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note
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-1): 3252 (m); 2067 (vs); 2054 (vs); 1607 (m). CAUTION! Azido complexes of metal ions in the presence of organic ligands are potentially explosive. Only a small amount of material should be handled with care.
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26
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70349424045
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note
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2 = 0.1368 [I > 2σ(I)]. Intensity data for single crystal of 1 were collected using Mo Kα (λ = 0.71073 Å) radiation on a Bruker SMART APEX CCD diffractometer at 293 K. All absorption corrections were performed with SADABS program. All the structures were solved by direct methods and refined with full-matrix least-squares and expanded using Fourier techniques. The non-hydrogen atoms were refined anisotropically. Hydrogen atoms were placed in the calculate positions. All calculations were performed using SHELXTL-97 program.
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34
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70349424044
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note
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Differential thermal analysis was recorded by heating 2-3 mg of the sample at a heating rate of 2 °C/min in the presence of nitrogen. The impact sensitivity was determined by the Fall-Hammer method using 2 kg drop weight, and friction sensitivity was determined by using the Julius Peters apparatus by following standard methods.
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