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Volumn 1, Issue 1, 2009, Pages 35-38

Novel calcium carboxyphosphonate/polycarboxylate inorganic-organic hybrid materials from demineralization of calcitic biomineral surfaces

Author keywords

calcite dissolution; calcium carbonate; carboxylates; inorganic organic hybrids; phosphonates

Indexed keywords

ANIONIC ADDITIVES; BIOMINERALS; CALCITE DISSOLUTION; CALCIUM OXALATES; CARBOXYLATES; DISSOLUTION PRODUCTS; INORGANIC-ORGANIC HYBRID; INORGANIC-ORGANIC HYBRID MATERIALS; PHOSPHONATES; POLYMERIC MATERIAL; SINGLE CRYSTAL X-RAY CRYSTALLOGRAPHY; SPARINGLY SOLUBLE SALT;

EID: 70349441665     PISSN: 19448244     EISSN: 19448252     Source Type: Journal    
DOI: 10.1021/am800030h     Document Type: Article
Times cited : (18)

References (76)
  • 18
    • 84879790762 scopus 로고    scopus 로고
    • Mollusk nacre provides an example of a polycrystalline calcium carbonate biomineral with excellent mechanical properties. Despite having a very low organic content (∼1%), this material is superior to most other composite ceramics.
    • Mollusk nacre provides an example of a polycrystalline calcium carbonate biomineral with excellent mechanical properties. Despite having a very low organic content (∼1%), this material is superior to most other composite ceramics.
  • 35
    • 84879792700 scopus 로고    scopus 로고
    • SPE International Symposium on Formation Damage Control, Lafayette, LA, Feb 23 and 24, 2000; Paper SPE 58715. (c) Williams, H.; Wat, R.; Chen, P.; Hagen, T.; Wennberg, K.; Viken, V.; Graham, G. M. Society of Petroleum Engineers 7th International Symposium on Oilfield Scale 2005: Pushing the Boundaries of Scale Control, Proceedings art. no. SPE 95127, p 247.
    • Huang, T., Ostensen, L., and Hill, A. D. SPE International Symposium on Formation Damage Control, Lafayette, LA, Feb 23 and 24, 2000; Paper SPE 58715. (c) Williams, H.; Wat, R.; Chen, P.; Hagen, T.; Wennberg, K.; Viken, V.; Graham, G. M. Society of Petroleum Engineers 7th International Symposium on Oilfield Scale 2005: Pushing the Boundaries of Scale Control, Proceedings art. no. SPE 95127, p 247.
    • Huang, T.1    Ostensen, L.2    Hill, A.D.3
  • 47
    • 84879791418 scopus 로고    scopus 로고
    • 3 mass, the dissolution efficiency of each ligand is calculated. Control experiments (no ligands added) are also carried out.
    • 3 mass, the dissolution efficiency of each ligand is calculated. Control experiments (no ligands added) are also carried out.
  • 48
    • 84879790445 scopus 로고    scopus 로고
    • See the Supporting Information.
    • See the Supporting Information.
  • 49
    • 0000107346 scopus 로고
    • Similar synthetic protocols were used for the syntheses of Ca-CEPA, Ca-MAL, and Sr-BTCA compounds. A quantity of the ligand (0.5 mmol) is dissolved in 50 mL of in-house deionized water. After the ligand dissolves, a quantity of metal hydroxide (0.5 mmol) is slowly added as a solid. The pH is adjusted to ∼5.4 with a 0.1 M NaOH solution and left to stand. After a prolonged period of time (1 day for Ca-CEPA, 30 days for Ca-MAL, and 25 days for Sr-BTCA), single crystals appeared, were isolated by filtration, and were washed with deionized water. Elemental analysis and spectroscopic characterization information are given in the Supporting Information. Ca-CIT was synthesized according to, - 2057.
    • Similar synthetic protocols were used for the syntheses of Ca-CEPA, Ca-MAL, and Sr-BTCA compounds. A quantity of the ligand (0.5 mmol) is dissolved in 50 mL of in-house deionized water. After the ligand dissolves, a quantity of metal hydroxide (0.5 mmol) is slowly added as a solid. The pH is adjusted to ∼5.4 with a 0.1 M NaOH solution and left to stand. After a prolonged period of time (1 day for Ca-CEPA, 30 days for Ca-MAL, and 25 days for Sr-BTCA), single crystals appeared, were isolated by filtration, and were washed with deionized water. Elemental analysis and spectroscopic characterization information are given in the Supporting Information. Ca-CIT was synthesized according to Sheldrick, B. Acta Crystallogr. 1974, B30, 2056 - 2057.
    • (1974) Acta Crystallogr. , vol.30 , pp. 2056
    • Sheldrick, B.1
  • 50
    • 84879791202 scopus 로고    scopus 로고
    • note
    • net)] 1084, no. of parameters 99, R1 = 0.0254 (0.0314, all data), wR2 = 0.0660 (0.0684, all data), GOF = 1.073.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.