The synthesis of polyoxygenated, enantiomerically pure cyclopentane derivatives on route to neplanocin A stereoisomers via alkylidenecarbene species prepared from sugar templates

Carbohydrate Research

Volumn 344, Issue 13, 2009, Pages 1605-1611

  Nguyen Van Nhien, Albert ^a   Soriano, Elena ^b   Marco Contelles, José ^b   Postel, Denis ^a  

^a UNIVERSITÉ DE PICARDIE JULES VERNE   (France)

^b INSTITUTO DE QUÍMICA ORGÁNICA GENERAL   (Spain)

Author keywords

Cyanomesylates; 1,5 C H bond insertion reactions; Alkylidenecarbenes; DFT analysis; Neplanocin A stereoisomers; Polyhydroxylated cyclopentanes

Indexed keywords

1,5 C-H BOND INSERTION REACTIONS; ALKYLIDENECARBENES; DFT ANALYSIS; NEPLANOCIN A STEREOISOMERS; POLYHYDROXYLATED CYCLOPENTANES;

HYDROXYLATION; ISOMERS; PROBABILITY DENSITY FUNCTION; SPECTROSCOPIC ANALYSIS; STEREOSELECTIVITY; SUGAR (SUCROSE);

SUGARS;

ALKYLIDENECARBENE; CARBENOID; CYCLOPENTANE DERIVATIVE; MANNOSE; NEPLANOCIN A; POLYOL; SUGAR; TRIMETHYLSILYL DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL REACTION; ENANTIOMER; PRIORITY JOURNAL; PROTON NUCLEAR MAGNETIC RESONANCE; STEREOCHEMISTRY; STEREOISOMERISM; SYNTHESIS; TRANS ISOMER;

ADENOSINE; CARBOHYDRATES; CYCLOPENTANES; MAGNETIC RESONANCE SPECTROSCOPY; METHANE; MODELS, MOLECULAR; MOLECULAR CONFORMATION; OXYGEN; QUANTUM THEORY; STEREOISOMERISM;

EID: 68949166344     PISSN: 00086215     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.carres.2009.04.006     Document Type: Article

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