Noninnocent behavior of ancillary ligands: Apparent trans coupling of a saturated N-heterocyclic carbene unit with an ethyl ligand mediated by nickel

Journal of the American Chemical Society

Volumn 131, Issue 30, 2009, Pages 10461-10466

  Steinke, Tobias ^a   Shaw, Bryan K ^a   Jong, Howard ^a   Patrick, Brian O ^a   Fryzuk, Michael D ^a   Green, Jennifer C ^b  

^a UNIVERSITY OF BRITISH COLUMBIA   (Canada)

^b UNIVERSITY OF OXFORD   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

ANCILLARY LIGANDS; C-C COUPLING; CARBENE; DIPHOSPHINE LIGAND; ETHYL GROUPS; H-BONDS; HYDRIDE COMPLEXES; MIGRATORY INSERTION; N-HETEROCYCLIC CARBENE; OXIDATIVE ADDITIONS; RAPID REACTIONS; SQUARE-PLANAR NICKEL; TRANSITION STATE;

CATALYST DEACTIVATION; CATALYST POISONING; DENSITY FUNCTIONAL THEORY; DEUTERIUM; ETHYLENE; LABELS; LIGANDS; METAL COMPLEXES; NICKEL ALLOYS; NICKEL COMPOUNDS;

NICKEL;

ALCOHOL; ALKENE; CARBENE; CARBON; DEUTERIUM; ETHYLENE; HETEROCYCLIC COMPOUND; LIGAND; METAL COMPLEX; NICKEL; TETRAHYDROFURAN;

ARTICLE; CATALYST; CHEMICAL BOND; CROSS LINKING; DENSITY FUNCTIONAL THEORY; ELIMINATION REACTION; LABELING INDEX;

EID: 68049103329     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja901346g     Document Type: Article

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