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48
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70349962693
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There is only one reported example with an aryl triflate (Ref. [13]). In fact, no examples of the use of aryl halides and aryl titanium reagents in palladium-catalyzed Ar-Ar′ coupling reactions have been reported so far
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There is only one reported example with an aryl triflate (Ref. [13]). In fact, no examples of the use of aryl halides and aryl titanium reagents in palladium-catalyzed Ar-Ar′ coupling reactions have been reported so far.
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49
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For our recent study on aminophosphanes based on an indolyl scaffold
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For our recent study on aminophosphanes based on an indolyl scaffold, see C. M. So, C. P. Lau, F. Y. Kwong, Org. Lett. 2007, 9, 2795.
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62149098076
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For our related indolylphosphane
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For our related indolylphosphane, see C. M. So, C. C. Yeung, C. P. Lau, F. Y. Kwong, J. Org. Chem. 2008, 73, 7803
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Pd black was observed after heating the reaction for about 10 minutes
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Pd black was observed after heating the reaction for about 10 minutes.
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3P ligand resulted in 29% conversion of ArCl and a 26% yield of the desired product (GC yield)
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3P ligand resulted in 29% conversion of ArCl and a 26% yield of the desired product (GC yield).
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