In situ xrd study of the thermal decomposition of natural arsenian plumbojarosite

Canadian Mineralogist

Volumn 47, Issue 3, 2009, Pages 683-696

  Mills, Stuart J ^a,b,c,d   Madsen, Ian C ^c   Grey, Ian E ^c   Birch, William D ^b  

^a UNIVERSITY OF MELBOURNE   (Australia)

^b MUSEUM VICTORIA   (Australia)

^c CSIRO   (Australia)

^d UNIVERSITY OF BRITISH COLUMBIA   (Canada)

Author keywords

Amorphous phases; Arsenian plumbojarosite; In situ powder X ray diffraction; Lomo deltoro mine; Metastable phases; Mexico; Rietveld quantitative phase analysis; Thermogravimetric analysis

Indexed keywords

AMORPHOUS PHASES; ARSENIAN PLUMBOJAROSITE; IN SITU POWDER X-RAY DIFFRACTION; LOMO DELTORO MINE; MEXICO; RIETVELD QUANTITATIVE PHASE-ANALYSIS;

ARSENIC; CRYSTALLINE MATERIALS; DIFFRACTION; HEMATITE; IRON ORES; LEAD; MATHEMATICAL TRANSFORMATIONS; MINES; MINING; OXIDE MINERALS; PHOSPHATE MINERALS; PHOTORESISTS; POWDERS; PYROLYSIS; RIETVELD ANALYSIS; SODIUM; THERMOGRAVIMETRIC ANALYSIS; X RAY ANALYSIS; X RAY DIFFRACTION; X RAY POWDER DIFFRACTION;

METASTABLE PHASES;

ARSENIC; CRYSTAL STRUCTURE; DEHYDROXYLATION; HEMATITE; PARTIAL MELTING; PHASE EQUILIBRIUM; TEMPERATURE EFFECT; THERMAL DECOMPOSITION; X-RAY DIFFRACTION;

MEXICO [NORTH AMERICA]; NORTH AMERICA;

EID: 69949137242     PISSN: 00084476     EISSN: None     Source Type: Journal    
DOI: 10.3749/canmin.47.3.683     Document Type: Article

References (47)

