Metal-organic framework assembled from T-shaped and octahedral nodes: A mixed-linker strategy to create a rare anatase TiO2 topology

Inorganic Chemistry

Volumn 48, Issue 19, 2009, Pages 9060-9062

  Verduzco, Jennifer M ^a   Chung, Haemi ^a   Hu, Chunhua ^b   Choe, Wonyoung ^a  

^a UNIVERSITY OF NEBRASKA LINCOLN   (United States)

^b NEW YORK UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 70349780698     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic9009916     Document Type: Article

References (53)

1. (a) Rowsell, J. L. C.; Yaghi, O. M. Angew. Chem., Int. Ed. 2005, 44, 4670.
2. (b) Dincä, M.; Long, J. R. Angew. Chem., Int. Ed. 2008, 47, 6766.
3. (c) Férey, G.; Mellot-Draznieks, C.; Serre, C.; Millange, F.; Dutour, J.; Surblé, S.; Margiolaki, I. Science 2005, 309, 2040.
4. (d) Long, J. R; Yaghi, O. M. Chem. Soc. Rev. 2009, 38, 1213.
5. (a) Cho, S.-H.; Ma, B.; Nguyen, S. T.; Hupp, J. T.; Albrecht-Schmitt, T. E. Chem. Commun. 2006, 2563.
6. (b) Seo, J. S.; Whang, D.; Lee, H.; Jun, S. I.; Oh, J.; Jeon, Y. J.; Kim, K. Nature 2000, 404, 982.
7. (c) Kitagawa, S.; Kitaura, R; Noro, S. Angew. Chem., Int. Ed. 2004, 43, 2334.
8. O'Keeffe, M.; Eddaoudi, M.; Li, H.; Reineke, T.; Yaghi, O. M. J. Solid State Chem. 2000, 152, 3.
9. Öhrström, L.; Larsson, K. Molecule Based Materials, The Structural Network Approach; Elsevier: Amsterdam, The Netherlands, 2005.
10. Examples of network structures with multiple nodes are (3,6), (4,6), and (4,8) nets. See: (a) Chun, H.; Kim, D.; Dybtsev, D. N.; Kim, K. Angew. Chem., Int. Ed. 2004, 43, 971.
11. (b) Natarajan, R; Savitha, G.; Dominiak, P.; Wozniak, K.; Moorthy, J. N. Angew. Chem., Int. Ed. 2005, 44, 2115.
12. (c) Du, M.; Zhang, Z.-H.; Zhao, X.-J.; Xu, Q. Inorg. Chem. 2006, 45, 5785.
13. (d) Lan, Y-Q.; Li, S.-L.; Li, Y-G.; Su, Z.-M.; Shao, K-Z.; Wang, X.-L. CrystEngComm 2008, 10, 1129.
14. For the three-letter net classification, see: O'Keeffe, M.; Peskov, M. M.; Ramsden, S. J.; Yaghi, O. M. Ace. Chem. Res. 2008, 41, 1782.
15. For the rtl net, see: (a) Xie, L. H.; Liu, S. X.; Gao, B.; Zhang, C. D.; Sun, C. Y.; Li, D. H.; Su, Z. M. Chem. Commun. 2005, 2402.
16. (b) Zhao, X.; Zhu, G.; Fang, Q.; Wang, Y.; Sun, F.; Qiu, S. Cryst. Growth Des. 2009, 9, 737.
17. For the ant net, see: (a) Caskey, S. R.; Wong-Foy, A. G.; Matzger, A. J. Inorg. Chem. 2008, 47, 7751.
18. (b) Xiang, S.; Wu, X.; Zhang, J.; Fu, R; Hu, S.; Zhang, X. J. Am. Chem. Soc. 2005, 127, 16352.
19. For the qom net, see: Chae, H. K.; Siberio-Perez, D. Y.; Kim, J.; Go, Y. B.; Eddaoudi, M.; Matzger, A. J.; O'Keeffe, M.; Yaghi, O. M. Nature 2004, 427, 523.
20. For the pyr net, see: Chae, H. K.; Kim, J.; Friedrichs, O. D.; O'Keeffe, M.; Yaghi, O. M. Angew. Chem., Int. Ed. 2003, 42, 3907.
21. (a) Delgado-Friedrichs, O.; O'Keeffe, M.; Yaghi, O. M. Acta Crystallogr., Sect. A 2003, 59, 22.
22. (b) For other (3,6) nets, see: Du, M.; Zhang, Z.-H.; Tang, L.-F.; Wang, X.-G.; Zhang, X.-J.; Batten, S. R Chem. Eur. J. 2007, 13 2578
23. (a) Cromer, D. T.; Herrington, K. J. Am. Chem. Soc. 1955, 77, 4708.
24. (b) Meagher, E. P.; Lager, G. A. Can. Mineral. 1979, 17, 77.
