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Similar synthetic protocols were used for the syntheses of Ca-CEPA, Ca-MAL, and Sr-BTCA compounds. A quantity of the ligand (0.5 mmol) is dissolved in 50 mL of in-house deionized water. After the ligand dissolves, a quantity of metal hydroxide (0.5 mmol) is slowly added as a solid. The pH is adjusted to ∼5.4 with a 0.1 M NaOH solution and left to stand. After a prolonged period of time (1 day for Ca-CEPA, 30 days for Ca-MAL, and 25 days for Sr-BTCA), single crystals appeared, were isolated by filtration, and were washed with deionized water. Elemental analysis and spectroscopic characterization information are given in the Supporting Information. Ca-CIT was synthesized according to, - 2057.
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Demadis, K. D., Neofotistou, E., Mavredaki, E., Tsiknakis, M., Sarigiannidou, E.-M., and Katarachia, S. D. Desalination 2005, 179, 281
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(2005)
Desalination
, vol.179
, pp. 281
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Demadis, K.D.1
Neofotistou, E.2
Mavredaki, E.3
Tsiknakis, M.4
Sarigiannidou, E.-M.5
Katarachia, S.D.6
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