1. BAIKIE, T., FERRARIS, C., KLOOSTER, W.T., MADHAVI, S., PRA- MANA, S.S., PRING, A., SCHMIDT, G. & WHITE, T.J. (2008): Crystal chemistry of mimetite, Pb10(AsO4)6C11.4O0 26and finnemanite, Pb10(AsO3)6C12. Acta Crystallogr. B64, 34-41.
2. BARBIER, J. (1994): Refinement of the eulytite-type Pb4(PO4)2SO4 structure. Eur. J. Solid State Inorg. Chem. 31, 163-171.
3. BARBIER, J. & MAXIN, D. (1995): Phase transformation in Pb4(PO4)2CrO4. J. Solid State Chem. 116, 179-184.
4. BEN-DOR, L., FISCHBEIN, E. & KALMAN, Z. (1976): Concerning the (3 phase of iron (III) oxide. Acta Crystallogr. B32, 667.
5. BIGHAM, J.M. & NORDSTROM, D.K. (2000): Iron and aluminum hydroxysulfates from acid sulfate waters. In Sulfate Minerals: Crystallography, Geochemistry, and Environmental Significance (C.N. Alpers, J.L. Jambor & D.K Nordstrom, eds.). Rev. Mineral. Geochem. 40, 351-403.
6. BILLHARDT, H.W. (1970): New data on basic lead sulfates. J. Electrochem. Soc: Solid State Sci. 117, 690-692.
7. BRIXNER, L.H., BIERSTEDT, P.E. & FORIS, CM. (1972): Crystal growth and properties of the lead phosphate Pb5P4O15. Mater. Res. Bull. 7, 883-889.
8. BURGINA, E. B., KUSTOVA, G. N., ISUPOVA, L. A., TSYBULYA, S. V., KRYUKOVA, G. N. & SADYKOV, V.A. (2000): Investigation of the structure of protohematite - metastable phase of ferrum (III) oxide. J. Molecular Catalysis A: Chemical 158, 257-261.
9. COELHO, A.A. (2004): TOPAS, V3.0, Broker AXS, Karlsruhe, Germany.
10. DROUET, C. & NAVROTSKY, A. (2003): Synthesis, characterization and thermochemistry of K-Na-H3O jarosites. Geochim. Cosmochim. Acta 67, 2063-2076.
11. DROUET, C., PASS, K. L., BARON, D., DRAUCKER, S. & NAV- ROTSKY, A. (2004): Thermochemistry of jarosite-alunite and natrojarosite-natroalunite solid solutions. Geochim. Cosmochim. Acta 68, 2197-2205.
12. DUTRIZAC, J.E. & CHEN, T.T. (2003): The synthesis and properties of V3+ analogues of jarosite-group minerals. Can. Mineral. 41, 479-488.
13. DUTRIZAC, J.E. & JAMBOR, J.L. (2000): Jarosites and their applications in hydrometallurgy. In Sulfate Minerals: Crystallography, Geochemistry, and Environmental Significance (C.N. Alpers, J.L. Jambor & D.K Nordstrom, eds.). Rev. Mineral. Geochem. 40, 405-452.
14. EUSDEN, J.D., JR., GALLAGHER, L., EIGHMY, T.T., CRANNELL, B.S., KRZANOWSKI, J.R., BUTLER, L.G., CARTLEDGE, F.K., EMERY, E.F., SHAW, E.L. & FRANCIS, C.A. (2002): Petrographie and spectroscopic characterization of phosphatestabilized mine tailings from Leadville, Colorado. Waste Management 22, 117-135.
15. FROST, R.L., WEIER, M. & MARTENS, W. (2005b): Thermal decomposition of jarosites of potassium, sodium and lead. J. Thermal Anal. Calorim. 82, 115-118.
16. FROST, R.L., WILLS, R.A., WEIER, M.L., MUSUMECI, A.W. & MARTENS, W. (2005a): Thermal decomposition of natural and synthetic plumbojarosites: importance in "archeo- chemistry". Thermochim. Acta 432, 30-35.
17. GARVIE, R.C. (1965): The occurrence of metastable tetragonal zirconia as a crystallite size effect. J. Phys. Chem. 69, 1238-1243.
18. GROHOL, D. & NOCERA, D.G. (2002): Hydrothermal oxidation-reduction methods for the preparation of highly pure and single crystalline alunites: synthesis and characterization of a new series of vanadium jarosites. J. Am. Chem. Soc. 124, 2640-2646.
19. GUALTIERI, A.F. & VENTURELLI, P. (1999): In situ study of the goethite-hematite phase transformation by real time synchrotron powder diffraction. Am. Mineral. 84, 895-904.
20. HILL, R.J., CRAIG, R.C. & GIBBS, G.V. (1979): Systematics of the spinel structure type. Phys. Chem. Minerals 4, 317-339.
21. HILL, R.J. & HOWARD, C.J. (1987): Quantitative phase analysis from neutron powder diffraction data using the Rietveld method. J. Appl. Crystallogr. 20, 467-474.
22. JACOBSEN, S.D., SMYTH, J.R., SOPE, R.J. & DOWNS, R.T. (1998): Rigid-body character of the SO4 groups in celestine, anglesite and barite. Can. Mineral. 36, 1053-1060.
23. JAMBOR, J.L. (1999): Nomenclature of the alunite supergroup. Can. Mineral. 37, 1323-1341.
