Access to a novel niobium octahedral cluster core via soft chemistry: Synthesis and structure of K2.6Cs3.4[Nb6Cl 4O4(OH)4(CN)6]·3H 2O containing isolated Nb6Cl4iO 4i(OH)4i(CN)6 a cluster unit

Inorganica Chimica Acta

Volumn 350, Issue , 2003, Pages 503-510

  Naumov, Nikolai G ^b   Cordier, Stéphane ^a   Gulo, Fakhili ^a,c   Roisnel, Thierry ^a   Fedorov, Vladimir E ^b   Perrin, Christiane ^a  

^a Laboratoire de Chimie du Solide et Inorganique Moleculaire de Rennes   (France)

^b NIKOLAEV INSTITUTE OF INORGANIC CHEMISTRY   (Russian Federation)

^c SRIWIJAYA UNIVERSITY   (Indonesia)

Author keywords

Cluster; CN ligand; Crystal structures; Hydroxyl group; Niobium; Oxychloride; Single crystal X ray diffraction; Soft chemistry

Indexed keywords

CHROMIUM COMPOUNDS; CRYSTAL ATOMIC STRUCTURE; CRYSTAL STRUCTURE; CYANIDES; ELECTRONIC PROPERTIES; LIGANDS; NIOBIUM; SINGLE CRYSTALS; TITANIUM COMPOUNDS; X RAY DIFFRACTION;

CLUSTER; CN-LIGAND; HYDROXYL GROUPS; OXYCHLORIDES; SINGLE CRYSTAL X-RAY DIFFRACTION; SOFT CHEMISTRY;

CHLORINE COMPOUNDS;

CHLORINE DERIVATIVE; HYDROXYL GROUP; LIGAND; NIOBIUM; OXIDE; OXYGEN; POTASSIUM CYANIDE;

AQUEOUS SOLUTION; ARTICLE; CHEMICAL INTERACTION; CRYSTAL STRUCTURE; ROOM TEMPERATURE; STRUCTURE ANALYSIS; SYNTHESIS; X RAY DIFFRACTION;

EID: 0142155730     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0020-1693(02)01506-2     Document Type: Article

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