Substitution reactions between bis-chelate ligands in palladium(ii) alkenyl complexes: An unusual way to form unstable trans-P complexes. A study on the isomerization mechanism

Dalton Transactions

Volumn , Issue 43, 2009, Pages 9475-9485

  Canovese, Luciano ^a   Visentin, Fabiano ^a   Chessa, Gavino ^a   Santo, Claudio ^a   Dolmella, Alessandro ^b  

^a CA' FOSCARI UNIVERSITY OF VENICE   (Italy)

^b UNIVERSITY OF PADOVA   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENYL; ALKENYL COMPLEXES; CHELATE LIGANDS; CHLORO DERIVATIVES; GEOMETRICAL FORMS; GEOMETRICAL ISOMERS; INTERCONVERSION PROCESS; LEAVING GROUPS; LOW TEMPERATURES; P-DERIVATIVE; STRUCTURE DETERMINATION; THEORETICAL CALCULATIONS; THERMODYNAMICALLY STABLE; TRANS INFLUENCE;

CHELATION; ISOMERS; LIGANDS; PALLADIUM; PHOSPHORUS COMPOUNDS; PYRIDINE; RUBIDIUM; STEREOSELECTIVITY; SUBSTITUTION REACTIONS;

PALLADIUM COMPOUNDS;

ALKENE; CHELATING AGENT; LIGAND; ORGANOMETALLIC COMPOUND; PALLADIUM;

ARTICLE; CHEMISTRY; KINETICS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; QUANTUM THEORY; STEREOISOMERISM; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

ALKENES; CHELATING AGENTS; CRYSTALLOGRAPHY, X-RAY; KINETICS; LIGANDS; MAGNETIC RESONANCE SPECTROSCOPY; ORGANOMETALLIC COMPOUNDS; PALLADIUM; QUANTUM THEORY; STEREOISOMERISM;

EID: 70350423915     PISSN: 14779226     EISSN: 14779234     Source Type: Journal    
DOI: 10.1039/b910952h     Document Type: Article

References (47)

