Niobium alcoholate clusters with an octahedral arrangement of metal atoms: [K(CH3OH)4]2 [Nb6(OCH 3)18] and [Na([18]crown-6)-(C2H 5OH)2]2 [Nb6(OC2H 5)12(NCS)6

Angewandte Chemie - International Edition

Volumn 48, Issue 14, 2009, Pages 2605-2608

  Flemming, Anke ^a   Köckerling, Martin ^a  

^a UNIVERSITY OF ROSTOCK   (Germany)

Author keywords

Alcoholates; Cluster compounds; Niobium; Structure elucidation

Indexed keywords

18-CROWN-6; ALCOHOLATE; ALCOHOLATES; CLUSTER COMPOUNDS; COMPLETE EXCHANGE; ELEVATED TEMPERATURE; METAL ATOMS; STRUCTURE ELUCIDATION;

ATOMS; NIOBIUM; SODIUM;

NIOBIUM COMPOUNDS;

EID: 70349912036     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200805166     Document Type: Article

References (79)

1. A. Simon, Angew. Chem. 1988, 100, 163-188;
2. Angew. Chem. Int. Ed. Engl. 1988, 27, 159-183;
3. b) Metal Clusters in Chemistry (Eds.: P. Braunstein, L. A. Oro, P.R. Raithly), Wiley-VCH, Weinheim, 1999;
4. c) N. Prokopuk, D. F. Shriver, Adv. Inorg. Chem. 1999, 46, 1-49;
5. d) C. Perrin, M. Sergent, Eur. J. Solid State Inorg. Chem. 1991, 28, 933-948;
6. e) A. Simon in Clusters and Colloids - From Theory to Applications (Ed.: G. Schmid), VCH, Weinheim, 1994, pp. 373-458;
7. f) J. D. Corbett in Modern Perspectives in Inorganic Crystal Chemistry, (Ed.: E. Parthe), Kluwer, Dortrecht, 1992, pp. 27-56;
8. g) J. D. Corbett, J. Chem. Soc. Dalton Trans. 1996, 575-587;
9. h) J. D. Corbett, Inorg. Chem. 2000, 39, 5178-5191;
10. i) F. A. Cotton, J. Chem. Soc. Dalton Trans. 2000, 1961-1968;
11. j) T. Hughbanks, J. Alloys Compd. 1995, 229, 40-53;
12. k) C. Perrin, S. Cordier, S. Ihmaïne, M. Sergent, J. Alloys Compd. 1995, 229, 123-133;
13. l) A. Simon, H.-J. Mattausch, G. J. Miller, W. Bauhofer, R. K. Kremer in Handbook on the Physics and Chemistry of Rare Earth, Vol. 15 (Eds.: K. A. Gschneider, L. Eyring), Elsevier Science, Amsterdam, 1991, pp. 191-285;
14. m) G. Meyer, Chem. Rev. 1988, 88, 93-107;
15. n) T. G. Gray, Coord. Chem. Rev. 2003, 243, 213-235.
16. S. C. Lee, R. H. Holm, Angew. Chem. 1990, 102, 868-885;
17. Angew. Chem. Int. Ed. Engl. 1990, 29, 840-856;
18. b) J. R. Long, L. S. McCarty, R. H. Holm, J. Am. Chem. Soc. 1996, 118, 4603-4616;
19. c) J. R. Long, A. S. Williamson, R. H. Holm, Angew. Chem. 1995, 107, 248-251;
20. Angew. Chem. Int. Ed. Engl. 1995, 34, 226-229;
21. d) O. M. Yaghi, M. J. Scott, R. H. Holm, Inorg. Chem. 1992, 31, 4778-4784;
22. e) X. Xie, J. N. Jones, T. Hughbanks, Inorg. Chem. 2001, 40, 522-527;
23. f) C. E. Runyan, Jr., T. Hughbanks, J. Am. Chem. Soc. 1994, 116, 7909-7910.
