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Although there is prototropy between species 10 and 4-pyridone, this was not included in Scheme 1 for clarity reasons see Chapman and Hall: London, The existence of this prototropy does not affect the kinetic results
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Although there is prototropy between species 10 and 4-pyridone, this was not included in Scheme 1 for clarity reasons (see Perrin, D. D.; Dempsey, B.; Serjeant, E. P. pKa Prediction for Organic Acids and Bases; Chapman and Hall: London, 1981; p 55). The existence of this prototropy does not affect the kinetic results.
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70349131017
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note
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10) was not included in Table 1 due to the large error involved in its determination.
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