Synthesis of multi-arm-star polyglycidols of different architecture grafted with polyacrylate side arms

European Polymer Journal

Volumn 45, Issue 9, 2009, Pages 2529-2539

  Schmitz, Christof ^a   Keul, Helmut ^a   Möller, Martin ^a  

^a RWTH AACHEN UNIVERSITY   (Germany)

Author keywords

Anionic ring opening polymerisation; Atom transfer radical polymerisation (ATRP); Graft copolymers; Polymer analogous reaction; Star shaped polymers

Indexed keywords

1-PROPANOL; ANIONIC RING-OPENING POLYMERISATION; ATOM TRANSFER RADICAL POLYMERISATION; ATOM TRANSFER RADICAL POLYMERISATION (ATRP); CONTROLLED SYNTHESIS; GLYCIDYL ETHERS; HYDROXYL GROUPS; KINETIC STUDY; MALDI-TOF; METHYL ACRYLATES; MULTIFUNCTIONAL INITIATORS; NMR SPECTROSCOPY; POLYMER ANALOGOUS REACTION; POLYMERISATION; PROTECTION GROUP; RING OPENING; STAR SHAPED POLYMERS; TERT-BUTYL ACRYLATE; TRIMETHYLOLPROPANE;

ARCHITECTURAL DESIGN; ATOMIC SPECTROSCOPY; ATOMS; CHROMATOGRAPHIC ANALYSIS; COPOLYMERIZATION; ESTERS; ETHERS; FREE RADICAL REACTIONS; GRAFT COPOLYMERS; GRAFTING (CHEMICAL); LIQUID CRYSTAL POLYMERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANIC POLYMERS; POLYMERS; SIZE EXCLUSION CHROMATOGRAPHY;

ATOM TRANSFER RADICAL POLYMERIZATION;

EID: 68549128650     PISSN: 00143057     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.eurpolymj.2009.06.005     Document Type: Article

References (31)

