A zirconium-containing sandwich-type dimer based on trivacant α- and β-[GeW9O34]10- units, [Zr3O(OH)2(α-GeW9O34)(β-GeW9O34)]12-

Inorganic Chemistry Communications

Volumn 12, Issue 10, 2009, Pages 1035-1037

  Chen, Lili ^a   Li, Lili ^a   Liu, Bin ^a   Xue, Ganglin ^a   Hu, Huaiming ^a   Fu, Feng ^b   Wang, Jiwu ^b  

^a BEIJING UNIVERSITY OF POSTS AND TELECOMMUNICATIONS   (China)

^b YAN'AN UNIVERSITY   (China)

Author keywords

Isomer; Polyoxometalates; Sandwich type; Zirconium

Indexed keywords

EID: 70349412909     PISSN: 13877003     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.inoche.2009.08.006     Document Type: Article

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28. 2 by full matrix least-squares using the SHELXTL-97 program package. Heavy atoms (Ge, W, Zr, Cs, Na, K) were refined with anisotropic displacement parameters. Oxygen atoms were refined isotropically. Hydrogen atoms were not included. As usual for most of large polyoxometalates crystallized with amounts of water, which with the counter ions fill the cavities formed by the molecular arrangement, the crystal shows some disorder in the range of counterions and water molecules, the exact composition and the number of water molecule were determined by elemental analysis and thermal analysis. Further details of the crystal structure investigation can be obtained from the Fachinformationszentrum Karlsruhe, 76344 Eggenstein-Leopoldshafen, Germany (fax: (49)7247 808 666; e-mail: crysdata@fiz-karlsruhe.de) on quoting the depository number CSD 420785.
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