510
    • Danesi, P.R.1    Chiarizia, R.2    Scibona, G.3    D'Alessandro, G.D.4
  • 29
    • 0012948332 scopus 로고
    • Complex formation of neptunium (IV) with nitrate and chloride ions
    • Shilin, I. V.; Nazarov, V. K. Complex formation of neptunium (IV) with nitrate and chloride ions. Radiokhim. 1966, 8, 514-519.
    • (1966) Radiokhim , vol.8 , pp. 514-519
    • Shilin, I.V.1    Nazarov, V.K.2
  • 31
    • 0003741627 scopus 로고    scopus 로고
    • Chemical thermodynamics of neptunium and plutonium
    • Chemical thermodynamics 4, ed. OECD Nuclear Energy Agency, Elsevier: Amsterdam
    • Chemical thermodynamics 4, Chemical thermodynamics of neptunium and plutonium, ed. OECD Nuclear Energy Agency, Elsevier: Amsterdam, 2001.
    • (2001)
  • 33
    • 0001510398 scopus 로고
    • Equilibrium partial pressures and mean activity and osmotic coefficients of 0-100% nitric acid as a function of temperature
    • Clegg, S. L.; Brimblecombe, P. Equilibrium partial pressures and mean activity and osmotic coefficients of 0-100% nitric acid as a function of temperature. J. Phys. Chem. 1990, 94, 5369-5380.
    • (1990) J. Phys. Chem. , vol.94 , pp. 5369-5380
    • Clegg, S.L.1    Brimblecombe, P.2
  • 34
    • 0000480583 scopus 로고    scopus 로고
    • Solubility, hydrolysis and colloid formation of plutonium(IV). Radiochim
    • Knopp, R.; Neck, V.; Kim, J. I. Solubility, hydrolysis and colloid formation of plutonium(IV). Radiochim. Acta 1999, 86, 101-108.
    • (1999) Acta , vol.86 , pp. 101-108
    • Knopp, R.1    Neck, V.2    Kim, J.I.3
  • 35
    • 0035128981 scopus 로고    scopus 로고
    • Solubility and hydrolysis of tetravalent actinides
    • Neck, V.; Kim, J. I. Solubility and hydrolysis of tetravalent actinides. Radiochim. Acta 2001, 89, 1-16.
    • (2001) Radiochim. Acta , vol.89 , pp. 1-16
    • Neck, V.1    Kim, J.I.2
  • 36
    • 2542452601 scopus 로고    scopus 로고
    • Update on the chemical thermodynamics of uranium, neptunium, plutonium, americium and technetium
    • Chemical thermodynamics 5, Ed.; OECD Nuclear Energy Agency, Elsevier: Amsterdam
    • Chemical thermodynamics 5, Update on the chemical thermodynamics of uranium, neptunium, plutonium, americium and technetium, Ed.; OECD Nuclear Energy Agency, Elsevier: Amsterdam 2003.
    • (2003)
  • 38
    • 56649111128 scopus 로고    scopus 로고
    • Hydrolysis constants of tetravalent neptunium by using solvent extraction method
    • Fujiwara, K.; Kohara, Y. Hydrolysis constants of tetravalent neptunium by using solvent extraction method. Radiochim. Acta 2008, 96, 613-616.
    • (2008) Radiochim. Acta , vol.96 , pp. 613-616
    • Fujiwara, K.1    Kohara, Y.2
  • 39
    • 0000878120 scopus 로고
    • Species involved in the anion-exchange absorption of quadrivalent actinide nitrates
    • Ryan, J. L. Species involved in the anion-exchange absorption of quadrivalent actinide nitrates. J. Phys. Chem. 1960, 64, 1375-1385.
    • (1960) J. Phys. Chem. , vol.64 , pp. 1375-1385
    • Ryan, J.L.1
  • 40
    • 37049103917 scopus 로고
    • Thermodynamics of extraction equilibria. Part 5. Correction of the method for the determination of equilibrium constants of extraction processes
    • Petkovic, D.M. Thermodynamics of extraction equilibria. Part 5. Correction of the method for the determination of equilibrium constants of extraction processes. J. Chem. Soc. Dalton Trans. 1978, 1, 1-4.
    • (1978) J. Chem. Soc. Dalton Trans. , vol.1 , pp. 1-4
    • Petkovic, D.M.1
  • 43
    • 46449083330 scopus 로고    scopus 로고
    • Neptunium(IV) solvate species in TBP formed by extraction from nitric acid solutions in the presence of uranyl nitrate
    • Fedorov, Yu.S; Zilberman, B.Ya.; Poverkova, L.Ya. Neptunium(IV) solvate species in TBP formed by extraction from nitric acid solutions in the presence of uranyl nitrate. Radiokhim. 2000, 42, 417-422.
    • (2000) Radiokhim , vol.42 , pp. 417-422
    • Fedorov, Y.S.1    Zilberman, B.Y.2    Poverkova, L.Y.3
  • 45
    • 0008087879 scopus 로고
    • Uranium (IV) nitrate and perchlorate species in tri-n-butyl phosphate solutions
    • Woodhead, J.L.; McKay, H.A.C. Uranium (IV) nitrate and perchlorate species in tri-n-butyl phosphate solutions. J. Inorg. Nucl. Chem. 1965, 27, 2247-2254.
    • (1965) J. Inorg. Nucl. Chem. , vol.27 , pp. 2247-2254
    • Woodhead, J.L.1    McKay, H.A.C.2
  • 46
    • 46449104217 scopus 로고    scopus 로고
    • Uranium(IV) complexes formed in extraction with tributyl phosphate from nitric acid solutions
    • Fedorov, Yu.S; Zilberman, B.Ya.; Kopyrin, A.A.; Arkhipov, S.A. Uranium(IV) complexes formed in extraction with tributyl phosphate from nitric acid solutions. Radiokhim. 2001, 43, 149-154.
    • (2001) Radiokhim , vol.43 , pp. 149-154
    • Fedorov, Y.S.1    Zilberman, B.Y.2    Kopyrin, A.A.3    Arkhipov, S.A.4
  • 52
    • 0033075280 scopus 로고    scopus 로고
    • Modelling of advanced flowsheets using data from miniature contactor trials
    • Wallwork, A. L.; Denniss, I. S.; Taylor, R. J.; Bothwell, P.; Baker, S. Modelling of advanced flowsheets using data from miniature contactor trials. Nuclear Energy 1999, 38, 31-35.
    • (1999) Nuclear Energy , vol.38 , pp. 31-35
    • Wallwork, A.L.1    Denniss, I.S.2    Taylor, R.J.3    Bothwell, P.4    Baker, S.5


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.