Investigating the effect of metal oxide additives on the properties of Cu/ZnO/Al2O3 catalysts in methanol synthesis from syngas using factorial experimental design

Fuel

Volumn 89, Issue 1, 2010, Pages 170-175

  Meshkini, Fatemeh ^a   Taghizadeh, Majid ^a   Bahmani, Mohsen ^b  

^a BABOL NOSHIRVANI UNIVERSITY OF TECHNOLOGY   (Iran)

^b NATIONAL PETROCHEMICAL COMPANY   (Iran)

Author keywords

Cu ZnO Al2O3 catalysts; Factorial design; Metal oxide additives; Methanol synthesis

Indexed keywords

CATALYTIC ACTIVITY; COPRECIPITATION METHOD; CU/ZNO/AL; CU/ZNO/AL2O3 CATALYSTS; FACTORIAL DESIGN; FACTORIAL EXPERIMENTAL DESIGN; FIXED-BED REACTORS; FULL FACTORIAL DESIGN; METAL OXIDE ADDITIVES; METHANOL SYNTHESIS; OXIDE ADDITIVE; PROMOTED CATALYSTS; STRUCTURE AND MORPHOLOGY; SURFACE COMPOSITIONS; SYN-GAS;

BARIUM; CATALYSIS; CERIUM; CERIUM COMPOUNDS; CHEMICAL ANALYSIS; CHEMICAL REACTORS; CHROMIUM; CRYSTALLITE SIZE; DESIGN OF EXPERIMENTS; MANGANESE; MANGANESE COMPOUNDS; METALLIC COMPOUNDS; METHANOL; PRECIPITATION (CHEMICAL); STAINLESS STEEL; SYNTHESIS GAS MANUFACTURE; X RAY DIFFRACTION; ZIRCONIUM;

CATALYSTS;

EID: 70349439009     PISSN: 00162361     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.fuel.2009.07.007     Document Type: Article

References (25)

1. 2-effects of the calcination and reduction conditions on the catalytic performance. Appl Catal A 207 (2001) 121-128
2. 3 for methanol synthesis. Catal Lett 68 (2000) 55-58
3. 2 to methanol over supported and promoted copper-based catalysts: influence of support and promoter. Appl Catal B 29 (2001) 207-215
4. Chen H.Y., Lin J., Tan K.L., and Li J. Comparative studies of manganese-doped copper-based catalysts: the promoter effect of Mn on methanol synthesis. Appl Surf Sci 126 (1998) 323-331
5. Li J.L., and Inui T. Characterization of precursors of methanol synthesis catalysts, copper/zinc/aluminium oxides, precipitated at different pHs and temperatures. Appl Catal A 137 (1996) 105-117
6. Fang D., Liu Z., Meng S., Wang L., Xu L., and Wang H. Influence of aging time on the properties of precursors of CuO/ZnO catalysts for methanol synthesis. J Nat Gas Chem 14 (2005) 107-114
7. Sofianos A. Catalyst for synthesis of methanol. US 5,254,520, 1993.
8. 2-rich feed and from a CO-rich feed. Appl Catal A 218 (2001) 235-240
9. Takeuchi M, Mabuse H, Watanabe T, Umeno M, Matsuda T, Mori K, et al. Copper-based catalyst and method for production thereof. US 6,048,820, 2000.
10. 2. Catal Today 45 (1998) 215-220
11. Nakamura T, Tsuji K, Obata Y. Method for preparing catalyst precursor for methanol synthesis. US 5, 089,452, 1992.
12. Huang X., Ma L., and Wainwright M.S. The influence of Cr, Zn and Co additives on the performance of skeletal copper catalysts for methanol synthesis and related reactions. Appl Catal A 257 (2004) 235-243
13. 2 hydrogenation over Pd-modified methanol synthesis catalysts. Catal Today 45 (1998) 251-256
14. 2 mixtures: catalytic structures and performance. J Catal 210 (2002) 285-294
15. Tierney JW, Wender I, Palekar VM. Alkali or alkaline earth metal promoted catalyst and process for methanol synthesis using alkali or alkaline metals as promoters. US 5,385,949, 1995.
16. 2. Appl Catal A 310 (2006) 127-137
17. 2. Appl Catal A 249 (2003) 129-138
18. 2. Catal Today 63 (2000) 447-452
19. Soylak M., Tuzen M., Souza A.S., Korn M.A., and Ferreira S.L.C. Optimization of microwave assisted digestion procedure for the determination of zinc, copper and nickel in tea samples employing flame atomic absorption spectrometry. J Hazard Mater 149 (2007) 264-268
20. Yu C., Hu C., Bai A., and Yang Y. Pore-size dependence of AAO films on surface roughness of Al-1050 sheets controlled by electropolishing coupled with fractional factorial design. Surf Coat Technol 201 (2007) 7259-7265
21. 2 over Cu/ZnO catalysts prepared from various coprecipitated precursors. Catal Today 45 (1998) 241-244
22. 2 hydrogenation. Appl Catal A: General 174 (1998) 231-238
23. Viswanathan B., Sivasanker S., and Ramaswamy A.V. Catalysis principles and applications (2002), Narosa Publishing House, New Delhi
24. 2O-method for measuring cu-dispersion. Appl Catal A 266 (2004) 117-122
25. Evans J.W., Wainwright M.S., and Bridgewater A.J. On the determination of copper surface area by reaction with nitrous oxide. Appl Catal 7 (1983) 75-83