1. Islam M.T., Archer J., and Archer L.A. Linear rheology of entangled six-arm and eight-arm polybutadiens. Macromolecules 34 (2001) 6438-6449
2. Pakula T., Vlassopoulos D., Fytas G., and Roovers J. Structure and dynamics of melts of multiarm polymer stars. Macromolecules 31 (1998) 8931-8940
3. Roovers J., Zhou L.-L., Toporowski M., Zwan M.v.d., Iatrou H., and Hadjichristidis N. Regular star polymers with 64 and 128 arms. Models for polymeric micelles. Macromolecules 26 (1993) 4324-4331
4. Gao H., and Matyjaszewski K. Synthesis of star polymers by a new, core first method: sequential polymerisation of cross-linker and monomer. Macromolecules 41 (2008) 1118-1125
5. Kanaoka S., Sawamoto M., and Higashimura T. Star-shaped polymer by living cationic polymerisation. 1. Synthesis of star-shaped polymers of alkyl vinyl ethers. Macromolecules 24 (1991) 2309-2313
6. Xia J., Zhang X., and Matyjaszewski K. Synthesis of star-shaped polystyrene by atom transfer radical polymerisation using an "Arm First" approach. Macromolecules 32 (1999) 4482-4484
7. Whittaker M.R., Urbani C.N., and Monteiro M.J. Synthesis of 3-miktoarm stars and 1st generation mikto dendritic copolymers by "living" radical polymerisation and "click" chemistry. J Am Chem Soc 128 (2006) 13360-13361
8. Goa H., and Matyjaszewski K. Synthesis of star polymers by a combination of atrp and the "click" coupling method. Macromolecules 39 (2006) 4960-4965
9. Ueda J., Matsuyama M., Kamigaito M., and Sawamoto M. Multifunctional initiators for the ruthenium-mediated living radical polymerisation of methyl methacrylate: di- and trifunctional dichloroacetates fort he synthesis of multiarmed polymers. Macromolecules 31 (1998) 557-562
10. Angot S., Murthy S., Taton D., and Gnanou Y. Atom transfer radical polymerisation of styrene using a novel octafunctional initiator: synthesis of well-defined polystyrene stars. Macromolecules 31 (1998) 7218-7225
11. Comanita B., Noren B., and Roover J. Star poly(ethylene oxide)s from carbosilane dendrimers. Macromolecules 32 (1999) 1069-1072
12. Magnusson H., Malmström E., and Hult A. Synthesis of hyperbranched aliphatic polyethers via cationic ring-opening polymerisation of 3-ethyl-3-(hydrocymethyl)oxetane. Macromol Rapid Commun 20 (1999) 453-457
13. Weberskirch R., Hettich R., Nuyken O., Schmaljohann D., and Voigt B. Synthesis of new amphiphilic star polymers derived from a hyperbranched macroinitiator by the cationic "grafting from" method. Macromol Chem Phys 200 (1999) 863-873
14. Sunder A., Hanselmann R., Frey H., and Mülhaupt R. Controlled synthesis of hyperbranched polyglycerols by ring-opening multibranching polymerisation. Macromolecules 32 (1999) 4240-4246
15. Knischa R., Lutz P., Sunder A., Mülhaupt R., and Frey H. Functional poly(ethylene oxide) multiarm star polymers: core-first synthesis using hyperbranched polyglycerol initiators. Macromolecules 33 (2000) 315-320
16. Burgath A., Sunder A., Neuner I., Mülhaupt R., and Frey H. Multi-arm star block copolymers based on ε-caprolactone with hyperbranched polyglycerol core. Macromol Chem Phys 201 (2000) 792-797
17. Gottschalk C., Wolf F., and Frey H. Multi-arm star poly(l-lactide) with hyperbranched polyglycerol core). Macromol Chem Phys 208 (2007) 1657-1665
18. Beers K.L., Gaynor S.G., Matyjaszewski K., Sheiko S., and Möller M. The synthesis of densely grafted copolymers by atom transfer radical polymerisation. Macromolecules 31 (1998) 9413-9415
19. Cheng G., Böker A., Zhang M., Krausch G., and Müller A.H.E. Amphiphilic cylindrical core-shell via a "grafting from" process using ATRP. Macromolecules 34 (2001) 6883-6888
20. Shen Z., Barriau E., and Frey H. Multi-arm star poly(glycerol)-block-poly (tert-butyl acrylate) and the respective multi-arm poly(acrylic acid) stars. Macromol Chem Phys 207 (2006) 57-64
21. Maier S., Sunder A., Frey H., and Mülhaupt R. Synthesis of poly(glycerol)-block-poly(methyl acrylate) multi-arm star polymers. Maromol Rapid Commun 21 (2000) 226-230
22. Chen Y., Shen Z., Barriau E., Kautz H., and Frey H. Synthesis of multiarm star poly(glycerol)-block-poly(2-hydroxyethyl methacrylate). Biomacromolecules 7 (2006) 919-926
23. Haddleton D.M., Kukulj D., Kelly E.J., and Waterson C. Glucose derived star polymers by atom transfer polymerization. Polym Mater Sci Eng 80 (1999) 145-146
24. Dworak A., Panchev I., Trzebicka B., and Walach W. Poly(α-t-butoxy-ω-styryol-glycidol): a new reactive surfactant. Polym Bull 40 (1998) 461-468
25. Taton D., Borgne A.L., Sepulchre M., and Spassky N. Synthesis of chiral racemic functional polymers from glycidol and thioglycidol. Macromol Chem Phys 195 (1994) 139-148
26. Hans M., Gasteier P., Keul H., and Moeller M. Ring-opening polymerisation of ε-caprolactone by means of mono and multifunctional initiators: comparison of chemical and enzymatic catalysis. Macromolecules 39 (2006) 3184-3193
27. Li P., Li Z., and Huang J. Water-soluble star brush copolymer with four arms composed of poly(ethylene oxide) as backbone and poly(acrylic acid) as side chains. Macromolecules 40 (2007) 491-498
28. Fitton A.O., Hill J., Jane D.E., and Millar R. Synthesis of simple oxetanes carrying reactive 2-substituents. Synthesis (1997) 1140-1142
29. Woodworth B.E., Metzner Z., and Matyjaszewski K. Copper triflate as a catalyst in atom transfer radical polymerisation of styrene and methyl acrylate. Macromolecules 31 (1998) 7999-8004
30. Zhang X., Xia J., and Matyjaszewski K. End-functional poly(tert-butyl acrylate) star polymers by controlled radical polymerisation. Macromolecules 33 (2000) 2340-2345
31. Renterghem L.M., Lammens M., Dervaux B., Viville P., Lazzaroni R., and Du Prez F.E. Design and use of organic nanoparticles prepared from star-shaped polymers with reactive end groups. J AM Chem Soc 130 (2008) 10802-10811