Oxidation of polystyrene aerosols by VUV-photolysis and/or ozone

Photochemical and Photobiological Sciences

Volumn 8, Issue 7, 2009, Pages 944-952

  Vicente, José Salas ^a,b   Gejo, Juan López ^a,c   Rothenbacher, Sonja ^a   Sarojiniamma, Sumalekshmy ^a,d   Gogritchiani, Eliso ^a,e   Wörner, Michael ^a   Kasper, Gerhard ^a   Braun, André M ^a  

^a UNIVERSITY OF KARLSRUHE   (Germany)

^b UV Consulting Peschl España S L   (Spain)

^c UNIVERSIDAD COMPLUTENSE DE MADRID   (Spain)

^d GEORGIA INSTITUTE OF TECHNOLOGY   (United States)

^e Reuter Chemische Apparatebau KG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CARBONYL DERIVATIVE; HYDROXYL GROUP; OXYGEN; OZONE; POLYMER; POLYSTYRENE; WATER;

AEROSOL; AIRBORNE PARTICLE; ARTICLE; CONTROLLED STUDY; GAS; INFRARED SPECTROSCOPY; LIGHT ABSORPTION; OXIDATION KINETICS; OXYGEN CONCENTRATION; PARTICLE SIZE; PHOTOLYSIS; PHOTOOXIDATION; PRIORITY JOURNAL; RADIATION ENERGY; ULTRAVIOLET IRRADIATION; VACUUM;

EID: 68149160051     PISSN: 1474905X     EISSN: 14749092     Source Type: Journal    
DOI: 10.1039/b902749a     Document Type: Article

References (42)

