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Volumn 15, Issue 34, 2009, Pages 8593-8604

Divalent E(0) compounds (E = Si-Sn)

Author keywords

Density functional calculations; Divalent e(0) compounds; Metal complexes; Proton affinity; Ylidone

Indexed keywords

BOND DISSOCIATION ENERGIES; BONDING SITUATION; CONDENSED PHASE; DENSITY FUNCTIONAL CALCULATIONS; DIVALENT E(0) COMPOUNDS; DONOR LIGANDS; DONOR-ACCEPTOR INTERACTION; LEWIS ACID; LONE PAIR; METAL CARBONYL; N-HETEROCYCLIC; O-DONOR; PROTON AFFINITY; QUANTUM-CHEMICAL CALCULATION; THEORETICAL RESULT; TRANSITION-METAL COMPLEX; VALENCE ELECTRON; YLIDONE;

EID: 69249119866     PISSN: 09476539     EISSN: 15213765     Source Type: Journal    
DOI: 10.1002/chem.200901401     Document Type: Article
Times cited : (124)

References (34)
  • 12
    • 0013464786 scopus 로고    scopus 로고
    • (Ed.: G. Bertrand), New York
    • b) Carbene Chemistry (Ed.: G. Bertrand), Marcel Dekker, New York, 2002;
    • (2002) Carbene Chemistry
    • Dekker, M.1
  • 29
    • 69249145619 scopus 로고    scopus 로고
    • 2 symmetry lacking a mirror plane there are no genuine n and a orbitais which are defined as being antisymmetric or symmetric with respect to a molecular plane. The shape of the orbitais which are shown in Figure 3 makes it possible, however, to classify the orbitais as π- or σ-type MOs.
    • 2 symmetry lacking a mirror plane there are no genuine n and a orbitais which are defined as being antisymmetric or symmetric with respect to a molecular plane. The shape of the orbitais which are shown in Figure 3 makes it possible, however, to classify the orbitais as π- or σ-type MOs.
  • 30
    • 0030862650 scopus 로고    scopus 로고
    • It has been shown that the n donor strength of an atom which carries a lone electron pair increases in the periodic system from top to the bottom: G. Frenking, S. Fau, C. M. Marchand, H. Grützmacher
    • It has been shown that the n donor strength of an atom which carries a lone electron pair increases in the periodic system from top to the bottom: G. Frenking, S. Fau, C. M. Marchand, H. Grützmacher, J. Am. Chem. Soc. 1997, 119, 6648.
    • (1997) J. Am. Chem. Soc. , vol.119 , pp. 6648
  • 31
    • 69249137876 scopus 로고    scopus 로고
    • 3 ligand and 1.0 À below the plane. The very large differences between the NICS values for the two different sides suggest that the molecule exhibits little if any aromaticity.
    • 3 ligand and 1.0 À below the plane. The very large differences between the NICS values for the two different sides suggest that the molecule exhibits little if any aromaticity.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.