Effects of spacers on surface activities and aggregation properties of anionic gemini surfactants

Journal of Surfactants and Detergents

Volumn 12, Issue 2, 2009, Pages 165-172

  Cao, Xulong ^a   Li, Zhenquan ^a   Song, Xinwang ^a   Cui, Xiaohong ^a   Wei, Yuping ^b   Cheng, Fa ^b   Wang, Jun ^b  

^a CHINA PETROLEUM AND CHEMICAL CORPORATION   (China)

^b TIANJIN UNIVERSITY   (China)

Author keywords

Critical micelle concentration; Gemini surfactant; Micelle; Micelle aggregation number; Micropolarity; NaCl

Indexed keywords

AGGREGATION NUMBERS; AGGREGATION PROPERTY; ANIONIC GEMINI SURFACTANT; AQUEOUS SOLUTIONS; CONCENTRATION OF; CRITICAL MICELLE CONCENTRATION (CMC); EXPERIMENTAL CONDITIONS; FLEXIBLE SPACER; FLUORESCENCE INTENSITIES; FLUORESCENCE PROBES; GEMINI SURFACTANT; INTRINSIC FLUORESCENCE; MICELLE AGGREGATION NUMBER; MICROPOLARITY; NACL; RING METHOD; SPACER GROUPS; SURFACE ACTIVITIES;

ANIONIC SURFACTANTS; CONCENTRATION (PROCESS); CRITICAL MICELLE CONCENTRATION; FLUORESCENCE; MICELLES; QUENCHING; SODIUM CHLORIDE; SURFACE TENSION;

AGGLOMERATION;

EID: 70349584767     PISSN: 10973958     EISSN: None     Source Type: Journal    
DOI: 10.1007/s11743-009-1108-8     Document Type: Article

References (51)