24. KLINGELHÖFER, G., MORRIS, R.V., BERNHARDT, B., SCHRÖDER, C., RODINOV, D.S., DE SOUZA, P.A., YEN, A., GELLERT, R., EVLANOV, E.N., ZUBKOV, B., FOH, J., BONNES, U., KAN- KELEIT, E., GÜTLICH, P., MING, D.W., RENZ, F., WDOWIAK, T., SQUYRES, S.W. & ARVIDSON, R.E. (2004): Jarosite and hematite at Meridiani Planum from Opportunity's Mössbauer spectrometer. Science 306, 1740-1745.
25. KOLITSCH, U. & PRING, A. (2001): Crystal chemistry of the crandallite, beudantite and alunite groups: a review and evaluation of the suitability as storage materials for toxic metals. J. Mineral. Petrol. Sci. 96, 67-78.
26. KRIVOVICHEV, S.V. & BURNS, P.C. (2003): Crystal chemistry of lead oxide phosphates: crystal structures of Pb4O(PO4)2, Pb8O5(PO4)2 and Pb10(PO4)6O. Z. Kristallogr. 218, 357-365.
27. MADSEN, I.C. & SCARLETT, N.V.Y. (2008): Quantitative phase analysis. In Powder Diffraction: Theory and Practice (R.E. Dinnebier & S. Billinge, eds.). Royal Society of Chemistry, Cambridge, U.K. (298-331).
28. MADSEN, I.C., SCARLETT, N.V.Y. & WHITTINGTON, B.I. (2005): Pressure acid leaching of nickel laterite ores: an in situ diffraction study of the mechanism and rate of reaction. J. Appl. Crystallogr. 38, 927-933.
29. MAJZLAN, J., STEVENS, R., BOERIO-GOATES, J., WOODFIELD, B.F., NAVROTSKY, A., BURNS, P.C., CRAWFORD, M.K. & AMOS, T.G. (2004): Thermodynamic properties, low-temperature heat capacity anomalies, and single crystal X-ray refinement of hydronium jarosite, (H3O)Fe3(SO4)2(OH)6. Phys. Chem. Minerals 31, 518-531.
30. MCHALE, J.M., AUROUX, A., PEROTTA, A.J. & NAVROTSKY, A. (1997): Surface energies and thermodynamic phase stability on nanocrystalline aluminas. Science 277, 788-791.
31. NORDSTROM, D.K., ALPERS, C.N., PTACEK, C.J. & BLOWES D.W. (2000): Negative pH and extremely acidic mine waters from Iron Mountain, California. Environ. Sci. Technol. 34, 254-258.
32. NORTON, G.A., RICHARDSON, R.G., MARKUSZEWSKI, R. & LEVINE, A.D. (1991): Precipitation of jarosite compounds as a method for removing impurities from acid wastes from chemical coal cleaning. Environ. Sci. Technol. 25, 449-455.
33. ÓZACAR, M., ALP, A. & AYDIN, A.O. (2000): Kinetics of thermal decomposition of plumbojarosite. J. Thermal Anal. Calorim. 59, 869-875.
34. PANCZNER, W.D. (1987): Minerals of Mexico. Van Nostrand Reinhold Company, New York, N.Y.
35. PAPIKE, J.J., BURGER, P.V., KARNER, J.M., SHEARER, C.K. & LUETH, V.W. (2007): Terrestrial analogs of Martian jarosites: major, minor element systematics and Na-K zoning in selected samples. Am. Mineral. 92, 444-447.
36. PAPIKE, J.J., KARNER, J.M., SPILDE, M.N. & SHEARER, C.K. (2006): Terrestrial analogs of Martian sulfates: major and minor element systematics of alunite-jarosite from Gold- field, Nevada. Am. Mineral. 91, 1197-1200.
37. RIETVELD, H. M. (1969): A profile refinement method for nuclear and magnetic structures. J. Appl. Crystallogr. 2, 65-71.
38. SCARLETT, N.V.Y., MADSEN, I.C., POWNCEBY, M.I. & CHRIS- TENSEN, A.N. (2004): In situ X-ray diffraction analysis of iron ore sinter phases. J. Appl. Crystallogr. 37, 362-368.
39. SCOTT, K.M. (1987): Solid solution in, and classification of gossan-derived members of the alunite-jarosite family, northwest Queensland, Australia. Am. Mineral. 72, 178-187.
40. SEGAL, D.J., SANTORO, R.P. & NEWNHAM, R.E. (1966): Neutron-diffraction study of Bi4Si3O12. Z. Krlstallogr. 123, 73-76.
41. SHPANCHENKO, R.V., PANIN, R.V., HADERMANN, J., BOUGEROL, C., TAKAYAMA-MUROMACHI, E. & ANTIPOV, E.V. (2005): Synthesis and structure investigation of the Pb3V(PO4)3eulytite. J. Solid State Chem. 178, 3715-3721.
42. SzYMÁNSKI, J.T. (1985): The crystal structure of plumbojarosite Pb[Fe3(SO4)2(OH)6]2. Can. Mineral. 23, 659-668.
43. WOLSKA, E. (1981): The structure of hydrohematite. Z. Kristallogr. 154, 69-75.
44. WOLSKA, E. & SCHWERTMANN, U. (1989): Nonstoichiometric structures during dehydroxylation of goethite. Z. Kristallogr. 189, 69-75.
45. YOUNG, R.A. (1993): The Rietveld Method. Oxford University Press, Oxford, U.K.
46. ZBORIL, R., MASHLAN, M., KRAUSOVA, D. & PIKAL, P. (1999): Cubic β-Fe2O3 as the product of the thermal decomposition of Fe2(SO4)3. Hyperfine Interactions 120-121, 497-501.
47. ZHANG, HENGZHONG & BANFIELD, J.F. (1998): Thermodynamic analysis of phase stability of nanocrystalline titania. J. Mater. Chem. 8, 2073-2076.