Glycosylations of tertiary alcohols: Synthesis of fully protected disaccharides with sterically demanding groups attached to the sugar core

Synthesis

Volumn , Issue 15, 2009, Pages 2596-2604

  Holkenbrink, Annika ^a   Vicente, Jordi Bertrán ^a   Werz, Daniel B ^a  

^a UNIVERSITY OF GÖTTINGEN   (Germany)

Author keywords

Carbohydrates; Glycosides; Glycosylation; Steric hindrance

Indexed keywords

FULLY PROTECTED; GLYCOSIDES; GLYCOSYL; GLYCOSYLATIONS; STERIC HINDRANCE; STERIC HINDRANCES; STERICALLY DEMANDING; TERTIARY ALCOHOLS; TRICHLOROACETIMIDATES;

ESTERIFICATION; GLYCOSYLATION; ORGANIC COMPOUNDS; POLYSACCHARIDES; SUGAR (SUCROSE); SYNTHESIS (CHEMICAL);

SUGARS;

ALCOHOL; ALCOHOL DERIVATIVE; DISACCHARIDE; DISACCHARIDE DERIVATIVE; GALACTOPYRANOSIDE; GLUCOPYRANOSIDE; GLYCOSYL PHOSPHATE DERIVATIVE; GLYCOSYL TRICHLOROACETIMIDATE DERIVATIVE; METHYL 2 2 BENZOYL 3,4,6 TRI 2 BENZYL ALPHA D MANNOPYRANOSYL (1 4) 2,3,6 TRI 2 BENZYL 4 METHYL ALPHA D GLUCOPYRANOSIDE; METHYL 2,3,4 TRI 2 ACETYL ALPHA RHAMNOPYRANOSYL (1 4) 2,3,6 TRI 2 BENZYL 4 BUTYL ALPHA D GALACTOPYRANOSIDE; METHYL 2,3,4 TRI 2 ACETYL ALPHA RHAMNOPYRANOSYL (1 4) 2,3,6 TRI 2 BENZYL 4 BUTYL ALPHA D GLUCOPYRANOSIDE; METHYL 2,3,4 TRI 2 ACETYL ALPHA RHAMNOPYRANOSYL (1 4) 2,3,6 TRI 2 BENZYL 4 PHENYLETHYNYL ALPHA D GALACTOPYRANOSIDE; METHYL 2,3,4 TRI 2 ACETYL ALPHA RHAMNOPYRANOSYL (1 4) 2,3,6 TRI 2 BENZYL 4 TRIMETHYLSILYLETHYNYL ALPHA D GALACTOPYRANOSIDE; METHYL 2,3,4 TRI 2 ACETYL ALPHA RHAMNOPYRANOSYL (1 4) 2,3,6 TRI 2 BENZYL 4 TRIMETHYLSILYLETHYNYL ALPHA D GLUCOPYRANOSIDE; METHYL 2,3,4,6 TETRA 2 ACETYL BETA D GALACTOPYRANOSYL (1 4) 2,3,6 TRI 2 BENZYL 4 PHENYLETHYNYL ALPHA D GALACTOPYRANOSIDE; METHYL 2,3,4,6 TETRA 2 ACETYL BETA D GALACTOPYRANOSYL (1 4) 2,3,6 TRI 2 BENZYL 4 TRIMETHYLSILYLETHYNYL ALPHA D GALACTOPYRANOSIDE; METHYL 2,3,4,6 TETRA 2 ACETYL BETA D GLUCOPYRANOSYL (1 4) 2,3,6 TRI 2 BENZYL 4 PHENYLETHYNYL ALPHA D GALACTOPYRANOSIDE; METHYL 2,3,4,6 TETRA 2 ACETYL BETA D GLUCOPYRANOSYL (1 4) 2,3,6 TRI 2 BENZYL 4 TRIMETHYLSILYLETHYNYL ALPHA D GALACTOPYRANOSIDE; METHYL 2,3,6 TRI 2 BENZYL 4 BUTYL ALPHA D GALACTOPYRANOSIDE; METHYL 2,3,6 TRI 2 BENZYL 4 BUTYL ALPHA D GLUCOPYRANOSIDE; METHYL 2,3,6 TRI 2 BENZYL 4 METHYL ALPHA D GALACTOPYRANOSIDE; METHYL 2,3,6 TRI 2 BENZYL 4 METHYL ALPHA D GLUCOPYRANOSIDE; METHYL 2,3,6 TRI 2 BENZYL 4 PHENYLETHYNYL ALPHA D GALACTOPYRANOSIDE; METHYL 2,3,6 TRI 2 BENZYL 4 PHENYLETHYNYL ALPHA D GLUCOPYRANOSIDE; METHYL 2,3,6 TRI 2 BENZYL 4 TRIMETHYLSILYLETHYNYL ALPHA D GALACTOPYRANOSIDE; METHYL 2,3,6 TRI 2 BENZYL 4 TRIMETHYLSILYLETHYNYL ALPHA D GLUCOPYRANOSIDE; METHYL 3,4,6 TRI 2 ACETYL 2 N TRICHLOROACETYL BETA D GLUCOSAMINO (1 4) 2,3,6 TRI 2 BENZYL 4 TRIMETHYLSILYLETHYNYL ALPHA D GALACTOPYRANOSIDE; PHOSPHATE; PYRANOSIDE; SUGAR; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; GLYCOSYLATION; ISOLATION PROCEDURE; STEREOCHEMISTRY; SYNTHESIS;

EID: 69749096439     PISSN: 00397881     EISSN: 1437210X     Source Type: Journal    
DOI: 10.1055/s-0029-1217403     Document Type: Article

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