Reducing Ga-H and Ga-C bonds in close proximity to oxidizing peroxo groups: Conflicting properties in single molecules

Chemistry - A European Journal

Volumn 15, Issue 42, 2009, Pages 11298-11306

  Uhl, Werner ^a   Halvagar, Mohammad Reza ^a   Claesener, Michael ^a  

^a UNIVERSITY OF MÜNSTER   (Germany)

Author keywords

Gallium; Hydrides; Lithium; Peroxides

Indexed keywords

CLOSE PROXIMITY; H-BONDS; HYDROXO GROUP; LITHIUM ATOMS; LOW-YIELD; ORGANOGALLIUM; OXYGEN ATOM; PEROXO GROUP; ROOM TEMPERATURE; SINGLE MOLECULE; STRUCTURAL MOTIFS;

ATOMS; DEGRADATION; HYDRIDES; HYDROGEN; HYDROGEN PEROXIDE; LITHIUM; OXIDATION; OXYGEN; SILICON;

GALLIUM;

EID: 70350500729     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200900746     Document Type: Article

References (60)

1. a) J. J. Eisch, Comprehensive Organometallic Chemistry, Vol.1 (Eds.: G. Wilkinson, F. G. A. Stone, W. W. Abel), Pergamon, Oxford, 1982, p. 557;
2. b) P. B. Brindley, The Chemistry of Peroxides (Ed.: S. Patai), Wiley, New York, 1983, p. 807.
3. a) W. M. Cleaver, A. R. Barron, J. Am. Chem. Soc. 1989, 111, 8966-8967;
4. b) M. B. Power, W M. Cleaver, A. W. Apblett, A. R. Barron, J. W. Ziller, Polyhedron 1992, 11, 477-486;
5. c) M. B. Power, J. W. Ziller, A. R. Barron, Organometallics 1993, 12, 4908-4916;
6. d) A. R. Barron, Chem. Soc. Rev. 1993, 22, 93-99;
7. e) Y. A. Alexandrov, N. V. Chikinova, J. Organomet. Chem. 1991, 418, 1-59.
8. W. Uhl, S. Melle, M. Prött, Z. Anorg. Allg. Chem. 2005, 631, 1377-1382.
9. Hydrazides: a) W. Uhl, T. Abel, J. Kösters, F. Rogel, Z. Naturforsch. B 2008, 63, 117-123;
10. b) W Uhl, T. Abel, A. Hepp, S. Grimme, M. Steinmetz, Eur. J. Inorg. Chem. 2008, 543-551;
11. c) W. Uhl, C. H. Emden, W. Massa, J. Organomet. Chem. 2006, 691, 1382-1388;
12. d)W Uhl, A. Vogelpohl, Z. Naturforsch. B 2008, 63, 1149-1154;
13. e) W. Uhl, T. Abel, A. Hepp, T. Nilges, F. Rogel, E. U. Würthwein, N. Ghavtadze, Inorg. Chem. 2009, 48, 752-759;
14. f) W. Uhl, Structure and Bonding (Eds.: H. W Roesky, D. A. Atwood), Springer, Berlin, 2003, pp. 41-66; Hydroxylamides
15. g) N. W. Mitzel, C. Lustig, Angew. Chem. 2001, 113, 4521-4524;
16. Angew. Chem. Int. Ed. 2001, 40, 4390-4392;
17. h) N. W. Mitzel, C. Lustig, M. Woski, Dalton Trans. 2004, 397-401;
18. i) P. Bösing, A. Willner, T. Pape, A. Hepp, N. W. Mitzel, Dalton Trans. 2008, 2549-2556.
19. a)W. Uhl, M. R. Halvagar, Angew. Chem. 2008, 120, 1981-1983;
20. Angew. Chem. Int. Ed. 2008, 47, 1955-1957;
21. see also: b) W. Uhl, M. R. Halvagar, M. Layh, Chem. Commun. 2009, 4269-4271;
22. W. Uhl, B. Jana, Eur. J. Inorg. Chem. 2009, 3942-3947.
23. a) W. Uhl, B. Jana, Chem. Eur. J. 2008, 14, 3067-3071;
24. b) W. Uhl, B. Jana, J. Organomet. Chem. 2009, 694, 1101-1106.
25. a) W. Uhl, T. Spies, Z. Anorg. Allg. Chem. 2000, 626, 1059-1064;
26. b)W Uhl, M. Prött, Z. Anorg. Allg. Chem. 2002, 628, 2259-2263;
