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In the diffusion-controlled electron transfer theory of Tang andMarcus*there are two characteristic times*the truncation or saturation timeand the critical time The Truncation Time is Notated as 1/γ in Their Work, Todistinguish It from the Critical Time, Notated Tc; the Critical Time is muchshorter. (Recent Experiments Suggest That the Critical Time is on the Orderof a Few milliseconds.) We Will Notate the Truncation Time as τon.
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In the diffusion-controlled electron transfer theory of Tang andMarcus, there are two characteristic times, the truncation or saturation timeand the critical time. The truncation time is notated as 1/γ in their work, todistinguish it from the critical time, notated tc; the critical time is muchshorter. (Recent experiments suggest that the critical time is on the orderof a few milliseconds.) We will notate the truncation time as τon.
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Two lots of these NCs were used; the first lot was used for themeasurements shown in Figure 4a-c had an absorption peak at 583nm an emission peak at 602 nm The Second Lot was Used for Themeasurements in Figure 4d-f and Had an Absorption Peak At 584 Nm Andan Emission Peak At 595 nm. the Absorption Spectrum from the First Lot Isshown in Figure 1.
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Two lots of these NCs were used; the first lot was used for themeasurements shown in Figure 4a-c and had an absorption peak at 583nm and an emission peak at 602 nm. The second lot was used for themeasurements in Figure 4d-f and had an absorption peak at 584 nm andan emission peak at 595 nm. The absorption spectrum from the first lot isshown in Figure 1.
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note The highest energy excitation used by Knappenberger et al.6 in theirinitial study corresponded to 525 nm so they did not explore this higherenergy regime with spherical NCs In a Follow-up Study of Excitation Energydependence in Tetradecylphosphonic Acid-capped CdSe Nanorods, They Sawno Difference Between 400 Nm Excitation and 510 Nm excitation. However,the Truncation Times Observed with NRs Are So Much Shorter (of Order 1 s)that It is Possible That Whenever the New Dynamics Are Introduced by Thehigh-energy Excitation, They Only Operate on the Longer (∼10 s) Timescalewe observe.
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The highest energy excitation used by Knappenberger et al.6 in theirinitial study corresponded to 525 nm, so they did not explore this higherenergy regime with spherical NCs. In a follow-up study of excitation energydependence in tetradecylphosphonic acid-capped CdSe nanorods, they sawno difference between 400 nm excitation and 510 nm excitation. However,the truncation times observed with NRs are so much shorter (of order 1 s)that it is possible that whenever the new dynamics are introduced by thehigh-energy excitation, they only operate on the longer (∼10 s) timescalewe observe.
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