Dynamics of 1,3-dipolar cycloaddition reactions of diazonium betaines to acetylene and ethylene: Bending vibrations facilitate reaction

Angewandte Chemie - International Edition

Volumn 48, Issue 15, 2009, Pages 2746-2748

  Xu, Lai ^b   Doubleday, Charles E ^a   Houk, K N ^b  

^a Och Spine at New York Presbyterian Hospitals   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Cyclo diradicals; Cycloaddition; Dipole bending; Trajectory calculations; Transition states

Indexed keywords

BENDING VIBRATIONS; CYCLO-DIRADICALS; DIPOLAR CYCLOADDITION REACTION; DIPOLE BENDING; DISTORTION ENERGY; QUASICLASSICAL TRAJECTORIES; TRAJECTORY CALCULATIONS; TRANSITION STATES; TRANSITION VECTORS; TRANSITION-STATE;

ACETYLENE; CYCLOADDITION; ETHYLENE; LIGHTING; VIBRATIONS (MECHANICAL);

TRAJECTORIES;

EID: 70349786292     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200805906     Document Type: Article

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