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Another approach is the Peterson olefination of (methylthio)(trimethylsilyl)methylphosphonate with thioketones, but this method suffers from low yields:
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In addition to the disubstituted diazomethanes 7a-g, monosubstituted diazomethanes such as diazoethane, methyl diazoacetate, and diethyl diazomethyl phosphonate were tested in reactions with 6. In all cases, complex mixtures of products were formed.
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