-
5
-
-
33845279890
-
-
Kajimoto, O.; Futakami, M.; Kobayashi, T.; Yamasaki, K. J. Phys. Chem. 1988, 92, 1347.
-
(1988)
J. Phys. Chem.
, vol.92
, pp. 1347
-
-
Kajimoto, O.1
Futakami, M.2
Kobayashi, T.3
Yamasaki, K.4
-
6
-
-
0001352433
-
-
Sun, Y.-P.; Fox, M. A.; Johnston, K. P. J. Am. Chem. Soc. 1992, 114, 1187.
-
(1992)
J. Am. Chem. Soc.
, vol.114
, pp. 1187
-
-
Sun, Y.-P.1
Fox, M.A.2
Johnston, K.P.3
-
7
-
-
0030669586
-
-
Zhang, J.; Roek, D. P.; Chateauneuf, J. E.; Brennecke, J. F. J. Am. Chem. Soc. 1997, 119, 9980.
-
(1997)
J. Am. Chem. Soc.
, vol.119
, pp. 9980
-
-
Zhang, J.1
Roek, D.P.2
Chateauneuf, J.E.3
Brennecke, J.F.4
-
8
-
-
0034673472
-
-
Myers, D. J.; Shigeiwa, M.; Fayer, M. D.; Cherayil, B. J. J. Phys. Chem. B 2000, 104, 2402.
-
(2000)
J. Phys. Chem. B
, vol.104
, pp. 2402
-
-
Myers, D.J.1
Shigeiwa, M.2
Fayer, M.D.3
Cherayil, B.J.4
-
9
-
-
52449112081
-
-
Bourne, R. A.; Han, X.; Chapman, A. O.; Arrowsmith, N. J.; Kawanami, H.; Poliakoff, M.; George, M. W. Chem. Commun. 2008, 37, 4457.
-
(2008)
Chem. Commun.
, vol.37
, pp. 4457
-
-
Bourne, R.A.1
Han, X.2
Chapman, A.O.3
Arrowsmith, N.J.4
Kawanami, H.5
Poliakoff, M.6
George, M.W.7
-
11
-
-
0000075265
-
-
Egorov, S. A.; Yethiraj, A.; Skinner, J. K. Chem. Phys. Lett. 2000, 317, 558.
-
(2000)
Chem. Phys. Lett.
, vol.317
, pp. 558
-
-
Egorov, S.A.1
Yethiraj, A.2
Skinner, J.K.3
-
14
-
-
34250770025
-
-
Skarmoutsos, I.; Dellis, D.; Samios, J. J. Chem. Phys. 2007, 126, 224503.
-
(2007)
J. Chem. Phys.
, vol.126
, pp. 224503
-
-
Skarmoutsos, I.1
Dellis, D.2
Samios, J.3
-
15
-
-
0029659151
-
-
Eckert, C. A.; Knutson, B. L.; Debenedetti, P. G. Nature (London) 1996, 383, 313.
-
(1996)
Nature (London)
, vol.383
, pp. 313
-
-
Eckert, C.A.1
Knutson, B.L.2
Debenedetti, P.G.3
-
16
-
-
33845376511
-
-
Eckert, C. A.; Ziger, D. H.; Johnston, K. P.; Kim, S. J. Phys. Chem. 1986, 90, 2738.
-
(1986)
J. Phys. Chem.
, vol.90
, pp. 2738
-
-
Eckert, C.A.1
Ziger, D.H.2
Johnston, K.P.3
Kim, S.4
-
20
-
-
0011503641
-
-
Devendorf, G. S.; Ben-Amotz, D.; de Souza, L. E. S. J. Chem. Phys. 1996, 104, 3479.
-
(1996)
J. Chem. Phys.
, vol.104
, pp. 3479
-
-
Devendorf, G.S.1
Ben-Amotz, D.2
De Souza, L.E.S.3
-
21
-
-
0033554953
-
-
Pan, X.; McDonald, J. C; MacPhail, R. A. J. Chem. Phys. 1999, 110, 1677.
