Solvent extraction behavior of plutonium (IV) Ions in the presence of simple hydroxamic acids

Solvent Extraction and Ion Exchange

Volumn 25, Issue 6, 2007, Pages 723-745

  Carrott, M J ^a   Fox, O D ^a   Maher, C J ^a   Mason, C ^a   Taylor, Robin ^a   Sinkov, S I ^b   Choppin, G R ^c  

^a NATIONAL NUCLEAR LABORATORY   (United Kingdom)

^b PACIFIC NORTHWEST NATIONAL LABORATORY   (United States)

^c FLORIDA STATE UNIVERSITY   (United States)

Author keywords

Acetohydroxamic acid; Actinide separations; Advanced Purex; Distribution coefficient; Formohydroxamic acid; Stability constant

Indexed keywords

ACTINIDES; NITRIC ACID; PHOSPHATES; PLUTONIUM;

ACETOHYDROXAMIC ACID; DISTRIBUTION COEFFICIENT; FORMOHYDROXAMIC ACID; STABILITY CONSTANT;

SOLVENT EXTRACTION;

ACTINIDES; NITRIC ACID; PHOSPHATES; PLUTONIUM; SOLVENT EXTRACTION;

EID: 34648822463     PISSN: 07366299     EISSN: 15322262     Source Type: Journal    
DOI: 10.1080/07366290701634560     Document Type: Article

References (49)