1. F. R. Hartley, in The Chemistry of Platinum and Palladium, Applied Science, London, 1973, ch. 11
2. R. G. Wilkins, in Kinetics and Mechanism of Reaction of Transition Metal Complexes, Wiley-VCH, New York, 1991, ch. 4
3. J. D. Atwood, in Inorganic and Organometallic Reaction Mechanisms, Wiley-VCH, New York, 1997, ch. 2
4. R. B. Jordan, in Reaction Mechanisms of Inorganic and Organometallic Systems, University Press, Oxford, 1998, ch. 3 and 4
5. M. L. Tobe and J. Burgess, in Inorganic Reaction Mechanisms, Addison-Wesley, New York, 1999, ch. 3
6. Z. Ciunik J. A. Wolny M. F. Rudolf S. Wolowiec J. Chem. Soc., Dalton Trans. 2002 885 895
7. V. W.-W. Yam X.-X. Lu C.-C. Ko Angew. Chem., Int. Ed. 2003 42 3385 3388
8. X.-X. Lu H.-S. Tang C.-C. Ko J. K.-Y. Wong N. Zhu V. W.-W. Yam Chem. Commun. 2005 1572 1574
9. D. Hanekom J. M. McKenzie N. M. Derix K. R. Koch Chem. Commun. 2005 767 769
10. J. Vicente A. Arcas M. D. Gálvez-López P. Jones Organometallics 2006 25 4247 4259
11. H. V. Huynh T. C. Neo G. K. Tan Organometallics 2006 25 1298 1302
12. H. V. Huynh Y. Han J. H. H. Ho G. K. Tan Organometallics 2006 25 3267 3274
13. C. Y. Liao K.-T. Chan J.-Y. Zeng C.-H. Hu C.-Y. Tu H. M. Lee Organometallics 2007 26 1692 1702
14. C. Y. Liao K. T. Chan Y. C. Chang C. Y. Chen C. Y. Tu C. H. Hu H. M. Lee Organometallics 2007 26 5826 5833
15. P. H. P. Brinkmann G. A Luinstra J. Organomet. Chem. 1999 572 193 205
16. K. J. Cavell Coord. Chem. Rev. 1996 155 209 243
17. M. Sperrle A. Aeby G. Consiglio A. Pfaltz Helv. Chim. Acta 1996 79 1387 1392
18. P. Sennhenn B. Gabler G. Helmchen Tetrahedron Lett. 1994 35 8595 8598
19. A. Togni U. Burckhardt V. Gramlich P. S. Saltzmann J. Am. Chem. Soc. 1996 118 1031 1037
20. L. Canovese F. Visentin G. Chessa submitted to Inorganic Syntheses 2008
21. G. P. C. M. Dekker A. Buijs C. J. Elsevier K. Vrieze P. W. N. M. van Leewuen W. J. J. Smeets A. L. Spek Y. F. Wang C. H. Stam Organometallics 1992 11 1937 1948
22. W. de Graaf S. Harder J. Boersma G. van Koten J. A. Canters J. Organomet. Chem. 1988 358 545 562
23. T. G. Appleton M. A. Bennett I. B. Tomkins J. Chem. Soc., Dalton Trans. 1976 439 44
24. H. A. Ankersmit B. H. Løken B. H. Kooijman A. L. Spek K. Eriksen K. Vriese G. van Koten Inorg. Chim. Acta 1996 252 141 155
25. H. A. Ankersmit N. Veldman A. L. Spek K. Eriksen K. Goubitz K. Vriese G. van Koten Inorg. Chim. Acta 1996 252 203 219
26. L. Canovese F. Visentin G. Chessa P. Uguagliati G. Bandoli Organometallics 2000 19 1461 1463
27. L. Canovese F. Visentin G. Chessa C. Santo P. Uguagliati G. Bandoli J. Organomet. Chem. 2002 650 43 56
28. E. Shirakawa H. Yoshida H. Takaya Tetrahedron Lett. 1997 38 3759 3762
29. J. H. Espenson, in Chemical Kinetics and Reaction Mechanisms, McGraw Hill, Singapore, 2nd int. edn, 1995, ch. 2
30. L. Canovese F. Visentin C. Levi C. Santo J. Organomet. Chem. 2008 693 3324 3330
31. P. D. Braddock R. Romeo M. L. Tobe Inorg. Chem. 1974 13 1170 1175
32. G. te Velde F. M. Bickelhaupt S. J. A. van Gisbergen C. Fonseca Guerra E. J. Baerends J. G. Snijders T. Ziegler Chemistry with ADF J. Comput. Chem. 2001 22 931 967
33. C. Fonseca Guerra J. G. Snijders G. te Velde E. J. Baerends Theor. Chem. Acc. 1998 99 391 403
34. ADF2007.01, SCM, Theoretical Chemistry, Vrije Universiteit, Amsterdam, The Netherlands, http://www.scm.com
35. A. D. Becke Phys. Rev. A: At., Mol., Opt. Phys. 1988 38 3098 3100
36. C. Lee W. Yang R. G. Parr Phys. Rev. B: Condens. Matter Mater. Phys. 1988 37 785 789
37. E. Van Lenthe E. J. Baerends J. G. Snijders J. Chem. Phys. 1994 101 9783 9792
38. C.K. Johnson, ORTEP, Report ORNL-5138, Oak Ridge National Laboratory, Oak Ridge, TN, 1976
39. L. Canovese F. Visentin G. Chessa P. Uguagliati C. Santo A. Dolmella Organometallics 2005 24 3297 3308
40. L. Canovese G. Chessa C. Santo F. Visentin P. Uguagliati Inorg. Chim. Acta 2003 46 158 168
41. F. R. Hartley Chem. Soc. Rev. 1973 2 163 179
42. D. A Redfield J. H. Nelson J. Am. Chem. Soc. 1974 96 6219 6220
43. A. Gillie K. J. Stille J. Am. Chem. Soc. 1980 102 4933 4941
44. G. Alibrandi L. Monsù Scolaro R. Romeo Inorg. Chem. 1991 30 4007 4013
45. D. Minniti Inorg. Chem. 1994 33 2631 2634
46. J. G. P. Delis P. G. Aubel K. Vrieze P. W. N. M. van Leeuwen N. Veldman A. L. Spek F. J. R. van Neer Organometallics 1997 16 2948 2957
47. P. Wehman H. M. A. van Donge A. Hagos P.C. Kamer J. Organomet. Chem. 1997 535 183 193