Oxidative extraction of thiophene from n-dodecane over TS-1 in continuous process: A model for non-severe sulfur removal from liquid fuels

Catalysis Communications

Volumn 11, Issue 1, 2009, Pages 1-6

  Napanang, Thasaneeya ^a   Sooknoi, Tawan ^a  

^a KING MONGKUT'S INSTITUTE OF TECHNOLOGY LADKRABANG   (Thailand)

Author keywords

Continuous process; Extraction; Oxidation; Thiophene; TS 1

Indexed keywords

CALCINATIONS TEMPERATURE; CONTINUOUS PROCESS; CONTINUOUS STIRRED TANK REACTOR; DODECANE; FEEDING RATE; HIGHER EFFICIENCY; ICP-AES; LIQUID HYDROCARBONS; LIQUID-PHASE OXIDATION; N-DODECANE; OXIDATION ACTIVITIES; OXIDATIVE EXTRACTION; OXIDIZED PRODUCTS; OXIDIZING AGENTS; PERISTALTIC PUMP; POLAR SOLVENTS; ROOM TEMPERATURE; SELECTIVE REMOVAL; SEM; SULFUR REMOVAL; THIOPHENE REMOVAL; TITANIUM LEACHING; TITANIUM SILICALITE-1; TS-1; TS-1 CATALYSTS; XRD;

ACETONITRILE; ATMOSPHERIC PRESSURE; ATOMIC EMISSION SPECTROSCOPY; CALCINATION; CATALYSIS; CATALYST DEACTIVATION; DESULFURIZATION; HYDROCARBONS; INDUCTIVELY COUPLED PLASMA; LEACHING; LIQUIDS; METHANOL; ORGANIC POLYMERS; ORGANIC SOLVENTS; OXIDATION; SILICATE MINERALS; SOLVENTS; SULFUR; THIOPHENE; TITANIUM; ZEOLITES;

METAL RECOVERY;

EID: 70349558557     PISSN: 15667367     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.catcom.2009.07.022     Document Type: Article

References (31)