27. c) W. Uhl, M. Prött, G. Geiseler, K. Harms, Z. Naturforsch. B 2002, 57, 141-144.
28. a) W. Hiller, M. Layh, W. Uhl, Angew. Chem. 1991, 103, 339-341;
29. Angew. Chem. Int. Ed. Engl. 1991, 30, 324-326;
30. b) W. Uhl, J. E. O. Schnepf, Z. Anorg. Allg. Chem. 1991, 595, 225-238;
31. c) T. Kottke, D. Stalke, Angew. Chem. 1993, 105, 619-621;
32. Angew. Chem. Int. Ed. Engl. 1993, 32, 580-582;
33. d) W. Uhl, Z. Anorg. Allg. Chem. 1989, 570, 37-53;
34. e) W. Uhl, E. Er, O. Hübner, H.-J. Himmel, Z. Anorg. Allg. Chem. 2008, 634, 2133-2139;
35. f) W. Uhl, E. Er, M. Matar, Main Group Chem. 2006, 5, 31-40;
36. g) W. Uhl, E. Er, M. Matar, Z. Anorg. Allg. Chem. 2006, 632, 1011-1017;
37. h) S. R. Boss, M. P. Coles, R. Haigh, P. B. Hitchcock, R. Snaith, A. E. M. Wheatley, Angew. Chem. 2003, 115, 5751-5754;
38. Angew. Chem. Int. Ed. 2003, 42, 5593-5596;
39. i) S. R. Boss, J. M. Cole, R. Haigh, R. Snaith, A. E. M. Wheatley, G. J. McIntyre, P. R. Raithby, Organometallics 2004, 23, 4527-4530.
40. a) J. M. Savariault, M. S. Lehmann, J. Am. Chem. Soc. 1980, 102, 1298-1303;
41. b) S. Samdal, V. S. Mastryukov, J. E. Boggs, J. Mol. Struct. 1995, 346, 35-48, and references therein.
42. a) Y. L. Slovokhotov, T. M. Timofeeva, M. Y. Antipin, Y. T. Steruchkov, J. Mol. Struct. 1984, 112, 127-140;
43. b) A. Y. Kosnikov, V. L. Antonovskii, S. V. Lindeman, M. Y. Antipin, Y. T. Struchkov, N. A. Turovskii, I. P. Zyat'kov, Teoret. Eksper. Khim. 1989, 25, 82-87.
44. a) C. Glidewell, D. C. Liles, D. J. Walton, G. M. Sheldrick, Acta Crystallogr. Sect. B 1979, 35, 500-502;
45. b) D. Königstein, M. Jansen, Monatsh. Chem. 1996, 127, 1221-1227;
46. c) A. G. DiPasquale, W. Kaminsky, J. M. Mayer, J. Am. Chem. Soc. 2002, 124, 14534-14535;
47. d) F. A. Chavez, J. A. Briones, M. M. Olmstead, P. K. Mascharak, Inorg. Chem. 1999, 38, 1603-1608;
48. e) H. Mimoun, R. Charpentier, A. Mitschler, J. Fischer, R. Weiss, J. Am. Chem. Soc. 1980, 102, 1047-1054.
49. T. Steiner, Angew. Chem. 2002, 114, 50-80;
50. Angew. Chem. Int. Ed. 2002, 41, 48-76.
51. G. Boche, K. Möbus, K. Harms, J. C. W. Lohrenz, M. Marsch, Chem. Eur. J. 1996, 2, 604-607.
52. a) W. Uhl, Coord. Chem. Rev. 2008, 252, 1540-1563;
53. b) W. Uhl, M. Claesener, Inorg. Chem. 2008, 47, 4463-4470;
54. c) W. Uhl, M. Claesener, Inorg. Chem. 2008, 47, 729-735;
55. d) W. Uhl, M. Claesener, S. Haddadpour, B. Jasper, I. Tiesmeyer, S. Zemke, Z. Anorg. Allg. Chem. 2008, 634, 2889-2896;
56. e) W. Uhl, H. R. Bock, M. Claesener, M. Layh, I. Tiesmeyer, E.-U. Würthwein, Chem. Eur. J. 2008, 14, 11557-11564.
57. P. J. Davidson, D. H. Harris, M.F. Lappert, J. Chem. Soc. Dalton Trans. 1976, 2268-2274.
58. A. E. Shirk, D. F. Shriver, Inorg. Synth. 1977, 17, 45-47.
59. SHELXTL-Plus, REL. 4.1, Siemens Analytical X-RAY Instruments Inc., Madison, 1990;
60. SHELXL-97, Program for the Refinement of Structures, G. M. Sheldrick, University of Göttingen, Göttingen, 1997.