A monomeric perfluoroalkyl iridium(III) amido complex with an Ir=N double bond and its reactions to activate sp 3 carbon - Hydrogen bonds at room temperature

Organometallics

Volumn 28, Issue 16, 2009, Pages 4646-4648

  Yuan, Jian ^a   Hughes, Russell P ^a   Rheingold, Arnold L ^b  

^a Lamont Doherty Earth Observatory   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMIDO COMPLEXES; C-H BOND; CARBON-HYDROGEN BOND; DFT CALCULATION; DOUBLE BONDS; ROOM TEMPERATURE; TERMINAL ALKENES;

DYES; HYDROGEN; HYDROGEN BONDS; IRIDIUM; OLEFINS; SULFUR COMPOUNDS; X RAY CRYSTALLOGRAPHY;

IRIDIUM COMPOUNDS;

EID: 68949186646     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om900657f     Document Type: Article

References (21)

1. Nugent, W. A.; Mayer, J. M., Metal-Ligand Multiple Bonds; Wiley: New York, 1988.
2. Richl, J.-F.; Jean, Y.; Eiscnstein, O.; Pélissier, M. Organometallics 1992, 11, 729-737.
3. Lunder, D. M.; Lobkovsky, E. B.; Streib, W. E.; Caulton, K. G. J. Am. Chem. Soc. 1991, 113, 1837-1838.
4. Holland, P. L.; Andersen, R. A.; Bergman, R. G. Comments Inorg. Chem. 1999, 21, 115-129.
5. Hughes, R. P.; Lindner, D. C.; Liable-Sands, L. M.; Rheingold, A. L. Organometallics 2001, 20, 363-366.
6. Hughes, R. P.; Smith, J. M.; Liable-Sands, L. M.; Concolino, T. E.; Lam, K.-C.; Incarvito, C.; Rhcingold, A. L. Dalton Trans. 2000, 873-879.
7. Glueck, D. S.; Hollander, F. J.; Bergman, R. G. J. Am. Chem. Soc. 1989, 111, 2719-2721.
8. Glueck, D. S.; Wu, J.; Hollander, F. J.; Bergman, R. G. J. Am. Chem. Soc. 1991, 113, 2041-2054.
9. Kanzelberger, M.; Zhang, X.; Emge, T. J.; Goldman, A. S.; Zhao, J.; Incarvito, C.; Hartwig, J. F. J. Am. Chem. Soc. 2003, 125, 13644-13645.
10. Zhao, J.; Goldman, A. S.; Hartwig, J. F. Science 2005, 307, 1080-1082.
11. Stykes, A. C.; White, P.; Brookhart, M. Organometallics 2006, 25, 1664-1675.
12. Details of the DFT calculations appear in the Supporting Information.
13. Glendening, E. D.; Badenhoop, J. K.; Reed, A. K.; Carpenter, J. E.; Bohmann, J. A.; Morales, C. M.; Weinhold, F. NBO 5.0; Theoretical Chemistry Institute, University of Wisconsin, Madison, WI, 2001.
14. Legzdins, P.; Rettig, S. J.; Ross, K. J. Organometallics 1993, 12, 2103-2110.
15. Li, D.; Keresztes, I.; Hopson, R.; Williard, P. G. Acc. Client. Res. 2009, 42, 270-280.
16. Li, D.; Kagan, G.; Hopson, R.; Williard, P. G. J. Am. Chem. Soc. 2009, 131, 5627-5634.
17. Rais, D.; Bergman, R. G. Chem. Eur, J. 2004, 10, 3970-3978.
18. Nishijo, J.; Nishi, N. Eur, J. Inorg. Chem. 2006, 3022-3027.
19. Durán, M. L.; Garcia-Vázquez, J. A.; Gómez, C.; Sousa-Pcdrarcs, A.; Romero, J.; Sousa, A. Eur, J. Inorg, Chem. 2002, 2348-2354.
20. Foley, N. A.; Gunnoe, T. B.; Cundari, T. R.; Boyle, P. D.; Petersen, J. L. Angew. Chem., Int. Ed. 2008, 47, 726-730.
21. McGhee, W. D.; Bergman, R. G. J. Am. Chem. Soc. 1988, 110, 4246-4262.