Relating mechanical properties and chemical bonding in an inorganic-organic framework material: A single-crystal nanoindentation study

Journal of the American Chemical Society

Volumn 131, Issue 40, 2009, Pages 14252-14254

  Jin, Chong Tan ^a   Furman, Joshua D ^a,b   Cheetham, Anthony K ^a  

^a UNIVERSITY OF CAMBRIDGE   (United Kingdom)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BASIC BUILDING BLOCK; BRIDGING LIGANDS; BUILDING BLOCKES; CHEMICAL BONDINGS; CRYSTALLOGRAPHIC ORIENTATIONS; HYBRID FRAMEWORK; INORGANIC METALS; INORGANIC-ORGANIC; MECHANICAL RESPONSE; METAL CENTERS; MIXED-LIGANDS; ORTHORHOMBIC SPACE GROUPS;

ATOMIC FORCE MICROSCOPY; CERIUM; CERIUM COMPOUNDS; CHEMICAL BONDS; CRYSTAL ORIENTATION; HARDNESS; HYBRID MATERIALS; LIGANDS; NANOINDENTATION; OXYGEN; RIGIDITY; SINGLE CRYSTALS; STIFFNESS;

MECHANICAL PROPERTIES;

CERIUM; CERIUM OXALATE; FORMIC ACID; UNCLASSIFIED DRUG;

ANISOTROPY; ARTICLE; ATOMIC FORCE MICROSCOPY; CHEMICAL BINDING; CHEMICAL STRUCTURE; CRYSTAL STRUCTURE; CRYSTALLOGRAPHY; TRANSMISSION ELECTRON MICROSCOPY;

EID: 70349903171     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9060307     Document Type: Article

References (33)

1. (a) Cheetham, A. K.; Rao, C. N. R.; Feller, R. K. Chem. Commun. 2006, 4780-4795.
2. (b) Rao, C. N. R.; Cheetham, A. K.; Thirumurugan, A. J. Phys. Condens. Matter. 2008, 20, 083202.
3. (c) Kurmoo, M. Chem. Soc. Rev. 2009, 38, 1353-1379.
4. (d) Allendorf, M. D.; Bauer, C. A.; Bhakta, R. K.; Houk, R. J. T. Chem. Soc. Rev. 2009, 38, 1330-1352.
5. (e) Jain, P.; Dalal, N. S.; Toby, B. H.; Kroto, H. W.; Cheetham, A. K. J. Am. Chem. Soc. 2008, 130, 10450-10451.
6. (a) Férey, G. Chem. Soc. Rev. 2008, 37, 191-214.
7. (b) Kitagawa, S.; Kitaura, R.; Noro, S. Angew. Chem., Int. Ed. 2004, 43, 2334-2375.
8. (c) Czaja, A. U.; Trukhan, N.; Muller, U. Chem. Soc. Rev. 2009, 38, 1284-1293.
9. (d) Banerjee, R.; Phan, A.; Wang, B.; Knobler, C.; Furukawa, H.; O'Keeffe, M.; Yaghi, O. M. Science 2008, 319, 939-943.
10. (e) Rosseinsky, M. J. Microporous Mesoporous Mater. 2004, 73, 15-30.
11. (f) Murray, L. J.; Dinca, M.; Long, J. R. Chem. Soc. Rev. 2009, 38, 1294-1314.
12. Cheetham, A. K.; Rao, C. N. R. Science 2007, 318, 58-59.
13. (a) Spencer, E. C.; Angel, R. J.; Ross, N. L.; Hanson, B. E.; Howard, J. A. K. J. Am. Chem. Soc. 2009, 131, 4022-4026.
14. (b) Chapman, K. W.; Halder, G. J.; Chupas, P. J. J. Am. Chem. Soc. 2008, 130, 10524-10526.
15. (c) Allendorf, M. D.; Houk, R. J. T.; Andruszkiewicz, L.; Talin, A. A.; Pikarsky, J.; Choudhury, A.; Gall, K. A.; Hesketh, P. J. J. Am. Chem. Soc. 2008, 130, 14404-14405.
16. (d) Bahr, D. F.; Reid, J. A.; Mook, W. M.; Bauer, C. A.; Stumpf, R.; Skulan, A. J.; Moody, N. R.; Simmons, B. A.; Shindel, M. M.; Allendorf, M. D. Phys. Rev. B 2007, 76, 184106.
17. Tan, J. C.; Orton, J. B.; Merrill, C. A.; Cheetham, A. K. Acta Mater. 2009, 57, 3481-3496.
18. (a) Kearney, C.; Zhao, Z.; Bruet, B. J. F.; Radovitzky, R.; Boyce, M. C.; Ortiz, C. Phys. Rev. Lett. 2006, 96, 255505.
19. (b) Lethbridge, Z. A. D.; Williams, J. J.; Walton, R. I.; Smith, C. W.; Hooper, R. M.; Evans, K. E. Acta Mater. 2006, 54, 2533-2545.
20. (c) Reddy, C. M.; Gundakaram, R. C.; Basavoju, S.; Kirchner, M. T.; Padmanabhan, K. A.; Desiraju, G. R. Chem. Commun. 2005, 3945-3947.
21. (d) Viswanath, B.; Raghavan, R.; Ramamurty, U.; Ravishankar, N. Scripta Mater. 2007, 57, 361-364.
22. Full details can be found in the Supporting Information.
23. Romero, S.; Mosset, A.; Trombe, J. C. J. Solid State Chem. 1996, 127, 256-266.
24. Rao, C. N. R.; Natarajan, S.; Vaidhyanathan, R. Angew. Chem., Int. Ed. 2004, 43, 1466-1496.
25. (a) Oliver, W. C.; Pharr, G. M. J. Mater. Res. 2004, 19, 3-20.
26. (b) Oliver, W. C.; Pharr, G. M. J. Mater. Res. 1992, 7, 1564-1583.
27. Swain, M. V. Mater. Sci. Eng., A 1998, 253, 160-166.
28. Tabor, D. Philos. Mag. A 1996, 74, 1207-1212.
29. Lloyd, S. J.; Castellero, A.; Giuliani, F.; Long, Y.; McLaughlin, K. K.; Molina-Aldareguia, J. M.; Stelmashenko, N. A.; Vandeperre, L. J.; Clegg, W. J. Proc. R. Soc. Edinburgh, Sect. A: Math. 2005, 461, 2521-2543.
30. Hebbache, M. Solid State Commun. 2000, 113, 427-432.
31. (a) Robson, R. J. Chem. Soc., Dalton Trans. 2000, 3735-3744.
32. (b) Robson, R. Dalton Trans. 2008, 5113-5131.
33. (c) Yaghi, O. M.; O'Keeffe, M.; Ockwig, N. W.; Chae, H. K.; Eddaoudi, M.; Kim, J. Nature 2003, 423, 705-714.