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A typical procedure is as follows: To a solution of 2.62 g (26.2 mmol) methyl methacrylate (filtered over alumina to remove the stabilizer) and 0.91 g (0.54 mmol) of 1 in 6 ml benzene, 21 mg (0.09 mmol) of dibenzoylperoxide were added. When heated to 65 °C, the solution became turbid after 2-3 h and then solidified. Heating was continued for 9-10 h, and then the solvent was removed at 70 °C / 8 mbar. The remaining benzene was extracted with ethyl acetate, and then the solvent was again removed under reduced pressure. The olefin : initiator : solvent ratio was kept constant when the cluster: olefin ratio was varied.
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