-
(1999)
J. Chem. Phys.
, vol.110
, pp. 1677
-
-
Pan, X.1
McDonald, J.C.2
MacPhail, R.A.3
-
22
-
-
14344260554
-
-
Sugimoto, K.; Fujiwara, H.; Koda, S. J. Supercrit. Fluids 2004, 32, 293.
-
(2004)
J. Supercrit. Fluids
, vol.32
, pp. 293
-
-
Sugimoto, K.1
Fujiwara, H.2
Koda, S.3
-
23
-
-
0037052260
-
-
Baglin, F. G.; Murray, S. K.; Daugherty, J. E.; Palmer, T. E.; Stanbery, W. Mol. Phys. 2000, 98, 409.
-
(2000)
Mol. Phys.
, vol.98
, pp. 409
-
-
Baglin, F.G.1
Murray, S.K.2
Daugherty, J.E.3
Palmer, T.E.4
Stanbery, W.5
-
24
-
-
53349128004
-
-
Fujisawa, T.; Terazima, M.; Kimura, Y. J. Phys. Chem. A 2008, 112, 5515.
-
(2008)
J. Phys. Chem. A
, vol.112
, pp. 5515
-
-
Fujisawa, T.1
Terazima, M.2
Kimura, Y.3
-
25
-
-
34948850744
-
-
Tono-oka, M.; Nakayama, H.; Ishii, K. Chem. Lett. 2007, 36, 1126.
-
(2007)
Chem. Lett.
, vol.36
, pp. 1126
-
-
Tono-Oka, M.1
Nakayama, H.2
Ishii, K.3
-
26
-
-
12344260790
-
-
Saitow, K.; Kajiya, D.; Nishikawa, K. J. Phys. Chem. A 2005, 109, 83.
-
(2005)
J. Phys. Chem. A
, vol.109
, pp. 83
-
-
Saitow, K.1
Kajiya, D.2
Nishikawa, K.3
-
27
-
-
24944524880
-
-
Kajiya, D.; Nishikawa, K.; Saitow, K. J. Phys. Chem. A 2005, 109, 7365.
-
(2005)
J. Phys. Chem. A
, vol.109
, pp. 7365
-
-
Kajiya, D.1
Nishikawa, K.2
Saitow, K.3
-
28
-
-
0347717655
-
-
Saitow, K.; Kajiya, D.; Nishikawa, K. J. Am. Chem. Soc. 2004, 126, 423.
-
(2004)
J. Am. Chem. Soc.
, vol.126
, pp. 423
-
-
Saitow, K.1
Kajiya, D.2
Nishikawa, K.3
-
29
-
-
0037155376
-
-
Saitow, K.; Ochiai, H.; Kato, T.; Nishikawa, K. J. Chem. Phys. 2002, 116, 4985.
-
(2002)
J. Chem. Phys.
, vol.116
, pp. 4985
-
-
Saitow, K.1
Ochiai, H.2
Kato, T.3
Nishikawa, K.4
-
30
-
-
0002475598
-
-
Saitow, K.; Ohtake, H.; Sarukura, N.; Nishikawa, K. Chem. Phys. Lett. 2001, 341, 86.
-
(2001)
Chem. Phys. Lett.
, vol.341
, pp. 86
-
-
Saitow, K.1
Ohtake, H.2
Sarukura, N.3
Nishikawa, K.4
-
31
-
-
0001750463
-
-
Saitow, K.; Nishikawa, K.; Ohtake, H.; Sarukura, N.; Miyagi, H.; Shimokawa, Y.; Matsuo, H.; Tominaga, K. Rev. Sci. Instrum. 2000, 71, 4061.
-
(2000)
Rev. Sci. Instrum.