24. H. Schafer, H. G. von Schnering, Angew. Chem. 1964, 76, 833-868.
25. B. Yan, H. Zhou, A. Lachgar, Inorg. Chem. 2003, 42, 8818-8822;
26. b) N. G. Naumov, S. Cordier, C. Perrin, Angew. Chem. 2002, 114, 3128-3130;
27. Angew. Chem. Int. Ed. 2002, 41, 3002-3004;
28. c) N. G. Naumov, S. Cordier, F. Gulo, T. Roisnel, V. E. Fedorov, C. Perrin, Inorg. Chim. Acta 2003, 350, 503-510.
29. A. Flemming, A. Bernsdorf, M. Köckerling, J. Clust. Sci., DOI: 10.1007/s10876-008-0217-2;
30. b) N. G. Naumov, S. Cordier, C. Perrin, Solid State Sci. 2003, 5, 1359-1367.
31. N. G. Naumov, S. Cordier, C. Perrin, Chem. Commun. 2004, 1126-1127;
32. b) O. Reckeweg, H.-J. Meyer, Z. Anorg. Allg. Chem. 1996, 622, 411-416.
33. H.-J. Meyer, Z. Anorg. Allg. Chem. 1995, 621, 921-924;
34. b) O. Reckeweg, H.-J. Meyer, Z. Naturforsch. B 1995, 50, 1377-1381;
35. c) O. Reckeweg, H.-J. Meyer, A. Simon, Z. Anorg. Allg. Chem. 2002, 628, 920-922.
36. A. Simon, H. G. von Schnering, H. Schäfer, Z. Anorg. Allg. Chem. 1968, 361, 235-248;
37. b) P. B. Fleming, L. A. Müller, R. E. McCarley, Inorg. Chem. 1967, 6, 1-4;
38. c) A. Broil, D. Juza, H. Schafer, Z. Anorg. Allg. Chem. 1971, 382, 69-79;
39. d) A. Broil, H. Schafer, J. Less-Common Met. 1970, 22, 367-368;
40. e) C. Perrin, M. Sergent, Eur. I Solid State Inorg. Chem. 1991, 28, 933-948;
41. f) S. Ihmaïne, C. Perrin, O. Peña, M. Sergent, J. Less-Common Met. 1988, 137, 323-332;
42. g) O. Peña, S. Ihmaïne, C. Perrin, M. Sergent, Solid State Commun. 1990, 74, 285-290;
43. h) S. Ihmaïne, C. Perrin, O. Peña, M. Sergent, Physica B 1990, 163, 615-617;
44. i) C. Perrin, S. Cordier, S. Ihmaïne, M. Sergent, J. Alloys Compd. 1995, 229, 123-133;
45. j) S. Ihmaïne, C. Perrin, M. Sergent, Acta Crystallogr. Sect. C 1987, 43, 813-816;
46. k) S. Ihmaïne, C. Perrin, M. Sergent, Acta Crystallogr. Sect. C 1989, 45, 705-707;
47. l) T. Duraisamy, J. S. Quails, A. Lachgar, J. Solid State Chem. 2003, 170, 227-231;
48. m) A. Nägele, E. Anokhina, J. Sitar, H.-J. Meyer, A. Lachgar, Z. Naturforsch. B 2000, 55, 139-144.
49. A. Flemming, M. Köckerling, Z. Anorg. Allg. Chem. 2008, 634, 2309-2315.
50. M. Vojnovic, N. Brničević, I. Bašic, R. Trojko, M. Miljak, I. D. Desnica-Frankovic, Mater. Res. Bull. 2001, 36, 211-225;
51. b) H. Schäfer, B. Plautz, H. Plautz, Z. Anorg. Allg. Chem. 1972, 392, 10-22;
52. c) F. W. Koknat, J. A. Parsons, A. Vongvusharintra, Inorg. Chem. 1974, 13, 1699-1702.
53. U. Beck, A. Simon, N. Brničević, S. širac, Croat. Chem. Acta 1995, 68, 837-848;
54. b) N. Brničević, F. Muštović, R. E. McCarley, Inorg. Chem. 1988, 27, 4532-4535;
