Insights into the nature of Mo(V) species in solution: Modeling catalytic cycles for molybdenum enzymes

Inorganica Chimica Acta

Volumn 362, Issue 12, 2009, Pages 4603-4608

  Rajapakshe, Asha ^a   Snyder, Rae Ana ^a   Astashkin, Andrei V ^a   Bernardson, Pablo ^a   Evans, David J ^b   Young, Charles G ^b   Evans, Dennis H ^a   Enemark, John H ^a  

^a University of Arizona   (United States)

^b UNIVERSITY OF MELBOURNE   (Australia)

Author keywords

Cyclic voltammetry; Density functional theory; EPR; Oxo Mo compounds; Trispyrazolyl borates

Indexed keywords

ACETONITRILE; CRYSTAL STRUCTURE; CYCLIC VOLTAMMETRY; ELECTRON SPIN RESONANCE SPECTROSCOPY; ELECTRON TRANSITIONS; MOLYBDENUM OXIDE; PARAMAGNETIC RESONANCE; PROTONATION; REDUCTION; VANADIUM DIOXIDE;

ELECTRON-PROTON TRANSFERS; MOLYBDENUM ENZYMES; MONONUCLEAR COMPOUNDS; ONE-ELECTRON REDUCTIONS; OXO-MO COMPOUNDS; POSITIVE POTENTIAL; TRISPYRAZOLYL BORATES; TRISPYRAZOLYLBORATE;

DENSITY FUNCTIONAL THEORY;

EID: 68849099638     PISSN: 00201693     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.ica.2009.05.040     Document Type: Article

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