, vol.71
, pp. 4061
-
-
Saitow, K.1
Nishikawa, K.2
Ohtake, H.3
Sarukura, N.4
Miyagi, H.5
Shimokawa, Y.6
Matsuo, H.7
Tominaga, K.8
-
32
-
-
0001533937
-
-
Nakayama, H.; Saitow, K.; Sakashita, M.; Ishii, K.; Nishikawa, K. Chem. Phys. Lett. 2000, 320, 323.
-
(2000)
Chem. Phys. Lett.
, vol.320
, pp. 323
-
-
Nakayama, H.1
Saitow, K.2
Sakashita, M.3
Ishii, K.4
Nishikawa, K.5
-
33
-
-
0037435461
-
-
Saitow, K.; Otake, K.; Nakayama, H.; Ishii, K.; Nishikawa, K. Chem. Phys. Lett. 2003, 368, 209.
-
(2003)
Chem. Phys. Lett.
, vol.368
, pp. 209
-
-
Saitow, K.1
Otake, K.2
Nakayama, H.3
Ishii, K.4
Nishikawa, K.5
-
34
-
-
3142680166
-
-
Saitow, K.; Nakayama, H.; Ishii, K.; Nishikawa, K. J. Phys. Chem. A 2004, 108, 5770.
-
(2004)
J. Phys. Chem. A
, vol.108
, pp. 5770
-
-
Saitow, K.1
Nakayama, H.2
Ishii, K.3
Nishikawa, K.4
-
36
-
-
33645707865
-
-
Otake, K.; Abe, M.; Nishikawa, K.; Saitow, K. Jpn. J. Appl. Phys 2006, 45, 2801.
-
(2006)
Jpn. J. Appl. Phys.
, vol.45
, pp. 2801
-
-
Otake, K.1
Abe, M.2
Nishikawa, K.3
Saitow, K.4
-
37
-
-
0037438339
-
-
Nishikawa, K.; Ochiai, H.; Saitow, K.; Morita, T. Chem. Phys. 2003, 286, 421.
-
(2003)
Chem. Phys.
, vol.286
, pp. 421
-
-
Nishikawa, K.1
Ochiai, H.2
Saitow, K.3
Morita, T.4
-
38
-
-
49149088088
-
-
Kajiya, D.; Mouri, Y.; Saitow, K. J. Phys. Chem. B 2008, 112, 7980.
-
(2008)
J. Phys. Chem. B
, vol.112
, pp. 7980
-
-
Kajiya, D.1
Mouri, Y.2
Saitow, K.3
-
40
-
-
84906407110
-
-
The resolution of this Raman spectrometer is less than 0.8 cm-1 at full width at half maximum at high resolution conditions
-
The resolution of this Raman spectrometer is less than 0.8 cm-1 at full width at half maximum at high resolution conditions.
-
-
-
-
43
-
-
84906392376
-
-
Note
-
Almost studies on supercritical solutions have been performed using solutions of saturated or fixed molar concentrations. In these experimental conditions, solute mole fraction changes by fluid density, because the solubility of solute and number density of solvent molecules change depending on fluid density. On the other hand, the mole fraction of solute molecule was set to be constant in the present study, and the density dependence was investigated under the fixed mole fraction. That is, the Raman spectra were measured at fixed mole fractions of solute and solvent molecules in all densities, temperatures, and both solute molecules of cis- and trans-isomers.
-
-
-
-
46
-
-
84906392377
-
-
Note
-
The analysis based on the perturbed hard-sphere theory was conducted in Raman spectroscopic studies of some neat supercritical fluids in refs 33-35, 47, and 48 and supercritical solutions in refs 21 and 38 and conducted in infrared spectroscopic studies of supercritical solutions in refs 49 and 50.
-
-
-
-
47
-
-
0141442040
-
-
ACS Symposium Series No. 488; Bright, F. V., McNanlly, M. E., Eds.; American Chemical Society: Washington, DC
-
Ben-Amotz, D.; LaPlant, F.; Shea, D.; Gardecki, J.; List, D. Proceedings of the Supercritical Fluids Technology; ACS Symposium Series No. 488; Bright, F. V., McNanlly, M. E., Eds.; American Chemical Society: Washington, DC, 1992; p 18.
