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Volumn , Issue 44, 2009, Pages 6741-6743

Hydroruthenation triggered catalytic conversion of dialdehydes and keto aldehydes to lactones

Author keywords

[No Author keywords available]

Indexed keywords

ALDEHYDE DERIVATIVE; LACTONE DERIVATIVE; RUTHENIUM DERIVATIVE;

EID: 70449359491     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b912850f     Document Type: Article
Times cited : (75)

References (33)
  • 4
    • 0003855123 scopus 로고
    • M. A. Ogliaruso, J. F. Wolfe, P. Saul and R. Zvi, John Wiley & Sons, Chichester, For a review on the Tishchenko reaction, see:
    • Synthesis of lactones and lactams, ed., M. A. Ogliaruso, J. F. Wolfe, P. Saul, and, R. Zvi, John Wiley & Sons, Chichester, 1993
    • (1993) Synthesis of Lactones and Lactams, Ed.
  • 29
    • 33645415472 scopus 로고    scopus 로고
    • The reaction of heptanedial gave a mixture of the envisaged 8-membered lactone (7%) and dimeric cyclic esters (13%) In Bosnich's Rh catalyzed lactonization,11 it was proposed that the first event is the oxidative addition of an aldehyde to a rhodium complex to generate an acylrhodium hydride complex. Thus, two reaction mechanisms were proposed starting from the complex: (i) intramolecular acylrhodation and reductive elimination, and (ii) hydrorhodation and reductive elimination For examples of catalytic transformations based on ruthenium enolates, see:
    • T. Doi T. Fukuyama J. Horiguchi T. Okamura I. Ryu Synlett 2006 721
    • (2006) Synlett , pp. 721
    • Doi, T.1    Fukuyama, T.2    Horiguchi, J.3    Okamura, T.4    Ryu, I.5


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.