1. J. Fu J. Fiegel J. Hanes Synthesis and characterization of PEG based ether-anhydride terpolymers: New polymers for controlled drug delivery Macromolecules 2004 37 7174 7180
2. J.-Y. Kim J. Wainaina J.-H. Kim J.-K. Shim Use of polymer nanoparticles as functional nano-absorbents for low-molecular weight hydrophobic pollutants J. Nanosci. Nanotechnol. 2007 7 4000 4004
3. S. Saliterman, Fundamentals of BioMEMS and Medical Microdevices, SPIE Press, Bellingham WA, 98225-6705, USA, 2006
4. I. Willner B. Willner Functional nanoparticle architectures for sensoric, optoelectronic and bioelectronic applications Pure Appl. Chem. 2002 74 1773 1783
5. R. Jordan N. West A. Ulman Y.-M. Chou O. Nuyken Nanocomposites by surface-initiated living cationic polymerization of 2-oxazolines on functionalized gold nanoparticles Macromolecules 2001 34 1606 1611
6. C. Pichot Position paper: functional polymer latexes Polym. Adv. Technol. 1995 6 427 434
7. T. Dey Polymer-coated magnetic nanoparticles: surface modification and end-functionalization J. Nanosci. Nanotechnol. 2006 6 2479 2483
8. R. Pearson G. Langer Generation of aerosols by vapour-phase polymerization of methyl acrylate Nature 1960 187 235
9. R. Partch E. Matijevi A. W. Hodgson B. E. Aiken Preparation of polymer colloids by chemical reactions in aerosols. I. Poly,(p-tertiarybutylstyrene) J. Polym. Sci., Polym. Chem. Ed. 1983 21 961
10. C. Esen G. Schweiger Preparation of Monodisperse Polymer Particles by Photopolymerization J. Colloid Interface Sci. 1996 179 276 280
11. 2 laser-induced formation of copolymeric ultrafine particles in a gaseous tetraethenylgermane- carbon disulfide mixture J. Photochem. Photobiol., A 2005 171 21 26
12. D. Lösch, V. Seidl and M. Rübenacker, Process for production of polymer powders containing vinylformamide units, BASF AG, Publ. Nr. WO/2007/054442, Intl. Appl. No.: PCT/EP2006/067866, 08.11.2005
13. A. Hozumi H. Inagaki T. Kameyama The hydrophilization of polystyrene substrates by 172 nm vacuum ultraviolet light J. Colloid Interface Sci. 2004 278 383 392
14. V. M. Graubner R. Jordan O. Nuyken B. Schnyder T. Lippert R. Kötz A. Wokaun Photochemical modification of cross-linked poly(dimethylsiloxane) by irradiation at 172 nmn Macromolecules 2004 37 5936 5943
15. J. López Gejo, Applications of the VUV-photochemically initiated oxidation for waste gas treatment and surface functionalization, Dissertation, Fakultät für Chemieingenieurwesen und Verfahrenstechnik, Universität Karlsruhe, Karlsruhe, 2005
16. J. López Gejo H. Glieman T. Schimmel A. M. Braun Vacuum-ultraviolet photochemically initiated modification of polystyrene surfaces: chemical changes Photochem. Photobiol. 2005 81 777 782
17. J. López Gejo N. P. Manoj S. Sumalekshmy H. Gliemann T. Schimmel M. Wörner A. M. Braun Vacuum-ultraviolet photochemically initiated modification of polystyrene surfaces: morphological changes and mechanistic investigations Photochem. Photobiol. Sci. 2006 5 948 954
18. V. V. Ivanov N. A. Popov O. V. Proshina T. V. Rakhimova G. B. Rulev V. B. Saenko Study of the ozone production and loss during oxygen photolysis in a VUV-ozonator chamber Tech. Phys. Lett. 2001 27 29 31
19. C. S. Foote, J. S. Valentine and A. Greenberg, Active Oxygen in Chemistry, Springer, New York, 1995
20. R. Wrobel W. Sander E. Kraka D. Cremer Reactions of dimethyl ether with atomic oxygen: a matrix isolation and a quantum chemical study J. Phys. Chem. A 1999 103 3693 3705
21. M. C. Gonzalez E. Oliveros M. Wörner A. M. Braun Vacuum ultraviolet photolysis of aqueous reaction systems J. Photochem. Photobiol., C 2004 5 225 246
22. M. Zahorodna E. Oliveros M. Wörner R. Bogoczek A. M. Braun Dissolution and mineralization of ion exchange resins: differentiation between heterogeneous and homogeneous (photo-)Fenton processes Photochem. Photobiol. Sci. 2008 7 1480 1492
23. N. Quici M. I. Litter A. M. Braun E. Oliveros Vacuum-UV photolysis of aqueous solutions of citric and gallic acids J. Photochem. Photobiol., A 2008 197 306 312
24. W. Kern Photochemical modification of polymer surfaces Trends Photochem. Photobiol. 2001 7 11 30
25. D. Feldman, Polymeric Building Materials, Taylor & Francis, Routledge, New York, 1989
26. G. A. Olah and Á. Molnár, Hydrocarbon Chemistry, Wiley, New York, 2003
27. V. D. Komissarov I. N. Komissarova Formation of phenol during ozonolysis of benzene Russ. Chem. Bull. 1973 22 656 658
28. J. Salas, Vicente. Modificatión fotoquímica de submicropartículas en aerosoles, Doctoral thesis, Universidad Politécnica de Valencia, Valencia, 2006 (Experimental work: Lehrstuhl für Umweltmesstechnik, Universität Karlsruhe)
29. K. R. May The Collison nebulizer: description, performance and application J. Aerosol Sci. 1973 4 235 238
30. Zs. Laszló I. Ilisz G. Peintler A. Dombl VUV intensity measurement of a 172 nm Xe excimer lamp by means of oxygen actinometry Ozone: Sci. Eng. 1998 20 421 432
31. H. J. Kuhn S. E. Braslavsky R. Schmidt Chemical actinometry Pure Appl. Chem. 2004 76 2105 2146
32. G. Gordon G. E. Pacey W. J. Cooper R. G. Rice Current state-of-the-art measurements of ozone in the gas phase and in solution Ozone: Sci. Eng. 1988 10 353 365
33. K. Rakness G. Gordon B. Langlais W. Masschelein N. Matsumoto Y. Richard C. M. Robson I. Somiya Guideline for measurement of ozone concentration in the process gas from an ozone generator Ozone: Sci. Eng. 1996 18 209 229
34. A. M. Braun, M.-T. Maurette and E. Oliveros, Technologie photochimique, Presses Polytechniques Romandes, Lausanne, 1986, Chapter 6.11
35. A. M. Braun, M.-T. Maurette and E. Oliveros, Photochemical Technology, transl. D. F. Ollis and N. Serpone, Wiley, Chichester, 1991, Chapter 6.11
36. 2 Ozone: Sci. Eng. 1999 21 583 603
37. A. M. Braun I. Gassiot Pintori H.-P. Popp Y. Wakahata M. Wörner Technical development of UV-C- and VUV-photochemically induced oxidative degradation processes Water Sci. Technol. 2004 49 235 240
38. J. Salas Vicente, J. López Gejo, S. Rothenbacher, S. Sarojiniamma, E. Gogritchiani, M. A. Miranda, M. Wörner, E. Oliveros, G. Kasper and A. M. Braun, VUV-photochemical functionalization of polystyrene aerosols, in Basics and applications of photopolymerization reactions, ed., J. P. Fouassier, and, X. Allonas., Research Signpost, Trivandrum, India, 2009
39. A. J. Cox A. J. DeWeerd J. Linden An experiment to measure Mie and Rayleigh total scattering cross sections Am. J. Phys. 2002 70 620 625
40. D. W. Hahn, Light scattering theory, University of Florida, Gainesville, 2008, http://plaza.ufl.edu/dwhahn/Rayleigh%20and%20Mie%20Light%20Scattering.pdf
41. J. Salas Vicente J. López Gejo S. Rothenbacher M. Wörner E. Oliveros G. Kasper A. M. Braun Functionalization of polystyrene aerosol particles by photooxychlorination Appl. Mater. Interface
42. G. V. Lubarsky M. R. Davidson R. H. Bradley Characterization of polystyrene microspheres surface-modified using a novel UV-ozone/fluidized- bed reactor Appl. Surf. Sci. 2004 227 268 274