Single-component molecular conductor [Pt(tmdt)2] (tmdt = trimethylenetetrathiafulvalenedithiolate) - An advanced molecular metal exhibiting high metallicity

Advanced Materials

Volumn 21, Issue 35, 2009, Pages 3596-3600

  Zhou, Biao ^a,b   Kobayashi, Akiko ^a,b   Okano, Yoshinori ^c   Nakashima, Takeshi ^d   Aoyagi, Shinobu ^d   Nishibori, Eiji ^d   Sakata, Makoto ^d   Tokumoto, Madoka ^d,e   Kobayashi, Hayao ^a,b  

^a NIHON UNIVERSITY   (Japan)

^b JAPAN SCIENCE AND TECHNOLOGY AGENCY   (Japan)

^c INSTITUTE FOR MOLECULAR SCIENCE   (Japan)

^d NAGOYA UNIVERSITY   (Japan)

^e NATIONAL DEFENSE ACADEMY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

COMPRESSED PELLETS; CRYSTALLINE POWDER; FOUR-PROBE METHODS; FRONTIER MOLECULAR ORBITALS; HIGH CONDUCTIVITY; ISOTROPIC ENERGY; METALLIC BEHAVIORS; METALLICITIES; MOLECULAR CONDUCTORS; MOLECULAR METALS; RESISTIVITY MEASUREMENT; STRUCTURAL ORIGIN; STRUCTURE-BASED; X-RAY POWDER;

CHEMICAL BONDS; MOLECULAR ORBITALS; ORGANIC CONDUCTORS; PELLETIZING; PLATINUM; POWDER METALS;

CRYSTAL STRUCTURE;

EID: 70349764554     PISSN: 09359648     EISSN: None     Source Type: Journal    
DOI: 10.1002/adma.200803116     Document Type: Article

References (27)

1. D. Jérome, A. Mazaud, M. Ribault, K. Bechgaard, J. Phys. Lett. 1980, 47, L95.
2. a) M. Fourmigué, P. Batail, Chem. Rev. 2004, 104, 5379.
3. b) Other papers in the same thematic issue of Chem. Rev. 2004, 104(Molecular Conductors, edited by P. Batail).
4. E. E. Laukhina, V. A. Merzhanov, S. I. Pesotskii, A. C. Khomenko, E. B. Yagubskii, J. Ulanski, M. Kryszewski, J. K. Jeszka, Synth. Met. 1995, 70, 797.
5. M. M. Torrent, E. Laukhina, C.Rovira, J. Veciana, V. Tkacheva, L. Zorina, S. Khasanov, Adv. Funct. Mater. 2001, 11, 299.
6. D. de Caro, J. Fraxedas, C. Faulmann, I. Malfant, J. Milon, J.-F. Lameré, V. Collière, L Valade, Adv. Mater. 2004, 16, 835.
7. J.-P. Savy, D. de Caro, L. Valade, J.-P. Legros, P. A. Senzier, C. R. Pasquier, J. Fraxedas, F. Senocq, Europhys. Lett. 2007, 18, 37005.
8. H.Tanaka, Y. Okano, H. Kobayashi, W. Suzuki, A. Kobayashi, Science 2001, 297, 285.
9. A. Kobayashi, E. Fujiwara, H. Kobayashi, Chem. Rev. 2004, 104, 5243.
10. J. P. M. Nunes, M. J. Figueira, D. Belo, I. C. Santos, B. Ribeiro, E. B. Lopes, R. T. Henriques, J. V. Cancedo, J. Veciana, C.Rovira, M. Almeida, Chem. Eur. J. 2007, 13, 9841.
11. H.-R. Wen, C-H. Li, Y. Song, J.-L. Zuo, B. Zhang, X.-Z. You, lnorg. Chem. 2007, 46, 6837.
12. C.Rovira, J.J. Novoa, J. Mozos, P. Ordejón, E. Canadell, Phys. Rev. B 2002, 65, 081104 (R).
13. H. Tanaka, M. Tokumoto, S. Ishibashi, D. Graf, E. S. Choi, J. S. Brooks, S. Yasuzuka, Y. Okano, H. Kobayashi, A. Kobayashi, J. Am. Chem. Soc. 2004, 126, 10518.
14. B. Zhou, M. Shimamura, E. Fujiwara, A. Kobayashi, T. Higashi, E. Nishibori, M. Sakata, H. Cui, K. Takahashi, H. Kobayashi J. Am. Chem. Soc. 2006, 128, 3872.
15. Y. Hara, K. Miyagawa, K. Kanoda, M. Shimamura, B. Zhou, A. Kobayashi, H. Kobayashi, J. Phys. Soc. Jpn. 2008, 11, 053706.
16. E. Coronado, J. R. Galán-Mascaros, C. J. Gómez- García, V. Laukhin, Nature 2000, 408, 447.
17. E. Coronado, P. Day, Chem. Rev. 2004, 104, 5419.
18. H. Kobayashi, H. Cui, A. Kobayashi, Chem. Rev. 2004, 104, 5265.
19. A. Kobayashi, H. Tanaka, M. Kumazaki, H. Torii, B. Narymbetov, T. Adachi, J. Am. Chem. Soc. 1999, 127, 10763.
20. M. Sasa, E. Fujiwara, A. Kobayashi, S. Ishibashi, K. Terakura, Y. Okano, H. Fujiwara, H. Kobayashi, J. Mater. Chem. 2005, 15, 155.
21. J. M. Williams, J. R. Ferraro, R. J. Thorn, K. D. Carlson, U. Geiser, H. H. Wang, A. M. Kini, M.-H. Whangbo, Organic Superconductors (Including Fullerenes), Prentice-Hall, Englewood Cliffs, NJ, USA 1992.
22. The extended-Hückel molecular orbital calculations were performed by using the parameters sets of atomic orbitais reported in the following paper: a) R. H. Summerville, R. Hoffmann J. Am. Chem. Soc. 1976, 98, 7240 (for Pt, C).
23. b) B.E.R. Schilling, R. Hoffmann, J. W. Faller, J. Am. Chem. Soc. 1979, 101, 592 (for S). The calculated HOMO-LUMO gap EHL was approximately 0.10eV.
24. S. Ishibashi, K. Terakura, A. Kobayashi, J. Phys. Soc. Jpn. 2008, 77, 024702.
25. H.Tanaka, S. Hara, M.Tokumoto, A. Kobayashi, H. Kobayashi, Chem. Lett. 2007, 1006.
26. a) L. Binet, J. M. Fabre, C.Montginoul, K. B. Simonsen, J. Becher J. Chem. Soc. Perkin Trans. 1 1996, 783.
27. b) L Binet, C. Montginoul, J. M. Fabre, L Ouahab, S. Colhen, J. Becher, Synth. Met. 1997, 86, 1825.