1. Chatterjee, B. (1978) Donor properties of hydroxamic acids. Coordination Chemistry Reviews, 26, pp. 281-303.
2. Raymond, K. N., Freeman, G. E. and Kappel, M. J. (1984) Actinide specific complexing agents: Their structural and solution chemistry. Inorganica Chimica Acta, 94, pp. 193-204.
3. Anderegg, G., L'Eplattenier, F., Schwarzenbach, G. and Hydroxamatkomplexe II (1963) Die Anwendung der pH-methode. Helvetica Chimica Acta, 46, pp. 1400-1408.
4. Barocas, A., Baroncelli, F., Biondi, G. B. and Grossi, G. (1966) The complexing power of hydroxamic acids and its effect on behaviour of organic extractants in the reprocessing of irradiated fuels-II. J. Inorg. Nucl. Chem, 28, pp. 2961-2967.
5. Baroncelli, F. and Grossi, G. (1965) The complexing power of hydroxamic acids and its effect on behaviour of organic extractants in the reprocessing of irradiated fuels-I. J. Inorg. Nucl. Chem, 27, pp. 1085-1092.
6. Ghosh, K. K. (1997) Kinetic and mechanistic aspects of acid-catalysed hydrolysis of hydroxamic acids. Ind. J. Chem, 36, pp. 1089-1102.
7. Vernon, F. (1982) Chelating ion exchangers - the synthesis and uses of poly(hydroxamic acid) resins. Pure and Applied Chem, 54, pp. 2151-2158.
8. Brandt, W. W. (1960) Analytical applications of hydroxamic acids. Record of Chemical Progress, 21, pp. 159-177.
9. Renshaw, J. C., Robson, G. D., Trinci, A. P. J., Wiebe, M. G., Livens, F. R., Collison, D. and Taylor, R. J. (2002) Fungal siderophores: Structures, functions and applications. Mycol. Res, 106, pp. 1123-1142.
10. Maggio, F., Romano, V. and Cefalu, R. (1966) A study of the nature and stability of the system uranyl-benzohydroxamic acid in acid medium. J. Inorg. Nucl. Chem, 28, pp. 1979-1984.
11. Sinkov, S. I. and Choppin, G. R. (2002) Acetohydroxamic Acid Complexes with Trivalent f-Block Metal Cations. J. Nucl. Sci. Tech, pp. 359-362.
12. 3 by hydroxamate and carboxylate ligands. J. Nucl. Sci. Tech, pp. 251-254.
13. Brainard, J. R., Strietelmeier, B. A., Smith, P. H., Langston-Unkefer, P. J., Barr, M. E. and Ryan, R. R. (1992) Actinide binding and solubilization by microbial siderophores. Radiochim. Acta, 5859, pp. 357-363.
14. John, S. G., Ruggerio, C. E., Hersman, L. E., Tung, C. -S. and Neu, M. P. (2001) Siderophore mediated plutonium accumulation by Microbacterium flavescens (JG-9). Environ. Sci. Technol, 35, pp. 2942-2948.
15. Renshaw, J. C., Halliday, V., Robson, G. D., Trinci, A. P. J., Wiebe, M. G., Livens, F. R., Collison, D. and Taylor, R. J. (2003) Development and application of an assay for uranyl complexation by fungal metabolites, including siderophores. Appl. Environ. Microbiol, 69, pp. 3600-3606.
16. Dasaradhi, L., Stark, P. C., Huber, V. J., Smith, P. H., Jarvinen, G. D. and Gopalan, A. S. (1997) 4-tert-butylcalix[4]arene tetrahydroxamate chelators for the selective extraction of actinide ions: Synthesis and preliminary metal ion extraction studies. J. Chem. Soc. Perkin Trans, 2, pp. 1187-1192.
17. 238Pu(IV) from mice by polycatecholate, -hydroxamate or -hydroxypyridinonate ligands. Radiation Protection Dosimetry, 26, pp. 351-358.
18. Cao, S., Dworschak, H. and Hall, A. (1973) Experiences of the hot reprocessing campaign of irradiated MTR fuel elements with an amine flowsheet at the Eurex plant Saluggia, Italy. Comitato Nazionale Energia Nucleare, RT/CHI(73)10
19. Cao, S., Dworschak, H. and Hall, A. (1974) Experiences of the hot reprocessing campaign of irradiated MTR fuel elements with an amine flowsheet at the Eurex plant Saluggia. Italy. Chem. Abstr
20. Grossi, G. (1970) Solvent extraction with hydroxamic acids -1. Comitato Nazionale Energia Nucleare, RT/CHI(70)15
21. Mannone, F., Cecille, L. and Landat, D. Neo-tridecano-hydroxamic acid as an extractant of long-lived actinides from Purex-type HAW raffinates. Proc. Int. Solv. Extr. Conf., ISEC '77 Torontopp. 661-668.
22. Fox, O. D., Jones, C. J., Birkett, J. E., Carrott, M. J., Maher, C. J., Roube, C. V. and Taylor, R. J. (2006) Advanced PUREX flowsheets for future Np and Pu fuel cycle demands. Separations for the Nuclear Fuel Cycle in the 21st Century, ACS Symposium Series 933. pp. 89-102. American Chemical Society, Washington, DC
23. Birkett, J. E., Carrott, M. J., Fox, O. D., Jones, C. J., Maher, C. J., Roube, C. V., Taylor, R. J. and Woodhead, D. A. (2007) A progress report on the control of neptunium and plutonium within single cycle solvent extraction flowsheets for advanced fuel cycles. J. Nucl. Sci. Tech, 44, pp. 337-343.
24. Zilberman, B. Ya., Fedorov, Yu. S., Mishin, E. N., Sytnik, L. V., Shmidt, O. V., Kukharev, D. N., Goletsky, N. D., Glekov, R. G., Palenik, Yu. V. and Sukhareva, S. Yu. (2002) Superpurex as a TBP-compatible process for recovery and partitioning of long lived radionuclides from NPP spent fuel. Proceedings of the International Symposium NUCEF 2001-Scientific Basis for Criticality Safety, Separation Process and Waste Disposal, pp. 189-196. Tokai-Mura
