Evaluation of automated stir bar sorptive extraction-thermal desorption-gas chromatography electron capture negative ion mass spectrometry for the analysis of PBDEs and PBBs in sheep and human serum

Journal of Chromatographic Science

Volumn 47, Issue 8, 2009, Pages 656-669

  Loconto, Paul R ^a  

^a MICHIGAN DEPARTMENT OF COMMUNITY HEALTH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

OVIS ARIES;

EID: 70349792885     PISSN: 00219665     EISSN: None     Source Type: Journal    
DOI: 10.1093/chromsci/47.8.656     Document Type: Article

References (22)

1. C. Naert, M. Piette, N. Bruneel, and C. Van Peteghem. Occurrence of polychlorinated biphenyls and polybrominated diphenyl ethers in Belgian human adipose tissue samples. Arch. Environ. Contam. Toxicol. 50: 290-296 (2006).
2. H. Aalm, B. Scholz, C. Fischer, K. Kultima, H. Viberg, P. Eriksson, L. Dencker, and M. Stigson. Proteomic evaluation of neonatal exposure to 2,2',4,4'5pentabromodiphenyl ether. Environ. Health Perspect. 114(2): 254-259 (2006).
3. A. Sjödin, R. Jones, J. Focant, C. Lapeza, R. Wang, E. McGhee III, Y. Zhang, W. Turner, B. Slazyk, L. Needham, and D. Patterson, Jr. Retrospective time-trend study of polybrominated diphenyl ether and polybrominated and polychlorinated biphenyl levels in human serumfromthe United States. Environ. Health Perspect. 112(6): 654-658 (2004).
4. A. Sjödin, L. Wong, R. Jones, A. Park, Y. Zhang, C. Hodge, E. Dipietro, C. McClure, W. Turner, L. Needham, and D. Patterson, Jr. Serum concentrations of polybromnated diphenyl ethers (PBDEs) and polybrominated biphenyl (PBB) in the United States population: 2003-2004. Environ. Sci. Technol. 42(4): 1377-1384 (2008).
5. J. Dye, M. Venier, L. Zhu, C. Ward, R. Hites, and L. Birnbaum. Elevated PBDE levels in pet cats: sentinels for humans? Environ. Sci. Technol. 41(18): 6350-6358 (2007).
6. P.R. Loconto, D. Isenga, M. O'Keefe, and M. Knotterus. Isolation and recovery of polybrominated diphenyl ethers from human and sheep serum: coupling reversed-phase solid-phase disk extraction and liquid-liquid extraction techniques with a capillary gas chromatographic electron capture negative ion mass spectrometric determinative technique. J. Chromatogr. Sci. 46: 53-60 (2008).
7. P.R. Loconto. Selectivity and sensitivity improvements for selected polybrominated dipheny ethers and polybrominated biphenyls using capillary gas chromatography/electron capture negative ion mass selective detection: a cost effective approach to biomonitoring. LC-GC NA 26(11): 1118-1130 (2008).
8. A. Prieto, O. Telleria, N. Etxebarria, L.A. Fernández, A. Usobiaga, and O. Zuloaga. Simultaneous preconcentration of a wide variety of organic pollutants in water samples: Comparison of stir bar sorptive extraction and membraneassisted solvent extraction. J. Chrom. A 1214(1-2): 1-10 (2008).
9. E. Baltussen, P. Sandra, F. David, and C. Cramers. Stir bar sorptive extraction (SBSE), a novel extraction technique for aqueous samples: theory and principles. J.Micro Sep. 11: 737-747 (1999).
10. F. David, B. Tienpont, and P. Sandra. Stir-bar sorptive extraction of trace organic compounds from aqueous matrices. LC-GC. 21(2): 1-7 (2003).
11. B. Tienpont, F. David, K. Desmet, and P. Sandra. Stir bar sorptive extractionthermal desorption-capillary GC-MS applied to biological fluids. Anal. Bioanal. Chem. 373: 46-55 (2002).
12. P. Serôdio and J.M.F. Nogueira. Multi-residue screening of endocrine disrupters chemicals in water samples by stirbar sorptive extraction-liquid desorption-capillary gas chromatography-mass spectrometry detection. Anal. Chim. Acta. 517: 21-32 (2004).
13. G. Fries. The PBB episode in Michigan: an overall appraisal. CRC Crit. Rev. Toxicol. 16: 105-156 (1985).
14. EPI Suite KOW WINNT.exe, Downloaded from the Environmental Protection Agency. Few log KOW values PBDEs are found in the database. The author calculated all KOW values for BDE congeners not found using the SMILES algorithm.
15. P.R. Loconto. Trace Environmental Quantitative Analysis, 2nd Ed., CRC Press, Taylor and Francis, Boca Raton, FL, 2006, Chapters 2,3, and Appendix A.
16. A. Pauwels, D. Wells, A. Covaci, and P. Schepens. Improved sample preparation method for selected persistent organochlorine pollutants in human serum using solid-phase disk extraction with gas chromatographic analysis. J. Chrom. B 723: 117-125 (1999).
17. P. Sandra, E. Baltussen, F. David, and A. Hoffman. "Stir bar sorptive extraction (SBSE) applied to environmental aqueous samples". App. Note 2/2000, Gerstel GmbH & Co. KG.
18. EPI Suite KOW WINNT.exe, Downloaded from the Environmental Protection Agency. Few log KOW values for PBDEs are found in the database. The author calculated all KOW values for BDE congeners not found using the SMILES algorithm. To download this software go to: http://www.epa.gov/oppt/exposure/pubs/episuitedl.htm
19. P. Loconto. IDLs: will we ever let 3s go? Am. Lab. News Ed. 37(4): Feb 27, 2005, pp. 36-40.
20. D. Coleman and L. Vanatta. Statistically derived detection limits (concluded). Am. Lab. 40(12): 34-37 (2008). This reference is from a series started in 2002.
21. J. Burdge, D. MacTaggart, and S. Farwell. Realistic Detection Limits from Confidence Bands. J. Chem. Educ. 76: 434-439 (1999).
22. L. Currie and G. Svehla. Nomenclature for the presentation of results of chemical analysis. Pure & Appl. Chem. 66(3): 595-608 (1994).