25. (c) Horn, M.; Scherdtfeger, C. F.; Meagher, E. P. Z. Kristallogr. 1972, 136, 273.
26. Burdett, J. K.; Hughbanks, T.; Miller, G. J.; Richardson, J. W.; Smith, J. V. J. Am. Chem. Soc. 1987, 109, 3639.
27. (e) O'Keeffe, M. Acta Crystallogr., Sect. A 1977, 33, 924.
28. (f) Burdett, J. K. Inorg. Chem. 1985, 24, 2244.
29. 2 is brookite (brk). However, this topology has not been observed in MOFs.
30. For the use of T-shaped nodes in MOFs, see:(a) Zaworotko, M. J. Chem. Commun. 2001, 1.
31. (b) Suh, M. P.; Cheon, Y. E.; Lee, E. Y. Coord. Chem. Rev. 2008, 252, 1007.
32. (c) Yong, G.; Qiao, S.; Xie, Y.; Wang, Z. Eur. J. Inorg. Chem. 2006, 4483.
33. Choi, E.-Y.; Barron, P. M.; Novotný, R. W.; Hu, C.; Kwon, Y.-U.; Choe, W. CrystEngComm 2008, 10, 824.
34. For reviews on porphyrin-based coordination polymers, see:(a) DeVries, L. D.; Choe, W. J. Chem. Crystallogr. 2009, 39, 229.
35. (b) Goldberg, I. CrystEngComm 2008, 10, 637.
36. (c) Suslick, K. S.; Bhyrappa, P.; Chou, J.-H.; Kosal, M. E.; Nakagaki, S.; Smithenry, D. W.; Wilson, S. Ace. Chem. Res. 2005, 38, 283.
37. (a) Stork, J. R.; Thoi, V. S.; Cohen, S. M. Inorg. Chem. 2007, 46, 11213.
38. (b) Halper, S. R.; Do, L.; Stork, J. R; Cohen, S. M. J. Am. Chem. Soc. 2006, 128, 15255.
39. -3, R1 = 0.0408, wR2 = 0.0901 [I > 2a(I), after SQUEEZE].
40. 2O: C, 65.04; H, 4.11; N, 9.00. Found: C, 65.13; H, 4.03; N, 9.00.
41. Choi, E.-Y.; Wray, C. A.; Hu, C.; Choe, W. CrystEngComm 2009,11, 553.
42. (a) Choi, E.-Y.; Barron, P. M.; Novotny, R. W.; Son, H.-T.; Hu, C.; Choe, W. Inorg. Chem. 2009, 48, 426.
43. (b) Chung, H.; Barron, P. M.; Novotny, R W.; Son, H.-T.; Hu, C.; Choe, W. Cryst. Growth Des. 2009, 9, 3327.
44. (a) The octahedral angles (corresponding to O-Ti-O angles in anatase) found in this Zn/BTB ant compound are 68-70° and 110-113°, representing a significant deviation from the ideal octahedral angle of 90° (see also Figure S5 in the Supporting Information).
45. (b) The stability of rtl and ant is closely related to the angular distortion of Ti-O-Ti. See refs 12d, 12f, and 22c.
46. Fahmi, A.; Minot, C.; Silvi, B.; Causa, M. Phys. Rev. B 1993, 47, 11717.
47. A similar trend can be seen in uninodal 3-connected nets. For example, the srs net demands an equilateral triangle node, but the ths net can adopt Y- or T-shaped nodes. See: Yaghi, O. M.; O'Keeffe, M.; Ockwig, N. W.; Chae, H. K.; Eddaoudi, M.; Kim, J. Nature 2003, 423, 705.
48. 3(1 +cos θ) sin θ for the ant and rtl topologies, respectively. As shown in Figure S6 in the Supporting Information, the ant topology is less dense than the rtl topology in the range of 106.3° < 2θ < 180°.
49. (a) Wells, A. F. Three Dimensional Nets and Polyhedra; Wiley: New York, 1977.
50. (b) lenco, A.; Proserpio, D. M.; Hoffmann, R. Inorg. Chem. 2004, 43, 2526.
51. (a) For example, various zeolite-like MOFs have been synthesized by mimicking the O-Si-O angle (144°). See: Park, K. S.; Ni, Z.; Côté, A. P.; Choi, J. Y.; Huang, R.; Uribe-Romo, F. J.; Chae, H. K.; O'Keeffe, M.; Yaghi, O. M. Proc. Natl. Acad. Sci. U.S.A. 2006, 103, 10186.
52. See also: (b) Yaghi, O. M.; O'Keeffe, M. Chem. Eur. J. 1999, 5, 2796.
53. 2 topology is also a rare topology in MOFs. See ref 15.