Facile generation of a strained cyclic vinyl cation by thermal solvolysis of cyclopent-1-enyl-λ3-bromanes

Angewandte Chemie - International Edition

Volumn 48, Issue 47, 2009, Pages 8931-8934

  Miyamoto, Kazunori ^a   Shiro, Motoo ^b   Ochiai, Masahito ^a  

^a UNIVERSITY OF TOKUSHIMA   (Japan)

^b RIGAKU CORPORATION   (Japan)

Author keywords

Bromine; Iodine; Isotope effects; Solvolysis vinyl cations

Indexed keywords

HIGHLY STRAINED; ISOTOPE EFFECTS; ROOM TEMPERATURE; SOLVOLYSIS VINYL CATIONS; UNIMOLECULAR DISSOCIATION; VINYL CATIONS;

BROMINE; CARRIER MOBILITY; DISSOCIATION; INDUSTRIAL CHEMICALS; IODINE; ISOTOPES; SOLVENTS;

POSITIVE IONS;

BROMINATED HYDROCARBON; CATION; CROWN ETHER; SOLVENT;

ARTICLE; CHEMISTRY; CONFORMATION; TEMPERATURE; X RAY CRYSTALLOGRAPHY;

CATIONS; CROWN ETHERS; CRYSTALLOGRAPHY, X-RAY; HYDROCARBONS, BROMINATED; MOLECULAR CONFORMATION; SOLVENTS; TEMPERATURE;

EID: 70449091880     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200903368     Document Type: Article

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