Oxazoline-oxazinone oxidative rearrangement. Divergent syntheses of (2S,3S)-4,4,4-trifluorovaline and (2S,4S)-5,5,5-trifluoroleucine

Journal of Organic Chemistry

Volumn 74, Issue 15, 2009, Pages 5510-5515

  Pigza, Julie A ^a   Quach, Tim ^a   Molinski, Tadeusz F ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL EQUATIONS; CONFIGURATIONALLY; DIVERGENT SYNTHESIS; ENAMINES; HYDROCHLORIDE SALTS; OXAZINONES; OXAZOLINES; OXIDATIVE REARRANGEMENTS; SELECTIVE HYDROGENATION; STEREOSELECTIVE SYNTHESIS;

AMINATION; AMINES; AMINO ACIDS; HYDROGENATION; HYDROLYSIS; NITROGEN COMPOUNDS; ORGANIC ACIDS; STEREOCHEMISTRY; STEREOSELECTIVITY;

SYNTHESIS (CHEMICAL);

4,4,4 TRIFLUORO 3 METHYLBUTANOIC ACID; 4,4,4 TRIFLUOROVALINE; 5,5,5 TRIFLUOROLEUCINE; AMINO ACID; BETA FLUOROMETHYLDIHYDROOXAZINONE; BUTYRIC ACID; CARBOXYLIC ACID DERIVATIVE; CHLORIDE; DIHYDRO 2H OXAZINONE; ENAMINE; IMINE; OXAZINONE; OXAZOLINE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHIRALITY; CONTROLLED STUDY; DRUG STRUCTURE; DRUG SYNTHESIS; HYDROGENATION; HYDROGENOLYSIS; HYDROLYSIS; ISOMERIZATION; OXIDATION; STEREOCHEMISTRY;

LEUCINE; MOLECULAR CONFORMATION; OXAZINES; OXAZOLES; OXIDATION-REDUCTION; STEREOISOMERISM; VALINE;

EID: 68049142866     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo900654y     Document Type: Article

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