1. Menger FM, Keiper JS (2000) Gemini surfactants. Angew Chem Int Ed 391:1906-1920
2. Kim SS, Zhang WZ, Pinnavaia TJ (1998) Ultrastable Mesostructured Silica Vesicles. Science 282:1302-1305
3. Bunton CA, Robinson L, Shaak J, Stam MF (1971) Catalysis of nucleophilic substitutions by micelles of dicationic detergents. J Org Chem 36:2346-2350
4. Bunton CA, Minch MJ, Hidalgo J, Sepulveda L (1973) Electrolyteeffects on the cationic micelle catalyzed decarboxylation of6-nitrobenzisoxazole-3- carboxylate anion. J Am Chem Soc 95:3262-3272
5. De S, Aswal VK, Goyal PS, Bhattacharya S (1996) Role of spacer chain length in dimeric micellar organization. Small angle neutron scattering and fluorescence studies. J Phys Chem 100:11664-11671
6. Zana R, Benrraou M, Rueff R (1991) Alkanediyl-.alpha.,omega.- bis(dimethyl alkylammonium bromide) surfactants. 1. Effect of the spacer chain length on the critical micelle concentration and micelle ionization degree. Langmuir 7:1072-1075
7. Bai GY, Yan HK, Thomas RK (2001) Microcalorimetric studies on the thermodynamic properties of cationic Gemini surfactants. Langmuir 17:4501-4504
8. Frindi M, Michels B, Levy H, Zana R (1994) Alkanediyl-α, omega-bis (dimethyl alkylammonium bromide) surfactants. 4. Ultrasonic absorption studies of amphiphile exchange between micelles and bulk phase in aqueous micellar solution. Langmuir 10:1040-1145
9. De S, Aswal VK, Goyal PS, Bhattacharya S (1998) Novel Geminimicelles from dimeric surfactants with oxyethylene spacer chain. Small angle neutron scattering and fluorescence studies. J Phys Chem B 102:6152-6160
10. Rosen MJ, Song LD (1996) Dynamic surface tension of aqueous surfactant solutions 8. Effect of spacer on dynamic properties of Gemini surfactant solutions. J Colloid Interface Sci 179:261-268
11. Kern F, Lequeux F, Zana R, Candau SJ (1994) Dynamic properties of salt-free viscoelastic micellar solutions. Langmuir 10:1714-1723
12. Danino D, Talmon Y, Zana R (1995) Alkanediyl-α, ω-bis( dimethyl alkylammonium bromide) surfactants (dimeric surfactants). 5. Aggregation and microstructure in aqueous solutions. Langmuir 10:1448-1456
13. In M, Bec V, Aguerre-Chariol O, Zana R (2000) Quaternary ammonium bromide surfactant oligomers in aqueous solution: Self-association and microstructure. Langmuir 16:141-148
14. Rosen MJ, Mathias JH, Davenport L (1999) Aberrant aggregation behavior in cationic Gemini surfactants investigated by surface tension, interfacial tension, and fluorescence methods. Langmuir 15:7340-7346
15. Chen QB, Liang XD, Wang SL, Xu SH, Liu HL, Hu Y (2007) Cationic Gemini surfactant at the air/water interface. J Colloid Interface Sci 314:651-658
16. Alami E, Levy H, Zana R, Skoulios A (1993) Alkanediyl-α, ω-bis(dimethyl alkylammonium bromide) surfactants. 2. Structure of the lyotropic mesophases in the presence of water. Langmuir 9:940-944
17. Zana R, In M, Lévy H (1997) Alkanediyl-α, ω-bis(dimethyl alkylammonium bromide). 7. Fluorescence probing studies of micelle micropolarity and microviscosity. Langmuir 13:5552-5557
18. Mathias JH, Rosen MJ, Davenport L (2001) Fluorescence study of premicellar aggregation in cationic Gemini surfactants. Langmuir 17:6148-6154
19. Junior PBS, Tiera VAO, Tiera MJ (2007) A fluorescence probe study of Gemini surfactants in aqueous solution: a comparison between n-2-n and n-6-n series of the alkanediyl-a, w-bis (dimethyl alkylammonium bromides. Ecl Quím São Paulo 32:47-54
20. Oda R, Huc I, Danino D, Talmon Y (2000) Aggregation properties and mixing behavior of hydrocarbon, fluorocarbon, and hybrid hydrocarbon-fluorocarbon cationic dimeric surfactants. Langmuir 16:9759-9769
21. Li F, Rosen MJ, Sulthana SB (2001) Surface properties of cationicGemini surfactants and their interaction with alkylglucoside or maltoside surfactants. Langmuir 17:1037-1042
22. Pinazo A, Wen X, Pérez L, Infante M-R, Franses EI (1999) Aggregation behavior in water of monomeric and Gemini cationic surfactants derived from arginine. Langmuir 15:3134-3142
23. Zhu YP, Masuyama A, Okahara M (1990) Preparation and surface active properties of amphipathic compounds with two sulfate groups and two lipophilic alkyl chains. J Am Oil Chem Soc 67:459-463
24. Zhu YP, Masuyama A, Okahara M (1991) Preparation and surface- active properties of new amphipathic compounds with two phosphate groups and two long-chain groups. J Am Oil Chem Soc 68:268-271
