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24144441333
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II, see:
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II, see:
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70349954595
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Crystal data for 2: C43Hs8N2PtSi 2, Mr, 854.18 gmol-1, yellow plates, 0.22 × 0.16 × 0.14 mm3, monoclinic space group Pljn, a, 21.252(7, b, 20.315(7, c, 21.422(7) Å, ß, 118.80(2)°, V= 8104(5) Å3, Z, 8, p caled, 1.40gcιrΓ3, F(000, 2236, T= 120(2) K, Rl, 0.0484, wR2, 0.1268, 13329 independent reflections (2θ, 48.8°) and 12018 parameters. The data were collected with an MAR345 image plate by using Mo Kα radiation (λ, 0.71069 A, The structure was solved by using direct methods, refined with the SHELX software package G. Sheldrick, University of Göttingen, 1997, and expanded by using Fourier techniques. All non-hydrogen atoms were refined anisotropi-cally. The hydrogen atoms
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Kα radiation (λ = 0.71069 A). The structure was solved by using direct methods, refined with the SHELX software package (G. Sheldrick, University of Göttingen, 1997), and expanded by using Fourier techniques. All non-hydrogen atoms were refined anisotropi-cally. The hydrogen atoms were calculated with AFIX and included in the refinement with a common isotropic temperature factor. CCDC 713799 contains the supplementary crystallo-graphic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data- request/cif.
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70349946935
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C .Watanabe, T. Iwamoto, C .Kabuto, M. Kira, Angew. Chem. 2008, 120, 5466; Angew. Chem. Int. Ed. 2008, 47, 5386.
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c) C .Watanabe, T. Iwamoto, C .Kabuto, M. Kira, Angew. Chem. 2008, 120, 5466; Angew. Chem. Int. Ed. 2008, 47, 5386.
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26
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70349948723
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We reached this conclusion by data mining of the CCDC database
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We reached this conclusion by data mining of the CCDC database.
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0033579627
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A. J. Arduengo III, R. Krafczyk, R. Schmutzler, H. A. Craig, J. R. Goerlich, W. J. Marshall, M. Unverzagt, Tetrahedron 1999, 55, 14523.
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Arduengo III, A.J.1
Krafczyk, R.2
Schmutzler, R.3
Craig, H.A.4
Goerlich, J.R.5
Marshall, W.J.6
Unverzagt, M.7
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28
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70349937771
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II complexes is commonly between δ = -1500 ppm and δ = -5000 ppm.
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II complexes is commonly between δ = -1500 ppm and δ = -5000 ppm.
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30
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70349969380
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All optimized structures, Cartesian coordinates, and significant molecular orbitals are reported in the Supporting Information
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All optimized structures, Cartesian coordinates, and significant molecular orbitals are reported in the Supporting Information.
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31
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1442334129
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33845929780
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36749009530
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36
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70349971334
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All attempts to optimize a Y-shaped geometry led to convergence to a T-shaped geometry
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All attempts to optimize a Y-shaped geometry led to convergence to a T-shaped geometry.
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