1. Yang R.T., Hernandez-Maldonado A.J., and Yang F.H. Adsorbent: fundamentals and application. Science 301 (2003) 79
2. European Standard for Gasoline EN 228/1999 and for Diesel EN/1999.
3. Babich I.V., and Moulijn J.A. Recent advancement on deep desulfurization of gasoline and diesel oil. Fuel 82 (2003) 607-631
4. de Souzaa W.F., Guimarãesb I.R., Guerreirob M.C., and Oliveirab L.C.A. Catalytic oxidation of sulfur and nitrogen compounds from diesel fuel. Appl. Catal. A: Gen. 360 2 (2009) 205-209
5. Gómez-Bernala H., Cedeño-Caero L., and Aída Gutiérrez-Alejandre A. Liquid phase oxidation of dibenzothiophene with alumina-supported vanadium oxide catalysts: an alternative to deep desulfurization of diesel. Catal. Today 142 3-4 (2009) 227-233
6. Cedeño-Caero L., Gomez-Bernala H., Fraustro-Cuevasa A., Guerra-Gomeza H.D., and Cuevas-Garciaa R. Oxidative desulfurization of synthetic diesel using supported catalysts. Part III. Support effect on vanadium-based catalysts. Catal. Today 133-135 (2008) 244-254
7. Zannikos F., Lois E., and Stournas S. Desulfurization of petroleum fraction by oxidation and solvent extraction. Fuel Process. Technol. 42 1 (1995) 35-45
8. A.S. Rappas, Unipure Corporation, US Patents US 6,402,940, US 6,406,616.
9. Guoxian Y., Shanxiang L., Hui C., and Zhongnan Z. Diesel fuel desulfurization with hydrogen peroxide promoted by formic acid and catalyzed by activated carbon. Carbon 43 (2005) 2285-2294
10. Dolbear G.E., and Skov E.R. Diesel fuel sulfur requirements. Prepr.-Am. Chem. Soc., Div. Petro. Chem. 45 2 (2000) 375
11. Bonde S.E., Gore W., and Dolbear G.E. Advanced oxidation process. Prepr.-Am. Chem. Soc. Chem. 44 2 (1999) 199
12. Shiraishi Y., Tachibana K., Hirai T., and Komasawa I. Ultra-deep desulfurization of transportation fuels via charge-transfer complexes under ambient conditions. Ind. Eng. Chem. Res 41 17 (2000) 4362
13. Zaku K., Makino M., and UkeGawa K. Oxidative desulfurization of diesel oil with hydrogen peroxide in the presence of acid catalyst in diesel oil/acetic acid biphasic system. Chem. Lett. 33 10 (2004) 1306-1307
14. Campos-Martin J.M., Capel-Sanchez M.C., and Fierro J.L.G. Highly efficient deep desulfurization of fuels by chemical oxidation. Green Chem. 6 (2004) 557-562
15. 2 systems. Appl. Catal. A 219 (2001) 267-280
16. Collins F.M., Andrew R.L., and Christopher S. Catalytic oxidative desulfurization of liquid fuels. J. Mol. Catal. A117 (1997) 397
17. Guoxian Y., Hui C., Shanxiang L., and Zhongnan Z. Deep desulfurization of diesel fuels by catalytic oxidation. Chem. Eng. 1 2 (2007) 162-166
18. K. Yatzu, K. Miki, K. Ukegaw, Study on the catalytic oxidation desulfurization of diesel under ultrasound, JP 2001354978 (2001).
19. 2 over Ti-containing molecular sieves - a very efficient method for removing aromatic sulfur compounds from fuels. J. Catal. 198 (2001) 179-186
20. Shiraishi Y., Hirai H., and Komosawa I. Oxidative desulfurization process for light oil using titanium silicate molecular sieve catalysts. J. Chem. Eng. Jpn. 35 12 (2002) 1305-1311
21. 2. Catal. Today 93-95 (2004) 341-345
22. Fang Y., and Hu H. Mesoporous TS-1: nanocasting synthesis with CMK-3 as template and its performance in catalytic oxidation of aromatic thiophene. Catal. Commun. 8 (2007) 817-820
23. Nemeth L., Bare S.R., Rathbun W., Gatter M., and Low J. Oxidative desulfurization of sulfur compounds: Oxidation of thiophene and derivatives with hydrogen peroxide using Ti-Beta catalyst. Studies Surf. Sci. Catal. 174 2 (2008) 1017-1020
24. Otsuki S., Nonaka T., Quin W., Ishihara A., Kabe T., and Sekiyu G. Oxidative desulfurization of middle distillate using ozone. Energy Fuel. 42 (1999) 315
25. 2 and oxidation of thiophene over supported gold catalysts, Chem. Eng. J., in press, doi:10.1016/j.cej.2009.04.004.
26. Lanju C., Shuohui G., and Dishun Z. Oxidation of thiophene over silica gel in hydrogen peroxide/formic acid system. Chin. J. Chem. Eng. 14 6 (2006) 835-838
27. Hulea V., and Patrice M. The solvent effect in the sulfoxidation of thioether by hydrogen peroxide using Ti-containing zeolites as catalysts. J. Mol. Catal. A Chem. 113 3 (1996) 499-505
28. 2 over Ti-containing zeolites. Appl. Catal. A Gen. 170 (1998) 169-175
29. Sooknoi T., and Limtrakul J. Activity enhancement by acetic acid in cyclohexane oxidation using Ti-containing zeolite catalyst. Appl. Catal. A Gen. 233 1-2 (2002) 227-237
30. Sooknoi T., and Chitranuwatkul V. Ammoximation of cyclohexanone in acetic acid using titanium silicalite-1 catalyst: activity and reaction pathway. J. Mol. Catal. A Chem. 236 (2005) 220-226
31. 2: a comparative study of catalytic activity and stability. Appl. Catal. A Gen. 345 (2008) 195-200