25. Zhu YP, Masuyama A, Kobata Y, Nakatsuji Y, Okahara M, Rosen MJ (1993) Double-chain surfactants with two carboxylategroups and their relation to similar double-chain compounds. J Colloid Interface Sci 158:40-45
26. Menger FM, Littau CA (1991) Gemini surfactants: synthesis and properties. J Am Chem Soc 113:1451-1452
27. Duivenvoorde FL, Feiters MC, van der Gaast SJ, Engberts JBFN (1997) Synthesis and properties of di-n-dodecyl a, x-alkyl bisphosphate surfactants. Langmuir 13:3737-3743
28. Dix LR (2001) Sodium salts of bis(1-dodecenylsuccinamic acids): a simple route to anionic Gemini surfactants. J Colloid Interface Sci 238:447-448
29. Magdassi S, Ben Moshe M, Talmon Y, Danino D (2003) Microemulsions ased on anionic Gemini surfactant. Colloids Surf A 212:1-7
30. Yoshimura T, Esumi K (2004) Synthesis and surface properties of anionic Gemini surfactants with amide groups. J Colloid Interface Sci 276:231-238
31. Du XG, Li L, Yang ZY (2007) Fluorescence investigation of aggregation behaviors of novel anionic Gemini surfactants. Z Phys Chem 221:873-879
32. Menger FM, Littau CA (1993) Gemini surfactants: a new class of self-assembling molecules. J Am Chem Soc 115:10083-10090
33. Wettig SD, Verrall RE (2001) Thermodynamic studies of aqueous msm Gemini surfactant systems. J Colloid Interface Sci 235:310-316
34. Wettig SD, Nowak P, Verrall RE (2002) Thermodynamic and aggregation properties of Gemini surfactants with hydroxyl substituted spacers in aqueous solution. Langmuir 18:5354-5359
35. Menger FM, Keiper JS, Azov V (2000) Gemini surfactants with acetylenic spacers. Langmuir 16:2062-2067
36. Zhu S, Cheng F, Wang J (2006) Anionic Gemini surfactants: synthesis and aggregation properties in aqueous solutions. Colloids Surf A 281:35-39
37. Zhu S, Cheng F, Wang J (2004) Aggregation properties of a new anionic Gemini surfactant in aqueous solution. Acta Physico- Chimica Sinica 20:1245-1248
38. Theander K, Pugh RJ (2001) The influence of pH and temperature on the equilibrium and dynamic surface tension of aqueous solutions of sodium oleate. J Colloid Interface Sci 239:209-216
39. Chen GZ (1990) Fluorescence analysis. Science Press, Beijing
40. Kalyansundaram K, Thomas JK (1977) Environmental effects on vibronic band intensities in pyrene monomer fluorescence and their application in studies of micellar systems. J Am Chem Soc 99:2039-2044
41. Ananthapadmanabhan KP, Goddard ED, Turro NJ, Kuo PL (1985) Fluorescence probes for critical micelle concentration determination. Langmuir 1:352-355
42. Turro NJ, Kuo PL (1986) Photoluminescence probes for pressure and temperature effects on the aggregates of water-soluble block copolymers. J Phys Chem 90:4205-4210
43. Rosen MJ (1989) Surfactants and interfacial phenomena, 2nd edn. Wiley, New York
44. Fang Y, Liu XF, Xia YM, Yang Y, Cai K, Xu YM, Zhao XY (2001) Determination of critical micellar aggregation numbers by steady-state fluorescence probe method. Acta Physico-Chimica Sinica 17:828-831 (Pubitemid 33339086)
45. Wang XY, Wang JB, Wang YL, Yan HK, Li PX, Thomas RK (2004) Effect of the nature of the spacer on the aggregation properties of Gemini surfactants in an aqueous solution. Langmuir 20:53-56
46. Dreja M, Pyckhout-Hintzen W, Tiecke B (1999) Cationic Gemini surfactants with oligo (oxyethylene) spacer groups and their use in the polymerization of styrene in ternary microemulsion. Langmuir 15:391-399
47. Missel PJ, Mazer NA, Benedek GB, Young CY, Carey MC (1980) Thermodynamic analysis of the growth of sodium dodecyl sulfate micelles. J Phys Chem 84:1044-1057
48. Lin TL, Chen SH, Gabriel NE, Roberts MF (1987) Small-angle neutron scattering techniques applied to the study of polydisperse rodlike diheptanoylphosphatidylcholine micelles. J Phys Chem 91:406-413
49. Hait SK, Moulik SP (2006) Gemini surfactants: a distinct class of self-assembling molecules. Curr Sci 82:1101-1111
50. Myers D (1999) Surfaces, interfaces and colloids: principles and applications, 2nd edn. Wiley, New York
51. Benrraou M, Bales BL, Zana R (2003) Effect of the nature of the counterion on the properties of anionic surfactants. 1. CMC, ionization degree at the CMC and aggregation number of micelles of sodium, cesium, tetramethylammonium, tetraethylammonium, tetrapropylammonium, and tetrabutylammonium dodecyl sulfates. J Phys Chem B 107:13432-13440