-
(1992)
Proceedings of the Supercritical Fluids Technology
, pp. 18
-
-
Ben-Amotz, D.1
Laplant, F.2
Shea, D.3
Gardecki, J.4
List, D.5
-
48
-
-
33645859614
-
-
Cabaco, M. I.; Besnard, M.; Tassaing, T.; Danten, Y. J. Mol. Liq. 2006, 125, 100.
-
(2006)
J. Mol. Liq.
, vol.125
, pp. 100
-
-
Cabaco, M.I.1
Besnard, M.2
Tassaing, T.3
Danten, Y.4
-
49
-
-
2342444458
-
-
Lalanne, P.; Tassaing, T.; Danten, Y.; Cansell, F.; Tucker, S. C; Besnard, M. J. Phys. Chem. A 2004, 108, 2617.
-
(2004)
J. Phys. Chem. A
, vol.108
, pp. 2617
-
-
Lalanne, P.1
Tassaing, T.2
Danten, Y.3
Cansell, F.4
Tucker, S.C.5
Besnard, M.6
-
50
-
-
7444219592
-
-
Tassaing, T.; Oparin, R.; Danten, Y.; Besnard, M. J. Supercrit. Fluids 2005, 33, 85.
-
(2005)
J. Supercrit. Fluids
, vol.33
, pp. 85
-
-
Tassaing, T.1
Oparin, R.2
Danten, Y.3
Besnard, M.4
-
54
-
-
0037149765
-
-
Takahashi, K.; Sugawara, M.; Yabushita, S. J. Phys. Chem. A 2002, 106, 2676.
-
(2002)
J. Phys. Chem. A
, vol.106
, pp. 2676
-
-
Takahashi, K.1
Sugawara, M.2
Yabushita, S.3
-
55
-
-
84906378647
-
-
The values of attractive shifts were listed in Supporting Information Tables S1 and S2
-
The values of attractive shifts were listed in Supporting Information Tables S1 and S2.
-
-
-
-
56
-
-
84906407107
-
-
According to the perturbed hard-sphere analysis, the repulsive shift is not zero but the nonzero value at the density=0. This is indicated by the following equation. That is, eq 2 at density=0 brings δvR/v0=C1 exp(O)+C2 exp(O)-C3 exp(O)=Q+C2-C3≢0
-
According to the perturbed hard-sphere analysis, the repulsive shift is not zero but the nonzero value at the density=0. This is indicated by the following equation. That is, eq 2 at density=0 brings δvR/v0=C1 exp(O)+C2 exp(O)-C3 exp(O)=Q+C2-C3≢0.
-
-
-
-
57
-
-
0000437782
-
-
Ben-Amotz, D.; Lee, M.-R.; Cho, S. Y.; List, D. J. J. Chem. Phys. 1992, 96, 8781.
-
(1992)
J. Chem. Phys.
, vol.96
, pp. 8781
-
-
Ben-Amotz, D.1
Lee, M.-R.2
Cho, S.Y.3
List, D.J.4
-
60
-
-
0003556247
-
-
Wiley; New York, 947-951, and 955-970
-
Hirschfelder, J. O.; Curtiss, C. F.; Bird, R. B. Molecular Theory of Gases and Liquids; Wiley; New York, 1954; pp 25-30, 947-951, and 955-970.
