Visible light generation of iodine atoms and I-I bonds: Sensitized I - oxidation and I3- photodissociation

Journal of the American Chemical Society

Volumn 131, Issue 44, 2009, Pages 16206-16214

  Gardner, James M ^a   Abrahamsson, Maria ^a   Farnum, Byron H ^a   Meyer, Gerald J ^a  

^a JOHNS HOPKINS UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION BAND; ACETONITRILE SOLUTIONS; ACTIVATED SURFACES; ARRHENIUS ANALYSIS; BIPYRIDINES; CHARGE RECOMBINATIONS; COORDINATION COMPOUNDS; DIFFUSION LIMITED; DISPROPORTIONATIONS; ELECTRON TRANSFER; EXCITED STATE LIFETIMES; EXCITED-STATE DECAY; HOLE TRANSFER; IODINE ATOMS; KINETIC MODELS; LIGAND FIELD; LIGHT EXCITATION; MECHANISTIC STUDIES; METAL-TO-LIGAND CHARGE TRANSFER; MLCT EXCITED STATE; NANOSECOND TRANSIENT ABSORPTION; PHOTOPRODUCTS; PREEXPONENTIAL FACTOR; PRODUCT YIELDS; RADICAL ANIONS; ROOM TEMPERATURE; SECOND ORDERS; STEADY STATE; TEMPERATURE DEPENDENT; TETRABUTYL; VISIBLE LIGHT; VISIBLE LIGHT EXCITATION;

ABSORPTION; ACETONITRILE; ACTIVATION ANALYSIS; ACTIVATION ENERGY; AMMONIUM COMPOUNDS; ATOMS; CHARGE TRANSFER; ELECTRON TRANSITIONS; EXCITED STATES; FREE RADICAL REACTIONS; INDUSTRIAL CHEMICALS; IODINE; ION EXCHANGE; LIGANDS; OXIDATION; PHOTODISSOCIATION; PHOTOLYSIS; QUENCHING; RATE CONSTANTS; SULFUR COMPOUNDS;

QUANTUM THEORY;

IODINE;

ARTICLE; ATOM; CHEMICAL BINDING; ELECTRON TRANSPORT; KINETICS; OXIDATION; PHOTOCHEMISTRY; PHOTOLUMINESCENCE; PHOTOOXIDATION; QUANTUM YIELD; ROOM TEMPERATURE; SURFACE PROPERTY;

EID: 70450208559     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja905021c     Document Type: Article

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