55. c) L. F. Piedra-Garza, M. Kockerling, Inorg. Chem. 2006, 45, 8829-8831;
56. d) B. Spreck-elmeyer, H. Schafer, J. Less-Common Met. 1966, II, 74-75;
57. e) I. Bašic, N. Brničević, U. Beck, A. Simon, R. E. McCarley, Z. Anorg. Allg. Chem. 1998, 624, 725-732.
58. J. Köhler, G. Svensson, A. Simon, Angew. Chem. 1992, 104, 1463-1483;
59. Angew. Chem. Int. Ed. Engl. 1992, 31, 1437-1456;
60. b) G. Svensson, J. Köhler, A. Simon in Metal Clusters in Chemistry (Eds.: P. Braunstein, L. A. Oro, P.R. Raithly), Wiley-VCH, Weinheim, 1999, pp. 1509-1550, and references therein.
61. To date, the only example of a M6 cluster compound with an octahedral metal atom framework, which bears exclusively methanolato ligands is of the [M6XJ type with M = molybdenum: a) P. Nannelli, B. P. Block, Inorg. Chem. 1968, 7, 2423-2426;
62. b) M. H. Chisholm, J. A. Heppert, J. C. Huffman, Polyhedron 1984, 3, 475-478.
63. 3, Z=4, R1=0.0507 (I>2σ(I)), wR2 = 0.1634 (all data), 5842 symmetry independent reflections, 265 parameter. CCDC 697148 (1) and CCDC 697149 (2) contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data-request/cif.
64. J. B. Willems, H. W. Rohm, C. Geers, M. Köckerling, Inorg. Chem. 2007, 46, 6197-6203.
65. B. O. Marinder, Chem. Scr. 1977, 11, 97-101;
66. b) R. Burnus, J. Köhler, A. Simon, Z. Naturforsch, B 1987, 42, 536-538.
67. S. Cordier, K. Kirakci, B. Fontaine, J.-F. Halet, R. Gautier, C. Perrin, Inorg. Chem. 2006, 45, 883-893.
68. F. W. Koknat, R. E. McCarley, Inorg. Chem. 1972, 11, 812-816.
69. J. D. Corbett, J. Solid State Chem. 1981, 39, 56-74.
70. E. Anokhina, A. Lachgar in Inorganic Chemistry in Focus III (Hrsg.: G. Meyer, D. Naumann, L. Wesemann), Wiley-VCH, Weinheim, 2006, pp. 79-104;
71. b) C. Perrin in Metal Clusters in Chemistry (Eds.: P. Braunstein, L. A. Oro, P. R. Raithby), Wiley-VCH, Weinheim 1999, pp. 1563-1590, and references therein.
72. E. V. Anokhina, M. W. Essig, A. Lachgar, Angew. Chem. 1998, 110, 538-540;
73. Angew. Chem. Int. Ed. 1998, 37, 522-525.
74. Z. Lin, I. A. Williams, Polyhedron 1996, 15, 3277-3287;
75. b) F. Ogliaro, S. Cordier, J.-F. Halet, C. Perrin, J.-Y Saillard, M. Sergent, Inorg. Chem. 1998, 37, 6199-6207;
76. c) T. Hughbanks, Prog. Solid State Chem. 1989, 19, 329-372, and references therein.
77. F. Rogel, J. D. Corbett, J. Am. Chem. Soc. 1990, 112, 8198-8200;
78. b) F. Rogel, Ph.D. Thesis, Iowa State University, Ames, IA 1990.
79. G. M. Sheldrick, ShelxS-97 and ShelxL-97, Programs for the Solution and Refinement of Crystal Structures, University of Göttingen, 1997.