25. Todd, T. A. and Wigelund, R. A. (2006) Advanced separation technologies for processing spent nuclear fuel and the potential benefits to a geologic repository. Separations for the Nuclear Fuel Cycle in the 21st Century, ACS Symposium Series 933. pp. 41-56. American Chemical Society, Washington, DC
26. Taylor, R. J., May, I., Wallwork, A. L., Denniss, I. S., Hill, N. J., Galkin, B. Ya, Zilberman, B. Ya and Fedorov, Yu. S. (1998) The applications of formo- and aceto-hydroxamic acids in nuclear fuel reprocessing. J. Alloys Cpds, 271, pp. 534-537.
27. Colston, B. J., Choppin, G. R. and Taylor, R. J. (2000) A preliminary study of the reduction of Np(VI) by formohydroxamic acid using stopped-flow near-infrared spectrophotometry. Radiochimica Acta, 88, pp. 329-334.
28. Chung, D. Y. and Lee, E. H. (2006) The reduction of Np(VI) by acetohydroxamic acid in nitric acid solution. Recent Advances in Actinide Science, pp. 587-589. Royal Society of Chemistry, Cambridge
29. Birkett, J. E., Carrott, M. J., Fox, O. D., Jones, C. J., Maher, C. J., Roube, C. V., Taylor, R. J. and Woodhead, D. A. (2005) Recent developments in the purex process for nuclear fuel reprocessing: Complexant based stripping for uranium - plutonium separation. Chimia, 59, pp. 898-904.
30. May, I., Taylor, R. J., Denniss, I. S., Brown, G., Wallwork, A. L., Hill, N. J., Rawson, J. M. and Less, R. (1998) Neptunium(IV) and Uranium(VI) Complexation by Hydroxamic Acids. J. Alloys Cpds, 275, pp. 769-772.
31. Petrich, G. and Kolarik, Z. The 1981 Purex Distribution Data Index.
32. Rydberg, J., Cox, M., Musikas, C. and Choppin, G. R. (2004) Solvent Extraction Principles and Practice, Marcel Dekker Inc, New York
33. May, I., Taylor, R. J., Brown, G. and Hill, N. J. (1998) Np(IV) distribution between 30% tributyl phosphate in odourless kerosene and nitric acid. Radiochim. Acta, 83, pp. 135-138.
34. Bozhenko, E. I. (1995) KARP-95. Second International Symposium on Knowledge Acquisition, Representation and Processing, p. 10.
35. Leggett, D. J. (1985) Computational Methods for the Determination of Formation Constants, Plenum Press, New York
36. Karraker, D. G., Rudisill, T. S. and Thompson, M. C. Studies of the effect of acetohydroxamic acid on plutonium and neptunium by 30 vol% tributyl phosphate, WSRC-TR-2001-00509.Westinghouse Savannah River Company
37. Jiang, H., Chang, Z. Y., Pan, Y. J. and Zhu, J. M. (2000) Effects of hydroxamic acid ligands on TBP extraction of plutonium. J. Nucl. Radiochem, 22, pp. 1-7.
38. Carrott, M. J., Fox, O. D., LeGurun, G., Jones, C. J., Mason, C., Taylor, R. J., Andrieux, F. and Boxall, C. (2007) Oxidation of simple hydroxamic acids in the presence of plutonium (IV) ions. Radiochimica Acta
39. Andrieux, F. P. L., Boxall, C., May, I. and Taylor, R. J. (2007) The hydrolysis of hydroxamic acid complexants in the presence of non-oxidising metal ions 2: Neptunium (IV) ions. J. Solution. Chem
40. May, I., Taylor, R. J., Denniss, I. S., Wallwork, A. L. and May, I. (1999) Actinide complexation in the Purex process. Czech J. Phys, 49, pp. 597-602.
41. Taylor, R. J., May, I. and Hill, N. J. (2001) The solvent extraction behavior of tetravalent actinides in the presence of simple hydroxamic acids. Solvent Extraction For the 21st Century, Proc. ISEC'99, 2, pp. 1339-1343. Society Chemical Industry, London
42. Birkett, J. E., Carrott, M. J., Fox, O. D., Crooks, G., Jones, C. J., Maher, C. J., Roube, C., Taylor, R. J. and Woodhead, D. (2006) The separation of plutonium from uranium by solvent extraction: Recent developments for advanced fuel cycles reprocessing. Recent Advances in Actinide Science, pp. 491-496. Royal Society of Chemistry, Cambridge
43. Mane, B. S. and Jagdale, M. H. (1977) Kinetics of the acid catalysed hydrolysis of isobutyrohydroxamic acid. J. Ind. Chem. Soc, pp. 615-618.
44. Clark, D. L., Johnson, S. G., Kimura, T. and Krsul, J. R. (2006) Plutonium. The Chemistry of the Actinide and Transactinide Elements, pp. 813-1264. Springer, Dordrecht
45. Dutt, N. K. and Seshadri, T. (1968) Organic reagents used in inorganic analysis - V. Determination of formation constants with several hydroxamic and N-arylhydroxamic acids. J. Inorg. Nucl. Chem, 31, pp. 2153-2157.
46. Caselato, U., Vigato, P. A. and Tamburini, S. (1984) Actinide and lanthanide complexes with bidentate ligands. Crystal structure of methanolbis(N-phenylbenzoyl-hydroxamato)-dioxouraniuum(VI). Inorganica Chimica Acta, 94, pp. 61-63.
47. Butler, R. J. (2000) Lanthanide and actinide complexation by hydroxamates. University of Manchester
48. Andrieux, F., Boxall, C. and Taylor, R. J.
49. Koide, Y., Uchino, M., Shosenji, H. and Yamada, K. (1989) Studies of collectors. X. Complexing ability of amino hydroxamic acid ligands with dioxouranium (VI) in aqueous solution. Bull. Chem. Soc. Jpn, 62, pp. 3714-3715.