-
(1954)
Molecular Theory of Gases and Liquids
, pp. 25-30
-
-
Hirschfelder, J.O.1
Curtiss, C.F.2
Bird, R.B.3
-
62
-
-
84906407108
-
-
Note
-
In the pseudodiatomic approximation, (∂αo/∂QδQ and (∂μ/∂Q)δQ can be expressed by (∂α0/∂r)Ar and (∂μ0/∂r)δr, where Ar is given by δr ≃-(3/2) hcvoglf2.571 The term h is the Planck constant, and c is the speed of light in vacuum. ∂μ0/∂Q is given by ∂μ/∂Q =(3c2μredA/πN) 1/2, 63 where N, A, and μred are the Avogadro's number, integrated absorption coefficient, and reduced mass obtained from v0 ≃(k//μred)1/2/2π. Parameters required for calculations are listed in Table 2. Since trans-C2H2Cl2 and CO2 molecules do not possess a permanent electric dipole moment, eq 4 can be simplified by writing CA=CA,dis+ CA,DID+CA-D-Q for cis-C2H2Cl2, and CA=CA,dis for trans-C2H2Cl2.
-
-
-
-
64
-
-
84906364344
-
-
Note
-
60
-
-
-
-
66
-
-
84906407109
-
-
Note
-
When the anisotropic shifts are averaged by θ and ø, the anisotropic shifts become the isotropic shift.
-
-
-
-
67
-
-
84906407105
-
-
Note
-
The value of CA is obtained from the summation of eqs 9-11, whose equations are functions of angles, θ0, θS, øo, and øs. One can obtain the CA value as a function of an angle by fixing the other angles.
-
-
-
-
68
-
-
84906378645
-
-
Note
-
In calculation of anisotropic attractive shift, the radial distance between solute and solvent molecules is fixed and is used as the sum of radii of solute and solvent molecules that are in contact. This idea is based on the model used in refs 49, 50, and 57 and is applied to the present analysis. As for the orientation, the anisotropic attractive shift is calculated by changing each angle.
-
-
-
-
69
-
-
84906392373
-
-
Note
-
As shown in Figure 7, the slope of attractive shifts changes slightly by the density. According to our estimation, the difference of slopes in the present density range is within 10%. Thus, we approximate the obtained data as linear density dependence.
-
-
-
-
70
-
-
30244465045
-
-
Inomata, H.; Saito, S.; Debenedetti, P. G. Fluid Phase Equilib. 1996, 116, 282.
-
(1996)
Fluid Phase Equilib.
, vol.116
, pp. 282
-
-
Inomata, H.1
Saito, S.2
Debenedetti, P.G.3
-
71
-
-
0002240713
-
-
Kanakubo, M.; Umecky, T.; Kawanami, H.; Aizawa, T.; Ikushima, Y.; Masuda, Y. Chem. Phys. Lett. 2001, 338, 95.
-
(2001)
Chem. Phys. Lett.
, vol.338
, pp. 95
-
-
Kanakubo, M.1
Umecky, T.2
Kawanami, H.3
Aizawa, T.4
Ikushima, Y.5
Masuda, Y.6
-
72
-
-
27744470587
-
-
Stubbs, J. M.; Drake-Wilhelm, D. D.; Siepmann, J. I. J. Phys. Chem. B 2005, 109, 19885.
-
(2005)
J. Phys. Chem. B
, vol.109
, pp. 19885
-
-
Stubbs, J.M.1
Drake-Wilhelm, D.D.2
Siepmann, J.I.3
-
73
-
-
0030251058
-
-
Iwai, Y.; Uchida, H.; Koga, Y.; Arai, Y.; Mori, Y. Ind. Eng. Chem. Res. 1996, 35, 3782.
-
(1996)
Ind. Eng. Chem. Res.
, vol.35
, pp. 3782
-
-
Iwai, Y.1
Uchida, H.2
Koga, Y.3
Arai, Y.4
Mori, Y.5
-
74
-
-
30244540914
-
-
Iwai, Y.; Koga, Y.; Arai, Y. Fluid Phase Equilib. 1996, 116, 267.
-
(1996)
Fluid Phase Equilib.
, vol.116
, pp. 267
-
-
Iwai, Y.1
Koga, Y.2
Arai, Y.3
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