Synthesis of amorphous copoly(thioether sulfone)s with high refractive indices and high Abbe numbers

European Polymer Journal

Volumn 46, Issue 1, 2010, Pages 34-41

  Suzuki, Yasuo ^a   Higashihara, Tomoya ^a   Ando, Shinji ^a   Ueda, Mitsuru ^a  

^a TOKYO INSTITUTE OF TECHNOLOGY   (Japan)

Author keywords

Abbe number; Poly(thioether sulfone); Random copolymer; Refractive index; Thermoplastics

Indexed keywords

ABBE NUMBER; DFT CALCULATION; DITHIOLS; DIVINYL SULFONE; EMPIRICAL DENSITY; GLASS TRANSITION TEMPERATURE; HIGH REFRACTIVE INDEX; POLYADDITION; POLYMER CHAINS; RANDOM COPOLYMER; RANDOM COPOLYMERIZATION; THERMAL STABILITY; THIOETHERS; WAVELENGTH DISPERSION; WEIGHT LOSS;

COPOLYMERIZATION; DIFFERENTIAL SCANNING CALORIMETRY; GLASS TRANSITION; LIGHT MEASUREMENT; LIGHT REFRACTION; ORGANIC POLYMERS; REFRACTIVE INDEX; REFRACTOMETERS; REINFORCED PLASTICS; SULFUR COMPOUNDS; THERMOPLASTICS; VOLTAGE STABILIZING CIRCUITS;

AMORPHOUS FILMS;

EID: 70449640614     PISSN: 00143057     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.eurpolymj.2009.09.006     Document Type: Article

References (19)

1. Ma H., Jen A.K.Y., and Dalton L.R. Polymer-based optical waveguides: materials, processing, and devices. Adv Mater 14 (2002) 1339-1365
2. Pagliaro M., and Ciriminna R.J. New fluorinated functional materials. Mater Chem 15 (2005) 4981-4991
3. Shacklette L.W. Polymers in the light path. Opt Photon News 15 (2004) 22-27
4. Gao C., Yang B., and Shen J. Study on syntheses and properties of 2,2′-mercaptoethylsulfide dimethacrylate transparent homo- and copolymer resins having high refractive index. J Appl Poly Sci 75 (2000) 1474-1479
5. Matsuda T., Funae Y., Yoshida M., Yamamoto T., and Takaya T. Optical material of high refractive index resin composed of sulfur-containing aromatic methacrylates. J Appl Polym Sci 76 (2000) 50-54
6. Kohara T. Development of new cyclic olefin polymers for optical uses. Macromol Symp 101 (1996) 571-579
7. Rubin M.L. Spectacles: past, present, and future. Surv Ophthalmol 30 (1986) 321
8. Morishiri H., and Kobayashi S. Episulfide compound with high refractive index. Jpn Kokai Tokkyo Koho (2005) 325274
9. Morishiri H., and Kobayashi S. Polythiols, transparent polymer compositions containing them, their polymers, their manufacture, their heat-resistant optical materials and lenses with high refractive index. Jpn Kokai Tokkyo Koho (2006) 131724
10. Okada R., Ohkubo T., and Kosaka M. Polythiourethanes for optical products and process for preparation thereof. Eur Pat Appl (1993) EP530757
11. Helmut D. Plastics as optical materials. Angew Chem Int Ed Engl 18 (1979) 49-59
12. Okubo T., Kohmoto S., and Yamamoto M. Optical polymer having a high refractive index and high Abbe number prepared by radical polymerization using 2,5-bis(2-thia-3-butenyl)-1,4-dithiane. JMS Pure Appl Chem A35 (1998) 1819-1834
13. Dislich H. Plastics as optical materials. Angew Chem Int Ed Engl 18 (1979) 49-59
14. Yang C.-J., and Jenekhe S.A. Group contribution to molar refraction and refractive index of conjugated polymers. Chem Mater 7 (1995) 1276-1285
15. Okutsu R., Suzuki Y., Ando S., and Ueda M. Poly(thioether sulfone) with high refractive index, high Abbe number. Macromolecules 41 (2008) 6165
16. Suzuki Y., Higashihara T., Ando S., and Ueda M. Polym J 41 (2009) ASAP. http://www.jstage.jst.go.jp/browse/polymj/-char/en See the website at http://www.jstage.jst.go.jp/browse/polymj/-char/en
17. Gaussian 03, Revision D.02. Wallingford, CT: Gaussian Inc.; 2004.
18. Bicerano J. Prediction of polymer properties (2002), Mercel Dekker Inc., New York, Basel
19. Ordian G. Principles of polymerization. 3rd ed. (1991), John Wiley & Sons, USA