Gas-phase facial diastereoselectivity of equatorial and axial 4-chloro-adamant-2-yl cations

Journal of Organic Chemistry

Volumn 74, Issue 15, 2009, Pages 5135-5144

  Fraschetti, Caterina ^a   Novara, Francesca R ^a   Filippi, Antonello ^a   Speranza, Maurizio ^a   Trout, Neil A ^b   Adcock, William ^b   Marcantoni, Enrico ^c   Renzi, Gabriele ^c   Roselli, Graziella ^c   Marcolini, Mauro ^c  

^a SAPIENZA UNIVERSITY OF ROME   (Italy)

^b FLINDERS UNIVERSITY   (Australia)

^c UNIVERSITY OF CAMERINO   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

2-METHYLENE; ADAMANTANE; ADAMANTANES; AXIAL ORIENTATIONS; CARBOCATIONS; CHEMICAL EQUATIONS; CHLORINE ATOM; DIASTEREO-SELECTIVITY; EXPERIMENTAL APPROACHES; GASPHASE; INTRINSIC FACTORS; MP2/6-31G; NONCOVALENT; REACTION COORDINATES; TEMPERATURE RANGE; THEORETICAL CALCULATIONS;

CHLORINE; POSITIVE IONS; STEREOSELECTIVITY;

COMPLEXATION;

4 CHLORO 2 METHYL ADAMANTAN 2 OL; 4 CHLORO 2 METHYLENE ADAMANTANE; 5 CHLORO 2 METHYL ADAMANTAN 2 OL; 5 CHLORO 2 METHYLENE ADAMANTANE; ACETOIN; ADAMANTANE DERIVATIVE; CATION; UNCLASSIFIED DRUG;

ARTICLE; CATALYSIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; DIASTEREOISOMER; EPIMERIZATION; FLUORINATION; PROTON TRANSPORT; STEREOCHEMISTRY; TEMPERATURE DEPENDENCE; TEMPERATURE SENSITIVITY; THERMODYNAMICS;

EID: 68049115657     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo9004298     Document Type: Article

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