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This article is part of a Special Issue dedicated to Professor
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This article is part of a Special Issue dedicated to Professor T. Ziegler.
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Ziegler, T.1
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68349111168
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We use the common cis/trans nomenclature for butadiene instead of the IUPAC-recommended s-cis/s-trans nomenclature in keeping with the conventions of the polyolefins research community
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We use the common cis/trans nomenclature for butadiene instead of the IUPAC-recommended s-cis/s-trans nomenclature in keeping with the conventions of the polyolefins research community
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The use of the cis/trans nomenclature for the allyl derived from butadiene is retained here although this is contrary to IUP AC standards, which recommend use of the syn/anti nomenclature. However, it allows us to discuss allyls derived from cis- and frarcs-butadiene without having to switch to the designators anti and syn, respectively
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The use of the cis/trans nomenclature for the allyl derived from butadiene is retained here although this is contrary to IUP AC standards, which recommend use of the syn/anti nomenclature. However, it allows us to discuss allyls derived from cis- and frarcs-butadiene without having to switch to the designators anti and syn, respectively.
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Butadiene π-complexes of the monomeric allyl lithium species are only marginally stable, with binding energies greater than -10 kJ/mol. Thus, they are not stable enough to form stable species at room temperature and may be ignored for the calculation of insertion barriers.
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Butadiene π-complexes of the monomeric allyl lithium species are only marginally stable, with binding energies greater than -10 kJ/mol. Thus, they are not stable enough to form stable spe
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